Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.
Published in | American Journal of Heterocyclic Chemistry (Volume 4, Issue 1) |
DOI | 10.11648/j.ajhc.20180401.12 |
Page(s) | 22-25 |
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Copyright © The Author(s), 2018. Published by Science Publishing Group |
Complex Compounds, Ruthenium, Nicotinic Acid Amide, Donor Ligands, Palladium
[1] | Raevskaya MV: Physicochemistry of ruthenium and its alloys / MV Raevskaya // Chemistry of ruthenium, rhodium, palladium, osmium, iridium, platinum, per. With the English. M.: 1979.-P. 138-140. |
[2] | Brockhaus F. A. Encyclopedic Dictionary Brockhaus and I. A. Efron / F. A. Brockhaus, I. A. Efron. - S.-Pb.: Brockhaus - Efron, 1890-1907.-347 p. |
[3] | Prokhorov A. M. Physical encyclopedia in 5 volumes / А. М. Prokhorov, Moscow: Soviet Encyclopedia. Editor-in-chief A. M. Prokhorov. - Volume 3, p. 317-319. |
[4] | Sokolov I. V. Popular library of chemical elements / I. V. Petryanov-Sokolov // Moscow: Nauka Publishers, 1963. pp. 83-86. |
[5] | M. Cavazzini, S. Quici, C. Scalera, F. Puntoriero, G. La Ganga, S. Campagna. Synthesis, characterization, absorption spectra, and luminescence properties of multinuclear species made of Ru (II) and Ir (III) chromophores. // Inorg. Chem.-2009.-V. 48.-P. 8578-8592. |
[6] | R. Lalrempuia, M. R. Kollipara. Rectivity studies of η6-arene ruthenium (II) dimers with polypyridyl ligands: isolation of mono, binuclear p- cymene ruthenium (II) complexes and bisterpyridine ruthenium (II) complexes. //Polyhedron-2003.-V. 22.-P. 3155-316. |
[7] | C. Mikel, P. G. Potvin. Synthesis and enhanced photosensitization ability of a 4-carboxy-2, 2′:6′, 2″- terpyridine complex of ruthenium (II)// Polyhedron-2002.-V. 21.-P. 49-54. |
[8] | J. Mola, E. Mas-Marza, X. Sala, I. Romero, M. Rodriguez, C. Vinas, T. Parella, A. Llobet. Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports. // Angew. Chem. Int. Ed.-2008.-V. 47.-P. 5830-5832. |
[9] | M. Agaguseynova, N. E. Jabbarova Coordination compounds of transition metals in catalysis.// Chem. Soc. Commun. Baku-2006 -p. 129-135. |
[10] | M. Agaguseynova, N. E. Jabbarova Complexes of transition metals with molecular oxygen.// Chem. Soc. Commun. Baku-2012 -p. 96-111. |
APA Style
Mikayilova Mexriban Rahil, Mustafayeva Rena Eldar. (2018). Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. American Journal of Heterocyclic Chemistry, 4(1), 22-25. https://doi.org/10.11648/j.ajhc.20180401.12
ACS Style
Mikayilova Mexriban Rahil; Mustafayeva Rena Eldar. Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. Am. J. Heterocycl. Chem. 2018, 4(1), 22-25. doi: 10.11648/j.ajhc.20180401.12
AMA Style
Mikayilova Mexriban Rahil, Mustafayeva Rena Eldar. Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. Am J Heterocycl Chem. 2018;4(1):22-25. doi: 10.11648/j.ajhc.20180401.12
@article{10.11648/j.ajhc.20180401.12, author = {Mikayilova Mexriban Rahil and Mustafayeva Rena Eldar}, title = {Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry}, journal = {American Journal of Heterocyclic Chemistry}, volume = {4}, number = {1}, pages = {22-25}, doi = {10.11648/j.ajhc.20180401.12}, url = {https://doi.org/10.11648/j.ajhc.20180401.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20180401.12}, abstract = {Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.}, year = {2018} }
TY - JOUR T1 - Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry AU - Mikayilova Mexriban Rahil AU - Mustafayeva Rena Eldar Y1 - 2018/01/29 PY - 2018 N1 - https://doi.org/10.11648/j.ajhc.20180401.12 DO - 10.11648/j.ajhc.20180401.12 T2 - American Journal of Heterocyclic Chemistry JF - American Journal of Heterocyclic Chemistry JO - American Journal of Heterocyclic Chemistry SP - 22 EP - 25 PB - Science Publishing Group SN - 2575-5722 UR - https://doi.org/10.11648/j.ajhc.20180401.12 AB - Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies. VL - 4 IS - 1 ER -