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Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis

Received: 14 November 2014     Accepted: 11 January 2015     Published: 28 January 2015
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Abstract

Due to fast industrialization the consumption as well as the cost of fossil fuels like petrol, diesel etc in the world is rising enormously leading to the generation of greenhouse gases like carbon monoxide, carbon dioxide etc besides decreasing the availability of the above fuels. The emission of these greenhouse gases rises the globe’s temperature leading the earth to face many dangerous complications. In order to save the earth from effect of rise of temperature and also to have an eco-friendly alternate energy fuel especially for the transport sector, attention is being focused on the generation of hydrogen gas which meets the above situations. During the combustion of hydrogen gas it emits only the beneficial water vapour to the atmosphere. In this research paper investigation has been carried out through CuCl-HCl electrolysis with 1M CuCl anolyte and 6M HCl catholyte for the generation of hydrogen gas at 70oC at normal atmospheric pressure employing a double compartment electrolytic cell having a nafion cation exchange membrane-324. Anode was graphite and cathode was 0.30 mg cm-2 platinum coated graphite. At a current density of 250 A m-2 the current efficiency for the oxidation of CuCl to CuCl2 and the formation of hydrogen gas was nearly 100% and the rate of hydrogen liberation was found to be 2 l h-1. Voltage efficiency and energy consumption values are calculated and are found to be more encouraging since they are more economical with less energy operation. The formed CuCl2 was reduced back to CuCl anolyte by chemical reduction with copper powder in 6M HCl at 70oC and the regenerated CuCl anolyte was again used in the CuCl-HCl electrolysis.

Published in International Journal of Energy and Power Engineering (Volume 4, Issue 1)
DOI 10.11648/j.ijepe.20150401.13
Page(s) 15-22
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Cuprous Chloride-Hydrochloric Acid, Nafion Cation Exchange Membrane-324, Divided Cell, Graphite, Platinum Coated Graphite, Hydrogen Gas, Cupric Chloride

References
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    Natarajan Sathaiyan, Venkataraman Nandakumar, Ganapathy Sozhan, Jegan Gandhibha Packiaraj, Elumalai Thambuswamy Devakumar, et al. (2015). Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis. International Journal of Energy and Power Engineering, 4(1), 15-22. https://doi.org/10.11648/j.ijepe.20150401.13

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    ACS Style

    Natarajan Sathaiyan; Venkataraman Nandakumar; Ganapathy Sozhan; Jegan Gandhibha Packiaraj; Elumalai Thambuswamy Devakumar, et al. Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis. Int. J. Energy Power Eng. 2015, 4(1), 15-22. doi: 10.11648/j.ijepe.20150401.13

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    AMA Style

    Natarajan Sathaiyan, Venkataraman Nandakumar, Ganapathy Sozhan, Jegan Gandhibha Packiaraj, Elumalai Thambuswamy Devakumar, et al. Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis. Int J Energy Power Eng. 2015;4(1):15-22. doi: 10.11648/j.ijepe.20150401.13

