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Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw

Received: 29 January 2017     Accepted: 14 February 2017     Published: 2 March 2017
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Abstract

In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.

Published in Petroleum Science and Engineering (Volume 1, Issue 1)
DOI 10.11648/j.pse.20170101.14
Page(s) 17-22
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Kinetics, Isotherm, Modified Wheat Straw

References
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[2] S. Jassim, H. Al-Robai, and M. Al-Taee, “Removing Reactive Orange Dye By Using Ceramic Purifier Type (AKPL1),” uobabylon.edu.iq, vol. 50, pp. 121–127, 2013.
[3] P. Pilipenko, “Cationic Polyelectrolytes as Primary Coagulants for Municipal Wastewater Treatment,” 2007.
[4] V. Correia, T. Stephenson, and S. Judd, “Characterisation of textile wastewaters‐a review,” Environ. Technol., 1994.
[5] R. H. Salman, “REMOVAL OF DYES FROM TEXTILE EFFLUENT BY ADSORPTION ONTO OVEN DRIED ALUM SLUDGE,” J. Eng., vol. 6, no. 2, 2010.
[6] A. Itodo, F. Abdulrahman, L. Hassan, and S. Maigandi, “Intraparticle diffusion and intraparticulate diffusivities of herbicide on derived activated carbon,” Researcher, 2010.
[7] V. J. Inglezakis and S. G. Poulopoulos, “Adsorption, Ion Exchange and Catalysis: Design of Operations and Environmental Applications,” Elsevier Sci. B V, p. 602, 2006.
[8] Z. Xu, J. Cai, and B. Pan, “Mathematically modeling fixed-bed adsorption in aqueous systems *,” vol. 14, no. 3, pp. 155–176, 2013.
[9] W. J. Thomas and B. Crittenden, Adsorption Technology and Design, no. April. 1998.
[10] R. Ansari, B. Seyghali, and A. Mohammad-Khah, “Highly efficient adsorption of anionic dyes from aqueous solutions using sawdust modified by cationic surfactant of cetyltrimethylammonium bromide,” J. Surfactants, 2012.
[11] Y. Su, Y. Jiao, C. Dou, and R. Han, “Biosorption of methyl orange from aqueous solutions using cationic surfactant-modified wheat straw in batch mode,” Desalination Water Treat., 2014.
[12] A. Pirbazari, E. Saberikhah, and S. Kozani, “Fe3 O4–wheat straw: preparation, characterization and its application for methylene blue adsorption,” Water Resour. Ind., 2014.
[13] S. Kaur, S. Rani, and R. Mahajan, “Adsorption kinetics for the removal of hazardous dye congo red by biowaste materials as adsorbents,” J. Chem., 2012.
[14] M. Yagub, T. Sen, S. Afroze, and H. Ang, “Dye and its removal from aqueous solution by adsorption: a review,” Adv. Colloid Interface, 2014.
[15] Y. Ho, J. Ng, and G. McKay, “Kinetics of pollutant sorption by biosorbents: review,” Sep. Purif. Rev., 2000.
[16] S. Ong, C. Lee, and Z. Zainal, “Removal of basic and reactive dyes using ethylenediamine modified rice hull,” Bioresour. Technol., 2007.
[17] B. Hameed, “Spent tea leaves: a new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions,” J. Hazard. Mater., 2009.
[18] M. Desta, “Batch sorption experiments: Langmuir and Freundlich isotherm studies for the adsorption of textile metal ions onto Teff Straw (Eragrostis tef) agricultural waste,” J. Thermodyn., 2013.
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  • APA Style

    Khalid M. Mousa, Alaa H. Taha. (2017). Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Petroleum Science and Engineering, 1(1), 17-22. https://doi.org/10.11648/j.pse.20170101.14

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    ACS Style

    Khalid M. Mousa; Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet. Sci. Eng. 2017, 1(1), 17-22. doi: 10.11648/j.pse.20170101.14

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    AMA Style

    Khalid M. Mousa, Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet Sci Eng. 2017;1(1):17-22. doi: 10.11648/j.pse.20170101.14

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  • @article{10.11648/j.pse.20170101.14,
      author = {Khalid M. Mousa and Alaa H. Taha},
      title = {Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw},
      journal = {Petroleum Science and Engineering},
      volume = {1},
      number = {1},
      pages = {17-22},
      doi = {10.11648/j.pse.20170101.14},
      url = {https://doi.org/10.11648/j.pse.20170101.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.pse.20170101.14},
      abstract = {In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw
    AU  - Khalid M. Mousa
    AU  - Alaa H. Taha
    Y1  - 2017/03/02
    PY  - 2017
    N1  - https://doi.org/10.11648/j.pse.20170101.14
    DO  - 10.11648/j.pse.20170101.14
    T2  - Petroleum Science and Engineering
    JF  - Petroleum Science and Engineering
    JO  - Petroleum Science and Engineering
    SP  - 17
    EP  - 22
    PB  - Science Publishing Group
    SN  - 2640-4516
    UR  - https://doi.org/10.11648/j.pse.20170101.14
    AB  - In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.
    VL  - 1
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemical Engineering, Al-Nahrain University, Baghdad, Iraq

  • Department of Chemical Engineering, Al-Nahrain University, Baghdad, Iraq

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