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Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite

Received: 7 September 2016     Accepted: 21 September 2016     Published: 11 October 2016
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Abstract

Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.

Published in Advances in Materials (Volume 5, Issue 5)
DOI 10.11648/j.am.20160505.14
Page(s) 51-56
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Lithium-Silicate Glasses, Glass-Ceramics, Sulfur Doped Glasses, Solid Batteries, Glass Cathode, Mössbauer Spectroscopy, X-ray Diffraction, Fourier-Transform Infrared, DC Electrical Conductivity

References
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Cite This Article
  • APA Style

    M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. (2016). Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Advances in Materials, 5(5), 51-56. https://doi.org/10.11648/j.am.20160505.14

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    ACS Style

    M. Y. Hassaan; H. H. El-Bahnasawy; S. M. Salem; T. Z. Amer; M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv. Mater. 2016, 5(5), 51-56. doi: 10.11648/j.am.20160505.14

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    AMA Style

    M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv Mater. 2016;5(5):51-56. doi: 10.11648/j.am.20160505.14

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  • @article{10.11648/j.am.20160505.14,
      author = {M. Y. Hassaan and H. H. El-Bahnasawy and S. M. Salem and T. Z. Amer and M. G. Moustafa and A. G. Mostafa},
      title = {Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite},
      journal = {Advances in Materials},
      volume = {5},
      number = {5},
      pages = {51-56},
      doi = {10.11648/j.am.20160505.14},
      url = {https://doi.org/10.11648/j.am.20160505.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20160505.14},
      abstract = {Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.},
     year = {2016}
    }
    

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    T1  - Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite
    AU  - M. Y. Hassaan
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    JO  - Advances in Materials
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    AB  - Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.
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Author Information
  • Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

  • Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

  • Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

  • Phys. Department, Faculty of Science, Al-Azhar University, (Girls Branch) Nasr City, Cairo, Egypt

  • Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

  • Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

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