Evaluation of Kinetic Approach in Describing Potassium Bioavailability

Monier Morad Wahba; Amal M. Aziz; Alaa M. Zaghloul

doi:doi:10.11648/j.ajhc.20170306.14

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Evaluation of Kinetic Approach in Describing Potassium Bioavailability

Monier Morad Wahba, Amal M. Aziz, Alaa M. Zaghloul

Published in American Journal of Heterocyclic Chemistry (Volume 3, Issue 6)

Received: 11 November 2017 Accepted: 27 November 2017 Published: 26 December 2017

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Abstract

The objective of this study was to determine the potassium (K) release kinetics of sandy soil sample representative soil of Egyptian new reclaimed areas as affected by treatments of different rates of compost and chemical fertilizers applied individually or mixture of both type sand the effect of two irrigation regimes i.e. 80 and 60% of water requirements IR. Four mathematical models (power function, Elovich, parabolic diffusion and first-order) were used to fitted the data describe K desorption reactions involving 168-hr cumulative reaction time. Comparison of the models using the coefficient of determination (r²) and the standard error of the estimate (SE) indicated that the Elovich and the power function equations overall displayed the best fitted ones. The first-order rate and for less extent, parabolic diffusion equation were less fitted to describe the kinetic data. The constants of the best fitted models represent the rate of K release indicated that all treatments applied to soil gave high and significant increase in rate of K release compared to the control (untreated soil). According to the same constants values, the organic fertilizer applied was the lowest one, meanwhile the chemical one was the highest values, the mixture treatments values, however, were in between the chemical and organic treatments. In addition, the 80% of IR gave the best water management in having both high K adsorption from used soil and significant K uptake by corn plant.

Published in	American Journal of Heterocyclic Chemistry (Volume 3, Issue 6)
DOI	10.11648/j.ajhc.20170306.14
Page(s)	78-85
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Kinetic Methods, Potassium Adsorption, Kinetic Models, Power Function Equation

