Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage

Dame Seye; Mouhamadou Birame Diop; Assane Toure; Tidiane Diop; Cheikh Abdoul Khadir Diop; Mamadou Sidibe; Aminata Diasse Sarr; Libasse Diop

doi:doi:10.11648/j.ajhc.20190504.12

Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage

Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, Mamadou Sidibe, Aminata Diasse Sarr, Libasse Diop

Published in American Journal of Heterocyclic Chemistry (Volume 5, Issue 4)

Received: 13 February 2020 Accepted: 27 February 2020 Published: 10 March 2020

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH₂ groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H₃O⁺ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl₂. 2H₂O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh₃Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh₃Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).

Published in	American Journal of Heterocyclic Chemistry (Volume 5, Issue 4)
DOI	10.11648/j.ajhc.20190504.12
Page(s)	81-85
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Chloride, Infrared, Mössbauer, Sn-Ph Bonds Cleavage, Tin (IV), Urea Deamination

References

[1]	Carraher C. E., Roner M. R., Frank J., Slawek P., Mosca F., Shahi K., Moric-Johnson A. and Miller L. (2019). Organotin Polymers for the Control of Pancreatic Cancer, OBM Hepatology and Gastroenterology. 3 (2): doi: 10.21926/obm.hg.1902019.
[2]	Roner M., Shahi K., Battin A., Barot G. and Arnold T. (2014). Organotin Polymers As Chemotherapeutic Agents: Breast and Pancreatic Cancers, Journal of Polymer Materials. 31 (1): 1-14.
[3]	Barot G., Roner M. R., Naoshima Y., Nagao K., Shahi K. and Carraher C. E. (2009). Synthesis, structural characterization, and preliminary biological characterization of organotin polyethers derived from hydroquinone and substituted hydroquinones, Journal of Inorganic and Organometallic Polymers and Materials. 19 (1): 12–27.
[4]	Roner M. R., Shahi K. R., Barot G., Battin, A. and Carraher C. E. (2009). Preliminary results for the inhibition of pancreatic cancer cells by organotin polymers, Journal of Inorganic and Organometallic Polymers and Materials.. 19 (3): 410–414.
[5]	Carraher C., Roner M., Lynch M., Moric-Johnson A., Miller L., Slawek P., Mosca F. and Frank J. (2018). Organotin poly (ester ethers) from salicylic acid and their ability to inhibit human cancer cell lines, Journal of Clinical Research in Oncology. 1 (1): 1-11.
[6]	Carraher Jr C. and Roner M. (2014). Organotin polymers as anticancer and antiviral agents, Journal of Organometallic Chemistry. 751: 67-82.
[7]	Sirajuddin M., Ali S., McKee V., Zaib S. and Iqbal J. (2014). Organotin (IV) carboxylate derivatives as a new addition to anticancer and antileishmanial agents: design, physicochemical characterization and interaction with Salmon sperm DNA, RSC Advances. 4: 57505–57521.
[8]	Meneghetti M. R. and Meneghetti S. M. P. (2015). Sn (IV)-based organometallics as catalysts for the production of fatty acid alkyl esters, Catalysis Science & Technology. 5: 765–771.
[9]	Mao W., Bao K., Feng Y., Wang Q., Li J. and Fan Z. (2015). Synthesis, crystal structure, and fungicidal activity of trioriganotin (IV) 1-methyl-1H-imidazole-4-carboxylates, Main Group Metal Chemistry. 38: 27–30.
[10]	Kagan C. R., Breen T. L. and Kosbar L. L. (2001). Patterning organic–inorganic thin-film transistors using microcontact printed templates, Applied Physics Letters. 79 (21): 3536–3538.
