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MSB - 3-Methyl-3-Sulfanylbutan-1-Ol Extraction Its Esterification with Citric Acid and PPCA Materials Synthesis

The 3-methyl-3-sulfanylbutan-1-ol (MSB) is a thiol molecule which could be used as food additive flavor agent and encountered in the white wine, in the coffee perfume, in the passion fruit and in the cat urine where it’s the responsible of its strong odor characteristics. Thus, this manuscript treated first the valorization of the cat-litters by extracting their MSB molecules using the ethanol-90° solvent. The number of the extraction per sample, its duration and the rinse cycle number are three factors influencing the extraction efficiency. In any case, the ethanol-90° extraction of the MSB molecule is interesting and allow to recover an MSB solution which concentration was deduced by the sulfur titration according to a BaCl2 precipitation procedure. Then, the second part of this manuscript treated the study of the esterification-addition reaction between the citric acid molecules and the MSB molecules. A titration procedure was established allowing to follow the sulfur concentration during this esterification-addition reaction. The results of these experimentations permitted not only to establish a kinetic study of this reaction but also to purpose some reactional mechanism where it was discovered that the sulfur atom of the MSB molecule play a fundamental role during this citric acid esterification reaction. Additionally, the kinetic parameters indicated that the protonic acid H+ concentration, the citric acid concentration and the MSB molecule concentration influenced the speed of this esterification reaction between the citric acid molecules and the MSB molecules. Finally, using the results and experimental conditions of the esterification reaction, the third part of this manuscript was dedicated to the synthesis of a material based on black citric acid polymers (pn), pozzolana and citric acid named PPCA (pn-pozzolana-citric-acid) which could play the role of a cat-litter.

PPCA, 3-Methyl-3-Sulfanylbutan-1-ol (MSB), Citric Acid, Esterification, Acid Sites, Basic Sites

APA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, et al. (2023). MSB - 3-Methyl-3-Sulfanylbutan-1-Ol Extraction Its Esterification with Citric Acid and PPCA Materials Synthesis. American Journal of Applied and Industrial Chemistry, 7(2), 25-37. https://doi.org/10.11648/j.ajaic.20230702.11

ACS Style

Andry Tahina Rabeharitsara; Henri Rakotondrina; Nambinina Richard Randriana; Soloniaina Rakotoarijaona; Hanitraniaina Marie Ratsimba, et al. MSB - 3-Methyl-3-Sulfanylbutan-1-Ol Extraction Its Esterification with Citric Acid and PPCA Materials Synthesis. Am. J. Appl. Ind. Chem. 2023, 7(2), 25-37. doi: 10.11648/j.ajaic.20230702.11

AMA Style

Andry Tahina Rabeharitsara, Henri Rakotondrina, Nambinina Richard Randriana, Soloniaina Rakotoarijaona, Hanitraniaina Marie Ratsimba, et al. MSB - 3-Methyl-3-Sulfanylbutan-1-Ol Extraction Its Esterification with Citric Acid and PPCA Materials Synthesis. Am J Appl Ind Chem. 2023;7(2):25-37. doi: 10.11648/j.ajaic.20230702.11

Copyright © 2023 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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2. Rabeharitsara Andry Tahina, Raharilaza Paulin Merix, Randriana Richard Nambinina – Chemical Process Engineering Department (E. S. P. A), Antananarivo University – Madagascar – “Esterification Between Citric Acid and Pumpkin Pips’ Organic Molecules – Esters Hydrolysis and Esters Used as Hydrocarbons Additives” - American Journal of Applied Chemistry in Vol. 6, Issue Number 3, June 2018. doi: 10.11648/j.ajac.20180603.12.
3. Raharilaza Paulin Merix - "Estérification entre les molécules d’acide citrique et les molécules organiques des graines de courges - hydrolyse et valorisations des esters comme additifs des hydrocarbures" – [Esterification between citric acid molecules and organic molecules of pumpkin seeds - hydrolysis and valuation of esters as hydrocarbon additives] - Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en Génie Chimique. E. S. P. A. Université d’Antananarivo. Promotion 2017.
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