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  • @article{10.11648/j.ijepe.20150401.13,
      author = {Natarajan Sathaiyan and Venkataraman Nandakumar and Ganapathy Sozhan and Jegan Gandhibha Packiaraj and Elumalai Thambuswamy Devakumar and Damaraju Parvatalu and Anil Bhardwaj and Bantwal Narayana Prabhu},
      title = {Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis},
      journal = {International Journal of Energy and Power Engineering},
      volume = {4},
      number = {1},
      pages = {15-22},
      doi = {10.11648/j.ijepe.20150401.13},
      url = {https://doi.org/10.11648/j.ijepe.20150401.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.20150401.13},
      abstract = {Due to fast industrialization the consumption as well as the cost of fossil fuels like petrol, diesel etc in the world is rising enormously leading to the generation of greenhouse gases like carbon monoxide, carbon dioxide etc besides decreasing the availability of the above fuels. The emission of these greenhouse gases rises the globe’s temperature leading the earth to face many dangerous complications. In order to save the earth from effect of rise of temperature and also to have an eco-friendly alternate energy fuel especially for the transport sector, attention is being focused on the generation of hydrogen gas which meets the above situations. During the combustion of hydrogen gas it emits only the beneficial water vapour to the atmosphere. In this research paper investigation has been carried out through CuCl-HCl electrolysis with 1M CuCl anolyte and 6M HCl catholyte for the generation of hydrogen gas at 70oC at normal atmospheric pressure employing a double compartment electrolytic cell having a nafion cation exchange membrane-324. Anode was graphite and cathode was 0.30 mg cm-2 platinum coated graphite. At a current density of 250 A m-2 the current efficiency for the oxidation of CuCl to CuCl2 and the formation of hydrogen gas was nearly 100% and the rate of hydrogen liberation was found to be 2 l h-1. Voltage efficiency and energy consumption values are calculated and are found to be more encouraging since they are more economical with less energy operation. The formed CuCl2 was reduced back to CuCl anolyte by chemical reduction with copper powder in 6M HCl at 70oC and the regenerated CuCl anolyte was again used in the CuCl-HCl electrolysis.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Hydrogen Generation through Cuprous Chloride-Hydrochloric Acid Electrolysis
    AU  - Natarajan Sathaiyan
    AU  - Venkataraman Nandakumar
    AU  - Ganapathy Sozhan
    AU  - Jegan Gandhibha Packiaraj
    AU  - Elumalai Thambuswamy Devakumar
    AU  - Damaraju Parvatalu
    AU  - Anil Bhardwaj
    AU  - Bantwal Narayana Prabhu
    Y1  - 2015/01/28
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ijepe.20150401.13
    DO  - 10.11648/j.ijepe.20150401.13
    T2  - International Journal of Energy and Power Engineering
    JF  - International Journal of Energy and Power Engineering
    JO  - International Journal of Energy and Power Engineering
    SP  - 15
    EP  - 22
    PB  - Science Publishing Group
    SN  - 2326-960X
    UR  - https://doi.org/10.11648/j.ijepe.20150401.13
    AB  - Due to fast industrialization the consumption as well as the cost of fossil fuels like petrol, diesel etc in the world is rising enormously leading to the generation of greenhouse gases like carbon monoxide, carbon dioxide etc besides decreasing the availability of the above fuels. The emission of these greenhouse gases rises the globe’s temperature leading the earth to face many dangerous complications. In order to save the earth from effect of rise of temperature and also to have an eco-friendly alternate energy fuel especially for the transport sector, attention is being focused on the generation of hydrogen gas which meets the above situations. During the combustion of hydrogen gas it emits only the beneficial water vapour to the atmosphere. In this research paper investigation has been carried out through CuCl-HCl electrolysis with 1M CuCl anolyte and 6M HCl catholyte for the generation of hydrogen gas at 70oC at normal atmospheric pressure employing a double compartment electrolytic cell having a nafion cation exchange membrane-324. Anode was graphite and cathode was 0.30 mg cm-2 platinum coated graphite. At a current density of 250 A m-2 the current efficiency for the oxidation of CuCl to CuCl2 and the formation of hydrogen gas was nearly 100% and the rate of hydrogen liberation was found to be 2 l h-1. Voltage efficiency and energy consumption values are calculated and are found to be more encouraging since they are more economical with less energy operation. The formed CuCl2 was reduced back to CuCl anolyte by chemical reduction with copper powder in 6M HCl at 70oC and the regenerated CuCl anolyte was again used in the CuCl-HCl electrolysis.
    VL  - 4
    IS  - 1
    ER  - 

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Author Information
  • Electro Hydro Metallurgy Division, CSIR-Central Electro-Chemical Research Institute, Karaikudi, India

  • Electro Hydro Metallurgy Division, CSIR-Central Electro-Chemical Research Institute, Karaikudi, India

  • Electro Inorganic Chemicals Division, CSIR-Central Electro-Chemical Research Institute, Karaikudi, India

  • Electro Hydro Metallurgy Division, CSIR-Central Electro-Chemical Research Institute, Karaikudi, India

  • Electro Hydro Metallurgy Division, CSIR-Central Electro-Chemical Research Institute, Karaikudi, India

  • ONGC Energy Centre, IEOT, Panvel, Navi Mumbai, India

  • ONGC Energy Centre, IEOT, Panvel, Navi Mumbai, India

  • ONGC Energy Centre, IEOT, Panvel, Navi Mumbai, India

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