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A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes

Received: 6 September 2014     Accepted: 23 September 2014     Published: 23 September 2014
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Abstract

The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.

Published in Science Journal of Chemistry (Volume 2, Issue 6-2)

This article belongs to the Special Issue Polyelectrolytes & Dyes

DOI 10.11648/j.sjc.s.2014020602.12
Page(s) 8-13
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Cationic Dye, Metachromasy, Anionicpolyelectrolytes, Electrostatic Interaction, Aggregation

References
[1] A Mitra, R. K Nath,, SBiswas., A. K., Chakraborty, A. K., Panda Mitra A. , J. Photochrem. Photobiol, A: Chem, vol.111, 1997, pp 157.
[2] A.Mitra, A.K.Chakraborty, J.Photochem.Photobiol.A:Chem., vol.178,2006, pp198.
[3] R.W Horbin., Biochemie.Biochem., vol.77, 2002, pp 3.
[4] Bergeron J. A., M. J Singer,. Biophys. Biochem. Cytol. vol.4,1958, pp.433.
[5] M. K. Pal , B. K. Ghosh, Makromol. Chem. vol. 181, 1980, pp1459 .
[6] Norden B., Kubista M., in : B.Samori, E.W.Thulstrup (Eds.), Polarized Spectroscopy of ordered systems, vol.242,Kulwer Academic Publisher, Dordrecht, Holland, 1988.
[7] Sabate R., EsterlichJ., J.Phys.ChemB, vol.107,2003, pp.4137.
[8] von Berlepsch H., Kirstein S., Bottcher, C, Langmuir, vol.18,2002,pp.769.
[9] Sabate R., Gallardo M., De la Maza A., J.Esterlich, Langmuir,vol.17,2001, pp.6433.
[10] Berret J.F., Cristobal G.,Hervel P., Oberdisse J.,Grillo I., vol.E9, Eur.Phys J 2002, pp.301.
[11] Meszaos R., Varga, I.,Gilanyi T.,J.Phys.Chem.B vol.117, 2005, pp.13538.
[12] Monteux C . ,WilliamsC.E., Meunier J., Anthony O., BergeronV., Langmuir Vol.20,2004,pp. 57.
[13] Honda C., Kamizono H.,.Matsumoto K., Endo K., J.Colloid Interface Sci vol.278.2004, , pp.310.
[14] MoulikS.P., GuptaS,.DasA.R., Makromol.Chem,vol.181, 1980,pp. 1459.
[15] Lee J ., Moroi Y,,J.Colloid Interface Sci. 2vol.273,2004, pp.645.
[16] Mesa C.L., J.Colloid Interface Sci . vol.286,2005, pp.148.
[17] Konradi R.,Ruhe J., Macromolecules vol.38,2005, pp.6140.
[18] VilletiM., BorsaliA., Crespo R.,SoldiV.,Fukada K., Macromol.Chem.Phys. vol.205,2004, pp.907.
[19] Fundin J,,Hansson P.,Brown W., Lidegran I.,Macromolecules vo.30, 1997, pp.1118.
[20] Mitra A., Nath A. R., and ChakrabortyA.K.,Colloid Polym Sci. , vol.271,1993, pp.1042.
[21] Panda A.K., Chakraborty A.K., J.Colloid Interface Sci. vol.203,1998, pp.260.
[22] Chakraborty, A.K,.Nath, R.K, Spectrochim Acta vol.45A,1989, pp.981.
[23] Jain N. ,Trabelsi S., Guillot S.,Meloughlin D. ,Langevin D., Leteiller P., Turmine, M., Langmuir, vol..20,2004, pp.8496.
[24] Bakshi M.S., Varga I., GilanyiT.,J.Phys.Chem.B,vol. 109 ,2005, pp.13538.
[25] Balomenou L.,and Bokias G., Langmuir, vol. 21,2005, pp.9038.
[26] Bakshi M.S., and Sachar S.,Colloid Polym.Sci. vol.283,2005,pp.671.
[27] Romani A.P., Gehlen M.H., Itri R., Langmuir, vol.21,2005, pp.127.
[28] Wang C., Tam K.C., Langmuir, vol.18,2002, pp. 6484.
[29] Sjogren H .,Ericsson C.A., Evenas J.,Ulvenlund S .,Biophys J., vol.89,2005, pp.4219 .
[30] Zhu D.M., EvansR.K., Langmuir, 2006, 22 ,pp.3735.
[31] Chatterjee A.,Moulik S.P., Majhi P.R., and Sanyal S.K., Biophys Chem.vol.98,,2002,98, pp.313.
[32] Mata J., Patel J., Jain N.,Ghosh G.,Bahadu, P., J.Colloid Interface Sci. 2006, 297 , pp.797.
[33] Jiao Q.C., Liu Q .,Sun C.,and He H ., Talanta, vol.1095,1999, , pp.48.
[34] Liu Q.,and Jiao Q.C .,Spectrosc.Lett., vol.31,1998, pp.913.
[35] Jiao Q.C. ,and Liu Q.,Spectrochim. Acta, 1vol.55A,999, pp.1667.
[36] Jiao Q.C and Liu Q., Anal.Lett. vol..31,1998, pp.1311.
[37] Jiao Q.C. ,and Liu Q, Spectrosc.Lett.vol.31, 1998, pp.1353.
[38] Hugglin D., Seiffert, A.,Zimmerman, W,Histochemistry, vol.86,1986, pp.71.
[39] Mitra A ., Nath R.K .,and. Chakraborty A.K., Colloid Polym. Sci., vol.271,1993, pp.1042.
[40] Basu. S. , Gupta A.K. ,and Rohatgi-Mukherjee K. K, J.Indian Chem. Soc.1vol.59,982, pp.578 .
[41] Pal M.K., SchubertM.J. Histochem Cytoche., vol.9,1961,pp. 673.
[42] Pal M.K,,and Ghosh B.K., Macromol.Chem, vol.181,1980,pp. 1459.
[43] Pal M.K and Ghosh B.K., Macromol.Chem. vol.180,1979, pp.959.
[44] Pal M.K and Schubert M .,J.Phys.Chem., vol.17,1963,pp.182.
[45] Frank. H.S., and.Evans M.W .,J.Chem.Phys. vol.17,1945, pp.507 .
[46] Kauzmann W.,Advan.Protein.Chem.vol.14, 1959, pp1.
[47] Bruning and Holtzer A., J.Am.Chem Soc.,vol.83,1961, pp.4865.
[48] WhitneyP.L., and Tanford C., J.Biol.Chem vol.237,1962, pp.1735 .
[49] Mukerjee P.,and Ray A. ,J.Phys.Chem. vol.67,1963, pp.190.
[50] Frank H.S. and Quist A.S., J.Chem.Phys.,1vol.34,961, pp.604.
[51] Rabinowitch E ., Epstein.,L.F J.Am.Chem.Soc., vol.63,1941,pp.69.
[52] Romani A.P., Gehlen M.H. and. Itri R., Langmuir, vol.21,2005, pp.127.
[53] Levine A., Schubert M., J.Am.Chem.Soc., vol.74,1958, pp.5702.
[54] Dasgupta S., Nath R.K .,Biswas S., Hossain J., Mitra A.,and Panda A.K. ,Colloids Surf A: Physicochem Eng.Aspects, vol.302,2007, pp.17.
[55] RoseNJ; DragoRS; Journal of American Chemical Society, 1vol.81,959, pp.6138.
[56] Nandini R, Vishalakshi B,e-journal of chemistry, vol.8,2011, pp.S253.
[57] Nandini R, Vishalakshi B,spectrochimica acta Part A,, vol.9,2009, pp.1025
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    Nandini Ratnakar. (2014). A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Science Journal of Chemistry, 2(6-2), 8-13. https://doi.org/10.11648/j.sjc.s.2014020602.12