[11]	Nardelli M., Pelizzi C. and Pelizzi G. (1976). Structulal researches on organotin (IV) compounds. Synthesis and structure of nitratotriphenyl (triphenylphosphine oxide) tin (IV), Journal of Organometallic Chemistry. 112: 263–272.
[12]	Nardelli M., Pelizzi C. and Pelizzi, G. (1977). Structulal researches on nitrato complexes of organotin: Coordinative interactions Sn–O in nitratotriphenyl (triphenylarsine oxide) tin (IV), Journal of Organometallic Chemistry. 125: 161–172.
[13]	Pelizzi C., Pelizzi G. and Tarasconi, P. A. (1977). Structulal researches on nitrato complexes of organotin: Coordinative interactions Sn–O in nitratotriphenyl (pyridine N-oxide) tin (IV), Journal of Organometallic Chemistry. 124: 151–160.
[14]	Renamy S. V., Okio K. Y. A., Diop M. B. and Diop L. (2019). Some organotin (IV) nitrate adducts: syntheses, far infrared and mössbauer characterization, International Journal of Advanced Research. 7 (5): 12–22.
[15]	Chandrasekhar V., Gopal K., Sasikumar P. and Thirumoorthi, R. (2005). Organooxotin assemblies from Sn-C bond cleavage reactions, Coordination Chemistry Reviews. 249: 1745–1765.
[16]	Gueye N., Diop L., Molloy K. C. and Kociok-Kohn G. (2010). Bis (dicyclohexylammonium) µ-oxalato-⁴O¹, O²: O^1', O^2'-bis [aqua (oxalato-²O¹, O²) diphenylstannate (IV)], Acta Crystallographica. E66: m1645-m1646.
[17]	Nakamoto K. (1997). Infrared and Raman Spectra of Inorganic and Coordination Compounds, Edited by John Wiley and Sons, 5th Edition.
[18]	Parish R. V. and Platt R. H. (1969). Studies in Mossbauer Spectroscopy. Part I. Interpretation of Quadrupole Splitting Data for Tin (IV) Compounds, Journal of the Chemical Society A: 2145–2150.
[19]	Reiss G. J. and Helmbrecht C. (2012). Bis (diiso¬propyl¬ammonium) hexa¬chlorido¬stannate (IV), Acta Crystallographica. E68: m1402–m1403.
[20]	vanMegen M., Prömper S. and Reiss G. J. (2013). Bis (3-aza¬niumylpyridin-1-ium) hexa¬chloridostannate (IV) dichloride, Acta Crystallographica. E69: m217.
[21]	Tudela D. and Fernandez, V. (1985). Mossbauer Study of the cis-trans Isomers of Tin (IV) Complexes. Some Considerations about the Sign of the Electric-field Gradient, Journal of the Chemical Society Dalton Transactions. 1281-1284.
[22]	Tudela D., Muro C., Fernandez V. and Tornero J. D. (1986). Vibrational and ¹¹⁹Sn Mössbauer Study of Tin Tetrahalide Complexes with Benzofuroxan Derivatives, Zeitschrift für anorganische und allgemeine Chemie. 538: 201–206.
[23]	Tudela D., Khan M. A. and Juckermant J. J. (1991). Structural Information from the Mossbauer Quadrupole Spfitting of Tin (IV) Chloride Complexes, Structural Chemistry. 2: (31) 239-(35) 243.
[24]	Tudela D. and Tornero, J. D. (1993). cis-trans Isomerism in tetrabromobis (1, 3-dimethylurea) tin (IV), Inorganica Chimica Acta. 214: 197–199.
[25]	Diop T., Diop L., Michaud F. and Ardisson J. D. (2013). Synthesis and crystal structure of Et₄NNO₃ (SnPh₃NO₃)(SnPh₃Cl) ₂, Main Group Metal Chemistry. 36: 83–88.
[26]	Tudela D., Sanchez-Herencia A. J., Diaz M., Fernandez-Ruiz R., Menéndez N. and Tornero J. D. (1999). Mössbauer spectra of tin (IV) iodide complexes, Journal of the Chemical Society Dalton Transactions. 4019–4023.
[27]	Diallo W., Toure A., Diop C. A. K. and Sidibe M. (2018). Some new oxalato and sulfato SnR₃ (R=Me, Ph) and SnR’ ₂Cl (R’=Ph, Bu) residues containing derivatives and complexes: synthesis, infrared, NMR and Mӧssbauer studies, International Journal of Advanced Research. 6 (2): 861–870.