References

[1]	Sparks, D. L. (1985). Kinetics of ionic reactions in clay minerals and soils. Advances in Agronomy. 38: 231-265.
[2]	Amer, F., Bouldin, D. R., and Black, C. A. (1955). Characterization of soil phosphorus by anion exchange resin adsorption and P32equilibration. Plant and soil 6: 391-394
[3]	Sparks, D. L. (1989). Kinetics of soil chemical processes. Academic Press, San Diego, CA
[4]	Harter R. D. and Lehmann, R. G. (1983) Use of kinetics for the study of exchange reactions in soils. Soil Sci. Soc. Am. J.
[5]	Jardine, P. M., and Sparks, D. L. (1984). Potassium - Calcium exchange in the multi-reactive soil system. I. Kinetics. Soil Sci. Soc. Am. J. 48:39- 45.1208.
[6]	Sparks, D. L. and Huang P. M. (1985). Physical chemistry of soil potassium. Munson, R. D. (ed.) Potassium in Agriculture. Am. SOC. Agronomy, Madison. pp. 201-276.
[7]	Sparks, D. L. (1986). Kinetics of reactions in pure and in mixed systems. In “Soil physical chemistry” (D. L. Sparks, ed.), pp 83 - 178 CRC press, Boca Raton, Florida
[8]	Sparks, D. L. (1988). Kinetics of Soil Chemical Processes. Academic Press, San Diego. pp. 4-38.
[9]	Römheld, V. and Kirkby, E. A. (2010). Research on potassium in agriculture: needs and prospects. Plant Soil 335, 155–180
[10]	Zörb, C., Senbayram, M. and Peiter, E. (2014). Potassium in agriculture – status and perspectives. J. Plant Physiol. 171, 656–669
[11]	Prakash, V., Kundu, S., Ghosh, B. N., Singh, R. D. and Gupta, H. S. (2002). Yield response of soybean (Glycine max) and wheat (Triticumaestivum) to potassium and changes of potassium status in soil after long-term sequential cropping. Indian J. Agri. Sci. 72, 514–518
[12]	Kulcheski, F. R., Côrrea, R., Gomes, I. A., de Lima, J. C. and Margis R. (2015). NPK macronutrients and micro RNA homeostasis. Front. Plant Sci. 6, 451
[13]	Wang, H. Y., Cheng, W., Li, T., Zhou, J. M. and Chen, X. Q. (2016). Can non-exchangeable potassium be differentiated from structural potassium in soils? Pedo-sphere 26, 206–215
[14]	Zörb, C., Senbayram, M. and Peiter, E. (2014). Potassium in agriculture – status and perspectives. J. Plant Physiol. 171, 656–669
[15]	Moritsuka, N., Yanai, J. and Kosaki, T. (2004). Possible processes releasing non-exchangeable potassium from the rhizosphere of maize. Plant Soil 258, 261–268
[16]	Sparks, D. L.; Zelazny, L. W., and Matens, D. C. (1980a). Kinetics of potassium exchange in paleudult from the coastal plain of Virginia. Soil Sci. Soc. Am. J., 44:37 - 40.
[17]	Zaghloul, A. M. (2002) Kinetics of potassium adsorption in some soils of Egypt using Electrical Stirred Flow unit (ESFU). Egyptian J. of soil Sci., 42, 463 – 471.
[18]	Wahba, M. M.; Sherine, M. Shehata and Zaghloul, A. M. (2012). Treatment of polluted water by clay minerals to eliminate the heavy metals. International journal of research in management. 2(3) 16:24
[19]	Parker, D. R., D. L. Sparks, G. J. Hendricks, and M. C. Sadusky. (1989). Potassium in Atlantic Coastal Plain Soils. I. Soil characterization and distribution of potassium. Soil Sci. Soc. Am. J. 53:392-396.
[20]	Sikora, F. J., Copeland, J. P.; Mullins, G. L., and Bartos, J. M. (1991). Phosphorus dissolution kinetics and bioavailability of water-insoluble fractions from mono-ammonium phosphate fertilizers. Soil Sci. Soc. Am. J., 55:362–36
[21]	Cottenie, A.; Verlea, M.; Krekens, L.; Velghe, G., and Bcamerlynck, R. (1982). Chemical analysis of plant and soils Lab. Anal. Agroch. Fac. Agric. State University Gent., Belgium.
[22]	SAS Institute, (1985) SAS user’s guide, Statistics, Version 5 ed. SAS Ins., Cary, NC.
[23]	FAO. (1992). Agro-Meteorological Data Systems, FAO, Rome
[24]	Allen, R. G, Pereira, L. S., Raes, D. and Smith, m., (1998). Crop evaporate transpiration - Guidelines for computing crop water requirements - FAO Irrigation and drainage paper 56, FAO, Rome.
[25]	Raven, K. P., and Hossner, L. R. (1994). Soil phosphorus desorption kinetics and its relationship with plant growth. Soil Sci. Soc. Am. J., 58: 416 – 423
[26]	Cooke, G. W. (1970). The control of soil fertility. The English Language Book Society and Crosby Lockwood & son LTD 26 old Brompton Boad. London. SW7
[27]	Elkhatib, E. A., and Hern, J. L. (1993). Kinetics of phosphorus desorption from Appalachian soils. Soil Sci., 145: 222 - 229.
[28]	Chien, S. H. and Clayton, W. R. (1979). Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Sci. Soc. Am. J. 44: 265-268
[29]	Barbagelata, P. A. and Mallarino, A. P. (2013). Field correlation of potassium soil test methods based on dried and field-moist soil samples for corn and soybean. Soil Sci. Soc. Am. J. 77, 318–327
[30]	Holland, J., Conyers, M., Orchard, B. and Poile, G. (2014). Soil potassium relationships, uptake efficiency and availability for six distinctive soils incentral and southern New South Wales, Australia. Soil Res. 52, 129–139
[31]	Hosseinpur, A. R. and Motaghian, H. R. (2013). Application of kinetic models in describing soil potassium release characteristics and their correlations with extracted by chemical methods. Pedo-sphere 23, 482–492
[32]	Ting Li1, Huoyan Wang1, Zijun Zhou, Xiaoqin Chen and Jianmin Zhou1. (2016). A new grading system for plant available potassium using exhaustive cropping techniques combined with chemical analyses of soils. Scientific Reports 6, Article number: 37327

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APA Style

Monier Morad Wahba, Amal M. Aziz, Alaa M. Zaghloul. (2017). Evaluation of Kinetic Approach in Describing Potassium Bioavailability. American Journal of Heterocyclic Chemistry, 3(6), 78-85. https://doi.org/10.11648/j.ajhc.20170306.14

