| Peer-Reviewed

Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel

Received: 6 May 2015     Accepted: 18 May 2015     Published: 28 May 2015
Views:       Downloads:
Abstract

Synthesis of biodiesel from the beef tallow using catalyst from Psammotaea elongata shell with methanol as a solvent was carried out. Synthesis the biodiesel was prepared in two steps, there are esterification and transesterification. In esterification was conducted in mole ratio of oil and methanol were 1: 9, with H2SO4 as a catalyst. Transesterification process conducted with mole ratio were 1:12 (oil and methanol), with CaO from cockle’ shell as a catalyst with a variation of the catalyst 11%, 12%, 13%, and 14%. Result of biodiesel was characterized based on FT-IR, 1H-NMR, GC-MS, and ASTM (American Standard Testing of Materials) method. The results obtained by the catalyst conversion of 51.9% and the optimum conditions in the biodiesel present in 12%. Yielded of biodiesel theoretically was 59.118% and experiment was 18.34%. The main component on biodiesel product is methyl stearate (40.65%) and examination result of biodiesel by using ASTM method are specific (0.8695 g/cm3), kinematic viscosity (5.393 mm/s2), flame point (178.5 °C), pour point (24 °C), and carbon Condradson residue (0.071%).

Published in International Journal of Materials Science and Applications (Volume 4, Issue 3)
DOI 10.11648/j.ijmsa.20150403.21
Page(s) 219-224
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Biodiesel, CaO, Esterification, Beef Tallow, Transesterification

References
[1] F.R. Ma, M.A. Hanna, “Biodiesel production: a review’’ Bioresour. Technol., 1999, 70: 1-15.
[2] Tesser R, Di Serio M Guida M, Nastasi M, Santacesaria E., “Kinetics of oleic acid esterification with methanol in the presence of triglycerides”, Ind. Eng. Chem. Res. 2005, 44,7978-7982.
[3] Shibasaki-Kitakawa N, Honda H, Kuribayashi H, Toda T, Fukumura T, Yonemoto T., “Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst’’ Bioresour. Technol. 2007, 98:416-421.
[4] Srivastava, A., P. Ram, “Triglycerides-based diesel fuels”, Ren. Sustain. Energy Rev., 2000, 4, 111-133.
[5] Lebedevas, S., Vaicekauskas, A., Lebedeva, G., Makareviciene, V., Janulis, P., and Kazancev, K., “Use of Waste Fats of Animal and Vegetable Origin for The Production of Biodiesel Fuel, Quality, Motor Properties, and Emissions of Harmful Components”, Energy Fuel, 2006, 20, 2274-2280.
[6] Kumar MS, Kerihuel A, Bellettre J, Tazerout M., “Ethanol animal fat emulsions as a diesel engine fuel – part 2: engine test analysis”, Fuel 2006, 85, 2646–52.
[7] Kerihuel A, Kumar MS, Bellettre J, Tazerout M.”Ethanol animal fat emulsions as a diesel engine fuel – part 1: formulations and influential parameters”, Fuel, 2006, 85, 2640-5.
[8] Kim, H. J., Kang, B. S., Kim, M. J., Park, Y. M., Kim, D. K., Lee, J. S., and Lee, K. Y., “Transesterification of Vegetable Oil to Biodiesel Using Heterogeneous Base Catalyst”, Catal. Today, 2004, 93-95, 315-320
[9] Gryglewicz S. “Rapeseed oil methyl esters preparation using heterogeneous catalysts”, Bioresour Technol , 1999,70, 249-53.
[10] Tanabe K, Ho lderich WF, ”Industrial application of solid acid–base catalysts”, Appl. Catal A, 1999, 181,399-434.
[11] Kawashima A, Matsubara K, Honda K, “Acceleration of catalytic activity of calcium oxide for biodiesel production”, Bioresour Technol, 2009,100, 696-700.
[12] Murugesan, A., Umarani, C., Chinnusamy, T. R., Krishnan, M. K., Subramanian, and R., Neduzchezhain, N., “Production and Analysis of Biodiesel from Non-edible Oils – a review”, Renewable and Sustainable Energy Reviews, 2008, 13, 825-834.
[13] Fogler, H. S., “Elements Of Chemical Reaction Engineering”, 1999, Prentice Hall PTR, New Jersey.
[14] R J Fessenden and J S Fessenden, Organic Chemistry (4th edition), Brooks/Cole, California, 1990. pp 1137
[15] Knothe, G., “Monitoring a Progressing Transesterification Reaction by Fiber-Optic Near Infrared Spectroscopy with Correlation to H Nuclear Magnetic Resonance Spectroscopy”, Jpn. Am. Oil. Chem. Soc, 2000, 77, 489-493.
[16] Mittelbach, M., Remschmidt, C., “Biodiesel The Comprehensive Handbook”, 2004, Marthin Mittelbach, Graz, Austria.
[17] Tilani, H. S., Rachman, Y., “Preparation Characteristics of Palm Oil Biodiesel”, Makara, Teknologi, 2002, 6, 2.
Cite This Article
  • APA Style