Cite This Article

Plain Text BibTeX RIS

APA Style

Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. (2020). Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. American Journal of Heterocyclic Chemistry, 5(4), 81-85. https://doi.org/10.11648/j.ajhc.20190504.12

Copy | Download

ACS Style

Dame Seye; Mouhamadou Birame Diop; Assane Toure; Tidiane Diop; Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am. J. Heterocycl. Chem. 2020, 5(4), 81-85. doi: 10.11648/j.ajhc.20190504.12

Copy | Download

AMA Style

Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am J Heterocycl Chem. 2020;5(4):81-85. doi: 10.11648/j.ajhc.20190504.12

Copy | Download

@article{10.11648/j.ajhc.20190504.12,
  author = {Dame Seye and Mouhamadou Birame Diop and Assane Toure and Tidiane Diop and Cheikh Abdoul Khadir Diop and Mamadou Sidibe and Aminata Diasse Sarr and Libasse Diop},
  title = {Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {5},
  number = {4},
  pages = {81-85},
  doi = {10.11648/j.ajhc.20190504.12},
  url = {https://doi.org/10.11648/j.ajhc.20190504.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20190504.12},
  abstract = {Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage
AU  - Dame Seye
AU  - Mouhamadou Birame Diop
AU  - Assane Toure
AU  - Tidiane Diop
AU  - Cheikh Abdoul Khadir Diop
AU  - Mamadou Sidibe
AU  - Aminata Diasse Sarr
AU  - Libasse Diop
Y1  - 2020/03/10
PY  - 2020
N1  - https://doi.org/10.11648/j.ajhc.20190504.12
DO  - 10.11648/j.ajhc.20190504.12
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 81
EP  - 85
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20190504.12
AB  - Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).
VL  - 5
IS  - 4
ER  -

Copy | Download

Author Information

Dame Seye

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Mouhamadou Birame Diop

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Assane Toure

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Tidiane Diop

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Cheikh Abdoul Khadir Diop

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Mamadou Sidibe

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Aminata Diasse Sarr

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal
Libasse Diop

Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. (2020). Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. American Journal of Heterocyclic Chemistry, 5(4), 81-85. https://doi.org/10.11648/j.ajhc.20190504.12

Copy | Download

ACS Style

Dame Seye; Mouhamadou Birame Diop; Assane Toure; Tidiane Diop; Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am. J. Heterocycl. Chem. 2020, 5(4), 81-85. doi: 10.11648/j.ajhc.20190504.12

Copy | Download

AMA Style

Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am J Heterocycl Chem. 2020;5(4):81-85. doi: 10.11648/j.ajhc.20190504.12

Copy | Download

@article{10.11648/j.ajhc.20190504.12,
  author = {Dame Seye and Mouhamadou Birame Diop and Assane Toure and Tidiane Diop and Cheikh Abdoul Khadir Diop and Mamadou Sidibe and Aminata Diasse Sarr and Libasse Diop},
  title = {Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {5},
  number = {4},
  pages = {81-85},
  doi = {10.11648/j.ajhc.20190504.12},
  url = {https://doi.org/10.11648/j.ajhc.20190504.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20190504.12},
  abstract = {Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage
AU  - Dame Seye
AU  - Mouhamadou Birame Diop
AU  - Assane Toure
AU  - Tidiane Diop
AU  - Cheikh Abdoul Khadir Diop
AU  - Mamadou Sidibe
AU  - Aminata Diasse Sarr
AU  - Libasse Diop
Y1  - 2020/03/10
PY  - 2020
N1  - https://doi.org/10.11648/j.ajhc.20190504.12
DO  - 10.11648/j.ajhc.20190504.12
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 81
EP  - 85
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20190504.12
AB  - Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).
VL  - 5
IS  - 4
ER  -

Copy | Download