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ACS Style

Monier Morad Wahba; Amal M. Aziz; Alaa M. Zaghloul. Evaluation of Kinetic Approach in Describing Potassium Bioavailability. Am. J. Heterocycl. Chem. 2017, 3(6), 78-85. doi: 10.11648/j.ajhc.20170306.14

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AMA Style

Monier Morad Wahba, Amal M. Aziz, Alaa M. Zaghloul. Evaluation of Kinetic Approach in Describing Potassium Bioavailability. Am J Heterocycl Chem. 2017;3(6):78-85. doi: 10.11648/j.ajhc.20170306.14

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@article{10.11648/j.ajhc.20170306.14,
  author = {Monier Morad Wahba and Amal M. Aziz and Alaa M. Zaghloul},
  title = {Evaluation of Kinetic Approach in Describing Potassium Bioavailability},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {3},
  number = {6},
  pages = {78-85},
  doi = {10.11648/j.ajhc.20170306.14},
  url = {https://doi.org/10.11648/j.ajhc.20170306.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20170306.14},
  abstract = {The objective of this study was to determine the potassium (K) release kinetics of sandy soil sample representative soil of Egyptian new reclaimed areas as affected by treatments of different rates of compost and chemical fertilizers applied individually or mixture of both type sand the effect of two irrigation regimes i.e. 80 and 60% of water requirements IR. Four mathematical models (power function, Elovich, parabolic diffusion and first-order) were used to fitted the data describe K desorption reactions involving 168-hr cumulative reaction time. Comparison of the models using the coefficient of determination (r2) and the standard error of the estimate (SE) indicated that the Elovich and the power function equations overall displayed the best fitted ones. The first-order rate and for less extent, parabolic diffusion equation were less fitted to describe the kinetic data. The constants of the best fitted models represent the rate of K release indicated that all treatments applied to soil gave high and significant increase in rate of K release compared to the control (untreated soil). According to the same constants values, the organic fertilizer applied was the lowest one, meanwhile the chemical one was the highest values, the mixture treatments values, however, were in between the chemical and organic treatments. In addition, the 80% of IR gave the best water management in having both high K adsorption from used soil and significant K uptake by corn plant.},
 year = {2017}
}

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TY  - JOUR
T1  - Evaluation of Kinetic Approach in Describing Potassium Bioavailability
AU  - Monier Morad Wahba
AU  - Amal M. Aziz
AU  - Alaa M. Zaghloul
Y1  - 2017/12/26
PY  - 2017
N1  - https://doi.org/10.11648/j.ajhc.20170306.14
DO  - 10.11648/j.ajhc.20170306.14
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 78
EP  - 85
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20170306.14
AB  - The objective of this study was to determine the potassium (K) release kinetics of sandy soil sample representative soil of Egyptian new reclaimed areas as affected by treatments of different rates of compost and chemical fertilizers applied individually or mixture of both type sand the effect of two irrigation regimes i.e. 80 and 60% of water requirements IR. Four mathematical models (power function, Elovich, parabolic diffusion and first-order) were used to fitted the data describe K desorption reactions involving 168-hr cumulative reaction time. Comparison of the models using the coefficient of determination (r2) and the standard error of the estimate (SE) indicated that the Elovich and the power function equations overall displayed the best fitted ones. The first-order rate and for less extent, parabolic diffusion equation were less fitted to describe the kinetic data. The constants of the best fitted models represent the rate of K release indicated that all treatments applied to soil gave high and significant increase in rate of K release compared to the control (untreated soil). According to the same constants values, the organic fertilizer applied was the lowest one, meanwhile the chemical one was the highest values, the mixture treatments values, however, were in between the chemical and organic treatments. In addition, the 80% of IR gave the best water management in having both high K adsorption from used soil and significant K uptake by corn plant.
VL  - 3
IS  - 6
ER  -

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Author Information

Monier Morad Wahba

Soils and Water Use Department, Agricultural Division, National Research Centre, Cairo, Egypt
Amal M. Aziz

Soils and Water Use Department, Agricultural Division, National Research Centre, Cairo, Egypt
Alaa M. Zaghloul

Soils and Water Use Department, Agricultural Division, National Research Centre, Cairo, Egypt

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APA Style

Monier Morad Wahba, Amal M. Aziz, Alaa M. Zaghloul. (2017). Evaluation of Kinetic Approach in Describing Potassium Bioavailability. American Journal of Heterocyclic Chemistry, 3(6), 78-85. https://doi.org/10.11648/j.ajhc.20170306.14