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    ACS Style

    Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci. J. Chem. 2014, 2(6-2), 8-13. doi: 10.11648/j.sjc.s.2014020602.12

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    AMA Style

    Nandini Ratnakar. A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes. Sci J Chem. 2014;2(6-2):8-13. doi: 10.11648/j.sjc.s.2014020602.12

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  • @article{10.11648/j.sjc.s.2014020602.12,
      author = {Nandini Ratnakar},
      title = {A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes},
      journal = {Science Journal of Chemistry},
      volume = {2},
      number = {6-2},
      pages = {8-13},
      doi = {10.11648/j.sjc.s.2014020602.12},
      url = {https://doi.org/10.11648/j.sjc.s.2014020602.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.s.2014020602.12},
      abstract = {The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.},
     year = {2014}
    }
    

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    T1  - A Comparative Study of Metachromasy Induced in Azure B by Anionic Polyelctrolytes
    AU  - Nandini Ratnakar
    Y1  - 2014/09/23
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    DO  - 10.11648/j.sjc.s.2014020602.12
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 8
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    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.s.2014020602.12
    AB  - The interaction of two cationic dyes, namely, Azure B (AB) with an anionic polyelectrolyte, namely, sodium heparinate (NaHep) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium alginate was found to be greater than that formed between Azure B and sodium carboxymethylcellulose.This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes.The interaction parametersrevealed that binding between Azure B and anionic poloyelectrolytes was mainly due to electrostaticinteraction.
    VL  - 2
    IS  - 6-2
    ER  - 

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Author Information
  • Department of Chemistry, MITE, Moodabidri-574 226 (DK), Karnataka, India

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