Study on the Structure Model of Water Molecule and the Reasons of Formation of Some Characteristics of Liquid & Solid Water
Peimin Pu,
Jiangping Pu,
Zhengbin Zhu
Issue:
Volume 9, Issue 2, March 2020
Pages:
11-27
Received:
14 April 2020
Accepted:
22 May 2020
Published:
17 June 2020
Abstract: A model for water (H2O) molecule, the structure of ice, snow and liquid water were presented, and the reasons of formation of their specific characteristics were modeled in good coincidence with observed data. (1) A stable quasi rigid molecule structure may be constructed by dominant trajectories of electrons round and between the H-O-H nucleus according with the laws of Columb’s force and Kepler’s movement rule. The core of the water molecule is a isosceles triangle with ratio of distances between nucleus: (H-H)2/(H-O)2=2.5, which would be surrounded by moving electrons and form an equilateral triangular pyramid (ETP Model) with 2 pairs of “+/-” electricity endpoints and edge length of 0.48017nm. (2) The “+/-” endpoint of a water molecule may attract other “-/+” endpoint in distance of less than 0.27 nm. A molecule may joints other molecule to have all their 4 planes parallel each other and the 6 molecules may joint as a hexagon loop with a common plane and then these loops may similarly be formed for each plane of the pyramid and extend to whole space and form the water ice structure with Zigzag Hexagon Tunnel-Vacancy System (ZHTVS Model) with porosity of ≥2.28. (3) A “sheet model” of desublimation like the snowflake is more possible phenomenon below 0°C in air, possessing the self-similarity with the hexagon-sexangle-six needle forms. (4) The liquid water has the same structure of the solid ice, but because there is 1/11 possibility to have an appearance of double electrons at one endpoint of the pyramid with “-” charge, so when the temperature is above 0°C, a part of water molecules on the frame may possess the energy for separating from the frame, and will move into the tunnel/vacancy, being as a “free water molecule”. The total volume of the liquid water would decrease until to 4°C to the minimum. The ratio of density of solid water ice and liquid water is 11/12=0.916667. (5) The relationships of the specific characteristics of the water with its construction, such as density, expansibility, compressibility, specific heat capacity, electric and thermal conductivity, solubility for O2, H2S, NaCl, KCl, etc. were discussed and numerical modeled. The experiments of saturated solution of NaCl audio-visual indicated that there are tunnel/vacancy spaces for storing NaCl molecules/ions, and increasing the volume of 1/11 of water volume after freezing. (6) The surface structure of liquid water and the applications of research results are presented in other papers.
Abstract: A model for water (H2O) molecule, the structure of ice, snow and liquid water were presented, and the reasons of formation of their specific characteristics were modeled in good coincidence with observed data. (1) A stable quasi rigid molecule structure may be constructed by dominant trajectories of electrons round and between the H-O-H nucleus acc...
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Thermodynamics of Moving Bodies or a New Approach to Emergent Gravity
Issue:
Volume 9, Issue 2, March 2020
Pages:
28-40
Received:
24 May 2020
Accepted:
15 June 2020
Published:
28 June 2020
Abstract: Recent theoretical developments propose that gravity is emergent phenomenon. In line with this, in this paper, we show that gravitational and inertial properties of matter can be sufficiently explained by thermodynamics for a system consisting of material systems immersed in the quantum vacuum energy reservoir without reference to the microscopic constituencies of the quantum vacuum. The study focuses on the transfer of energy and matter in the interaction of material system with its vacuum surroundings and the relation of those to the system's macroscopic state variables and mechanical behavior of the system associated with forces acting on it. This analysis suggests that vacuum energy density about material systems is diminished and quantum vacuum energy density field takes on specific gradient there. Hence, gravity appears as effect of the change in the energy density of medium related with presence of another material object modifying vacuum surroundings and causing spontaneous motion of the system to minimize its energy driven by the second law. Whereas, inertia is explained to be an emergent thermodynamic effect of the change in the vacuum energy field about objects associated with the alteration of energy of systems itself due to the transfer of energy between systems to its surroundings. When those energy transfer operations do not comply with the second law of thermodynamic in terms of direction and rate of the energy flow, there will be generated resistance to the imposed changes known as inertial force. In such representation the equivalence principle finds unique definition revealing its origin.
Abstract: Recent theoretical developments propose that gravity is emergent phenomenon. In line with this, in this paper, we show that gravitational and inertial properties of matter can be sufficiently explained by thermodynamics for a system consisting of material systems immersed in the quantum vacuum energy reservoir without reference to the microscopic c...
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