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ACS Style

Monier Morad Wahba; Amal M. Aziz; Alaa M. Zaghloul. Evaluation of Kinetic Approach in Describing Potassium Bioavailability. Am. J. Heterocycl. Chem. 2017, 3(6), 78-85. doi: 10.11648/j.ajhc.20170306.14

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AMA Style

Monier Morad Wahba, Amal M. Aziz, Alaa M. Zaghloul. Evaluation of Kinetic Approach in Describing Potassium Bioavailability. Am J Heterocycl Chem. 2017;3(6):78-85. doi: 10.11648/j.ajhc.20170306.14

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@article{10.11648/j.ajhc.20170306.14,
  author = {Monier Morad Wahba and Amal M. Aziz and Alaa M. Zaghloul},
  title = {Evaluation of Kinetic Approach in Describing Potassium Bioavailability},
  journal = {American Journal of Heterocyclic Chemistry},
  volume = {3},
  number = {6},
  pages = {78-85},
  doi = {10.11648/j.ajhc.20170306.14},
  url = {https://doi.org/10.11648/j.ajhc.20170306.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20170306.14},
  abstract = {The objective of this study was to determine the potassium (K) release kinetics of sandy soil sample representative soil of Egyptian new reclaimed areas as affected by treatments of different rates of compost and chemical fertilizers applied individually or mixture of both type sand the effect of two irrigation regimes i.e. 80 and 60% of water requirements IR. Four mathematical models (power function, Elovich, parabolic diffusion and first-order) were used to fitted the data describe K desorption reactions involving 168-hr cumulative reaction time. Comparison of the models using the coefficient of determination (r2) and the standard error of the estimate (SE) indicated that the Elovich and the power function equations overall displayed the best fitted ones. The first-order rate and for less extent, parabolic diffusion equation were less fitted to describe the kinetic data. The constants of the best fitted models represent the rate of K release indicated that all treatments applied to soil gave high and significant increase in rate of K release compared to the control (untreated soil). According to the same constants values, the organic fertilizer applied was the lowest one, meanwhile the chemical one was the highest values, the mixture treatments values, however, were in between the chemical and organic treatments. In addition, the 80% of IR gave the best water management in having both high K adsorption from used soil and significant K uptake by corn plant.},
 year = {2017}
}

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TY  - JOUR
T1  - Evaluation of Kinetic Approach in Describing Potassium Bioavailability
AU  - Monier Morad Wahba
AU  - Amal M. Aziz
AU  - Alaa M. Zaghloul
Y1  - 2017/12/26
PY  - 2017
N1  - https://doi.org/10.11648/j.ajhc.20170306.14
DO  - 10.11648/j.ajhc.20170306.14
T2  - American Journal of Heterocyclic Chemistry
JF  - American Journal of Heterocyclic Chemistry
JO  - American Journal of Heterocyclic Chemistry
SP  - 78
EP  - 85
PB  - Science Publishing Group
SN  - 2575-5722
UR  - https://doi.org/10.11648/j.ajhc.20170306.14
AB  - The objective of this study was to determine the potassium (K) release kinetics of sandy soil sample representative soil of Egyptian new reclaimed areas as affected by treatments of different rates of compost and chemical fertilizers applied individually or mixture of both type sand the effect of two irrigation regimes i.e. 80 and 60% of water requirements IR. Four mathematical models (power function, Elovich, parabolic diffusion and first-order) were used to fitted the data describe K desorption reactions involving 168-hr cumulative reaction time. Comparison of the models using the coefficient of determination (r2) and the standard error of the estimate (SE) indicated that the Elovich and the power function equations overall displayed the best fitted ones. The first-order rate and for less extent, parabolic diffusion equation were less fitted to describe the kinetic data. The constants of the best fitted models represent the rate of K release indicated that all treatments applied to soil gave high and significant increase in rate of K release compared to the control (untreated soil). According to the same constants values, the organic fertilizer applied was the lowest one, meanwhile the chemical one was the highest values, the mixture treatments values, however, were in between the chemical and organic treatments. In addition, the 80% of IR gave the best water management in having both high K adsorption from used soil and significant K uptake by corn plant.
VL  - 3
IS  - 6
ER  -

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