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Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial

Received: 12 February 2017     Accepted: 9 March 2017     Published: 29 November 2017
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Abstract

Metallic soap prepared by saponification of melon seed oil (Cucumeropsis mannii N) with copper (II) salt was investigated as corrosion inhibitor for mild steel corrosion in 1 M hydrochloric acid solution. Results reveal that the metallic soap inhibited the corrosion process by spontaneous physical adsorption of the phytochemicals of the seed oil onto the mild steel surface. The highest inhibition efficiency of 82.7% was obtained at 30°C with 10 g/L of the metallic soap, but this efficiency decreased with increase in temperature. The fractional surface coverage data best fitted into Temkin adsorption model which was used to predict the inhibitor-metal binding strength as a function of temperature. Atomic Absorption Spectrophotometric assessment of copper (II) ion composition in the inhibitor afforded a value within the safe limit for health, environment and personnel. Density functional theorem (DFT) studies provided supportive evidence of possible involvement of the fatty acid phyto-components in the adsorption process. The mechanism of inhibition was also predicted by applying the recent temperature coefficient of inhibition efficiency equation.

Published in International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)
DOI 10.11648/j.ogce.20170506.16
Page(s) 158-166
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Adsorption, Bio-Metallic Soap, Melon Seed Oil, Metallic Soap

References
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Cite This Article
  • APA Style

    Ekemini Ituen, James Asuquo, Edidiong Essien. (2017). Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial. International Journal of Oil, Gas and Coal Engineering, 5(6), 158-166. https://doi.org/10.11648/j.ogce.20170506.16

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    ACS Style

    Ekemini Ituen; James Asuquo; Edidiong Essien. Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial. Int. J. Oil Gas Coal Eng. 2017, 5(6), 158-166. doi: 10.11648/j.ogce.20170506.16

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    AMA Style

    Ekemini Ituen, James Asuquo, Edidiong Essien. Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial. Int J Oil Gas Coal Eng. 2017;5(6):158-166. doi: 10.11648/j.ogce.20170506.16

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  • @article{10.11648/j.ogce.20170506.16,
      author = {Ekemini Ituen and James Asuquo and Edidiong Essien},
      title = {Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial},
      journal = {International Journal of Oil, Gas and Coal Engineering},
      volume = {5},
      number = {6},
      pages = {158-166},
      doi = {10.11648/j.ogce.20170506.16},
      url = {https://doi.org/10.11648/j.ogce.20170506.16},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.16},
      abstract = {Metallic soap prepared by saponification of melon seed oil (Cucumeropsis mannii N) with copper (II) salt was investigated as corrosion inhibitor for mild steel corrosion in 1 M hydrochloric acid solution. Results reveal that the metallic soap inhibited the corrosion process by spontaneous physical adsorption of the phytochemicals of the seed oil onto the mild steel surface. The highest inhibition efficiency of 82.7% was obtained at 30°C with 10 g/L of the metallic soap, but this efficiency decreased with increase in temperature. The fractional surface coverage data best fitted into Temkin adsorption model which was used to predict the inhibitor-metal binding strength as a function of temperature. Atomic Absorption Spectrophotometric assessment of copper (II) ion composition in the inhibitor afforded a value within the safe limit for health, environment and personnel. Density functional theorem (DFT) studies provided supportive evidence of possible involvement of the fatty acid phyto-components in the adsorption process. The mechanism of inhibition was also predicted by applying the recent temperature coefficient of inhibition efficiency equation.},
     year = {2017}
    }
    

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    T1  - Inhibition of Steel Corrosion in Simulated Oilfield Acidizing Medium Using Metallic Soap from Local Biomaterial
    AU  - Ekemini Ituen
    AU  - James Asuquo
    AU  - Edidiong Essien
    Y1  - 2017/11/29
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ogce.20170506.16
    DO  - 10.11648/j.ogce.20170506.16
    T2  - International Journal of Oil, Gas and Coal Engineering
    JF  - International Journal of Oil, Gas and Coal Engineering
    JO  - International Journal of Oil, Gas and Coal Engineering
    SP  - 158
    EP  - 166
    PB  - Science Publishing Group
    SN  - 2376-7677
    UR  - https://doi.org/10.11648/j.ogce.20170506.16
    AB  - Metallic soap prepared by saponification of melon seed oil (Cucumeropsis mannii N) with copper (II) salt was investigated as corrosion inhibitor for mild steel corrosion in 1 M hydrochloric acid solution. Results reveal that the metallic soap inhibited the corrosion process by spontaneous physical adsorption of the phytochemicals of the seed oil onto the mild steel surface. The highest inhibition efficiency of 82.7% was obtained at 30°C with 10 g/L of the metallic soap, but this efficiency decreased with increase in temperature. The fractional surface coverage data best fitted into Temkin adsorption model which was used to predict the inhibitor-metal binding strength as a function of temperature. Atomic Absorption Spectrophotometric assessment of copper (II) ion composition in the inhibitor afforded a value within the safe limit for health, environment and personnel. Density functional theorem (DFT) studies provided supportive evidence of possible involvement of the fatty acid phyto-components in the adsorption process. The mechanism of inhibition was also predicted by applying the recent temperature coefficient of inhibition efficiency equation.
    VL  - 5
    IS  - 6
    ER  - 

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Author Information
  • Materials and Oilfield Technology Research Group, Department of Chemistry, University of Uyo, Uyo, Nigeria

  • Materials and Oilfield Technology Research Group, Department of Chemistry, University of Uyo, Uyo, Nigeria

  • Department of Environmental Science, Cyprus International University, Mersin, Turkey

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