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A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor

Received: 25 January 2017     Accepted: 24 February 2017     Published: 25 April 2017
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Abstract

The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.

Published in European Journal of Clinical and Biomedical Sciences (Volume 3, Issue 2)
DOI 10.11648/j.ejcbs.20170302.12
Page(s) 47-52
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Sodium Saccharin, Nano-Sensor, Cyclic Voltammetry, Different Temperature, Thermodynamic Parameters, Non-aqueous Electrolyte

References
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[9] Romman, U. K. R., K. M. A. Malik and S. Z. Haider. 1999. Synthesis, Characterization and Properties of some Saccharine Complex Containing 2,2’-bipyridine as Secondary Ligand. J. Bangladesh Acad. Sci. 23(2): 155.
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Cite This Article
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    Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. (2017). A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. European Journal of Clinical and Biomedical Sciences, 3(2), 47-52. https://doi.org/10.11648/j.ejcbs.20170302.12

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    ACS Style

    Muhammed Mizher Radhi; Yousif A. Kadium; Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur. J. Clin. Biomed. Sci. 2017, 3(2), 47-52. doi: 10.11648/j.ejcbs.20170302.12

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    AMA Style

    Muhammed Mizher Radhi, Yousif A. Kadium, Anfal Ismael Ibrahim. A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor. Eur J Clin Biomed Sci. 2017;3(2):47-52. doi: 10.11648/j.ejcbs.20170302.12

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  • @article{10.11648/j.ejcbs.20170302.12,
      author = {Muhammed Mizher Radhi and Yousif A. Kadium and Anfal Ismael Ibrahim},
      title = {A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor},
      journal = {European Journal of Clinical and Biomedical Sciences},
      volume = {3},
      number = {2},
      pages = {47-52},
      doi = {10.11648/j.ejcbs.20170302.12},
      url = {https://doi.org/10.11648/j.ejcbs.20170302.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ejcbs.20170302.12},
      abstract = {The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - A Study of Electrochemical Behavior for Redox Current Peaks of Sodium Saccharin at Different Temperature Using Nano-Sensor
    AU  - Muhammed Mizher Radhi
    AU  - Yousif A. Kadium
    AU  - Anfal Ismael Ibrahim
    Y1  - 2017/04/25
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ejcbs.20170302.12
    DO  - 10.11648/j.ejcbs.20170302.12
    T2  - European Journal of Clinical and Biomedical Sciences
    JF  - European Journal of Clinical and Biomedical Sciences
    JO  - European Journal of Clinical and Biomedical Sciences
    SP  - 47
    EP  - 52
    PB  - Science Publishing Group
    SN  - 2575-5005
    UR  - https://doi.org/10.11648/j.ejcbs.20170302.12
    AB  - The study of Sodium Saccharin (NaSc), this one of the chemical compounds was used as a replacement for natural sugar, which taking by diabetic patients. NaSc was studied by cyclic voltammetric technique to analysis at different temperature using modified glassy carbon electrode (GCE) with carbon nanotubes (CNT) as working electrode (CNT/GCE). Activation energy (Ea*) of NaSc was studied in 1M Na2SO4 as an electrolyte at different temperature using Arrhenius equation at both GCE and CNT/GCE. Other thermodynamic parameters such as activation free energy (∆G*), activation enthalpy (∆H*) and activation entropy (∆S*) were determined at both GCE and CNT/GCE using Eyring equation. Other thermodynamic parameters such as the values of entropy for cathodic current peak of NaSc on GCE and CNT/GCE are positive value, this means that the reaction is spontaneous reversible, but the negative values of entropy is irreversible reaction.
    VL  - 3
    IS  - 2
    ER  - 

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Author Information
  • Radiological Techniques Department, Health and Medical Technology College-Baghdad, Middle Technology University, Baghdad, Iraq

  • Chemistry Department, Science College, Al-Mustansiriyah University, Baghdad, Iraq

  • Chemistry Department, Science College, Al-Mustansiriyah University, Baghdad, Iraq

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