    I. Wayan Sutapa, A. Bandjar, Rosmawaty, M. Sitaniapessy. (2015). Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel. International Journal of Materials Science and Applications, 4(3), 219-224. https://doi.org/10.11648/j.ijmsa.20150403.21

    Copy | Download

    ACS Style

    I. Wayan Sutapa; A. Bandjar; Rosmawaty; M. Sitaniapessy. Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel. Int. J. Mater. Sci. Appl. 2015, 4(3), 219-224. doi: 10.11648/j.ijmsa.20150403.21

    Copy | Download

    AMA Style

    I. Wayan Sutapa, A. Bandjar, Rosmawaty, M. Sitaniapessy. Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel. Int J Mater Sci Appl. 2015;4(3):219-224. doi: 10.11648/j.ijmsa.20150403.21

    Copy | Download

  • @article{10.11648/j.ijmsa.20150403.21,
      author = {I. Wayan Sutapa and A. Bandjar and Rosmawaty and M. Sitaniapessy},
      title = {Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel},
      journal = {International Journal of Materials Science and Applications},
      volume = {4},
      number = {3},
      pages = {219-224},
      doi = {10.11648/j.ijmsa.20150403.21},
      url = {https://doi.org/10.11648/j.ijmsa.20150403.21},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20150403.21},
      abstract = {Synthesis of biodiesel from the beef tallow using catalyst from Psammotaea elongata shell with methanol as a solvent was carried out. Synthesis the biodiesel was prepared in two steps, there are esterification and transesterification. In esterification was conducted in mole ratio of oil and methanol were 1: 9, with H2SO4 as a catalyst. Transesterification process conducted with mole ratio were 1:12 (oil and methanol), with CaO from cockle’ shell as a catalyst with a variation of the catalyst 11%, 12%, 13%, and 14%. Result of biodiesel was characterized based on FT-IR, 1H-NMR, GC-MS, and ASTM (American Standard Testing of Materials) method. The results obtained by the catalyst conversion of 51.9% and the optimum conditions in the biodiesel present in 12%. Yielded of biodiesel theoretically was 59.118% and experiment was 18.34%. The main component on biodiesel product is methyl stearate (40.65%) and examination result of biodiesel by using ASTM method are specific (0.8695 g/cm3), kinematic viscosity (5.393 mm/s2), flame point (178.5 °C), pour point (24 °C), and carbon Condradson residue (0.071%).},
     year = {2015}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Application of CaO from Psammotaea elongata Shell as Catalyst in Conversion the Beef Tallow to Biodiesel
    AU  - I. Wayan Sutapa
    AU  - A. Bandjar
    AU  - Rosmawaty
    AU  - M. Sitaniapessy
    Y1  - 2015/05/28
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ijmsa.20150403.21
    DO  - 10.11648/j.ijmsa.20150403.21
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 219
    EP  - 224
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20150403.21
    AB  - Synthesis of biodiesel from the beef tallow using catalyst from Psammotaea elongata shell with methanol as a solvent was carried out. Synthesis the biodiesel was prepared in two steps, there are esterification and transesterification. In esterification was conducted in mole ratio of oil and methanol were 1: 9, with H2SO4 as a catalyst. Transesterification process conducted with mole ratio were 1:12 (oil and methanol), with CaO from cockle’ shell as a catalyst with a variation of the catalyst 11%, 12%, 13%, and 14%. Result of biodiesel was characterized based on FT-IR, 1H-NMR, GC-MS, and ASTM (American Standard Testing of Materials) method. The results obtained by the catalyst conversion of 51.9% and the optimum conditions in the biodiesel present in 12%. Yielded of biodiesel theoretically was 59.118% and experiment was 18.34%. The main component on biodiesel product is methyl stearate (40.65%) and examination result of biodiesel by using ASTM method are specific (0.8695 g/cm3), kinematic viscosity (5.393 mm/s2), flame point (178.5 °C), pour point (24 °C), and carbon Condradson residue (0.071%).
    VL  - 4
    IS  - 3
    ER  - 

    Copy | Download

Author Information
  • Chemistry Department of Mathematic and Naturals Science, Pattimura University, Ambon-Maluku, Indonesia

  • Chemistry Department of Mathematic and Naturals Science, Pattimura University, Ambon-Maluku, Indonesia

  • Chemistry Department of Mathematic and Naturals Science, Pattimura University, Ambon-Maluku, Indonesia

  • Chemistry Department of Mathematic and Naturals Science, Pattimura University, Ambon-Maluku, Indonesia

  • Sections