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Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria

Received: 25 April 2016     Accepted: 19 May 2016     Published: 6 June 2016
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Abstract

The gamut of applications for metal nanoparticles fuels the interest for their synthesis. The hazardous, time and energy consuming nature of conventional techniques necessitates the search for alternative methods of synthesis that ensures the desired size, shape and dispersity is achieved. The use of aqueous plant extracts to reduce toxic heavy metals is a spontaneous, cost effective, eco-friendly method used in the synthesis of nanoparticles. Microwave catalysis have also gained acceptance as another green method for material synthesis due to its high reaction rates and shortened reaction times. This study was embarked on to develop a rapid and eco-friendly method for synthesizing silver nanoparticles (AgNPs), stabilized within a biocompatible matrix using orange peel extracts, starch and a microwave. Data obtained revealed from the characterization of the synthesized AgNPs revealed that the surface plasmon resonance (SPR) peaked at 408nm using a UV-Visible Spectrophotometer. The EDX spectrum of the solution containing silver nanoparticles confirmed the presence of an elemental silver signal. SEM and HR-TEM images suggest that the nanoparticles were of spherical shape. HR- TEM particle size range was 7-17.31±0.84nm. FT-IR spectroscopy analysis of synthesized AgNPs indicated a slight shift at the O-H absorption bands of starch. PXRD confirmed the reflections of silver nanoparticles at corresponding 2θ values respectively. The results obtained suggested that rapid catalysis of AgNPs using plant extracts is further boosted using microwave enhanced catalysis whereby the functional biomolecules from the plant extract is retained, altogether forming stable AgNPs.

Published in Chemical and Biomolecular Engineering (Volume 1, Issue 1)
DOI 10.11648/j.cbe.20160101.12
Page(s) 5-11
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Silver Nanoparticles, Bioreduction/Synthesis, Orange Peel Extract, SPR, HR-TEM, Microwave

References
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Cite This Article
  • APA Style

    Ihegwuagu Nnemeka, Etuk-Udo Godwin, Fatokun Olakunle, Odusanya Olushola, Omojola Moses, et al. (2016). Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria. Chemical and Biomolecular Engineering, 1(1), 5-11. https://doi.org/10.11648/j.cbe.20160101.12

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    ACS Style

    Ihegwuagu Nnemeka; Etuk-Udo Godwin; Fatokun Olakunle; Odusanya Olushola; Omojola Moses, et al. Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria. Chem. Biomol. Eng. 2016, 1(1), 5-11. doi: 10.11648/j.cbe.20160101.12

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    AMA Style

    Ihegwuagu Nnemeka, Etuk-Udo Godwin, Fatokun Olakunle, Odusanya Olushola, Omojola Moses, et al. Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria. Chem Biomol Eng. 2016;1(1):5-11. doi: 10.11648/j.cbe.20160101.12

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  • @article{10.11648/j.cbe.20160101.12,
      author = {Ihegwuagu Nnemeka and Etuk-Udo Godwin and Fatokun Olakunle and Odusanya Olushola and Omojola Moses and Onyenekwe Paul Chidozie and Sha’Ato Rufus},
      title = {Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria},
      journal = {Chemical and Biomolecular Engineering},
      volume = {1},
      number = {1},
      pages = {5-11},
      doi = {10.11648/j.cbe.20160101.12},
      url = {https://doi.org/10.11648/j.cbe.20160101.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20160101.12},
      abstract = {The gamut of applications for metal nanoparticles fuels the interest for their synthesis. The hazardous, time and energy consuming nature of conventional techniques necessitates the search for alternative methods of synthesis that ensures the desired size, shape and dispersity is achieved. The use of aqueous plant extracts to reduce toxic heavy metals is a spontaneous, cost effective, eco-friendly method used in the synthesis of nanoparticles. Microwave catalysis have also gained acceptance as another green method for material synthesis due to its high reaction rates and shortened reaction times. This study was embarked on to develop a rapid and eco-friendly method for synthesizing silver nanoparticles (AgNPs), stabilized within a biocompatible matrix using orange peel extracts, starch and a microwave. Data obtained revealed from the characterization of the synthesized AgNPs revealed that the surface plasmon resonance (SPR) peaked at 408nm using a UV-Visible Spectrophotometer. The EDX spectrum of the solution containing silver nanoparticles confirmed the presence of an elemental silver signal. SEM and HR-TEM images suggest that the nanoparticles were of spherical shape. HR- TEM particle size range was 7-17.31±0.84nm. FT-IR spectroscopy analysis of synthesized AgNPs indicated a slight shift at the O-H absorption bands of starch. PXRD confirmed the reflections of silver nanoparticles at corresponding 2θ values respectively. The results obtained suggested that rapid catalysis of AgNPs using plant extracts is further boosted using microwave enhanced catalysis whereby the functional biomolecules from the plant extract is retained, altogether forming stable AgNPs.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Microwave Enhanced Synthesis of Silver Nanoparticles Using Orange Peel Extracts from Nigeria
    AU  - Ihegwuagu Nnemeka
    AU  - Etuk-Udo Godwin
    AU  - Fatokun Olakunle
    AU  - Odusanya Olushola
    AU  - Omojola Moses
    AU  - Onyenekwe Paul Chidozie
    AU  - Sha’Ato Rufus
    Y1  - 2016/06/06
    PY  - 2016
    N1  - https://doi.org/10.11648/j.cbe.20160101.12
    DO  - 10.11648/j.cbe.20160101.12
    T2  - Chemical and Biomolecular Engineering
    JF  - Chemical and Biomolecular Engineering
    JO  - Chemical and Biomolecular Engineering
    SP  - 5
    EP  - 11
    PB  - Science Publishing Group
    SN  - 2578-8884
    UR  - https://doi.org/10.11648/j.cbe.20160101.12
    AB  - The gamut of applications for metal nanoparticles fuels the interest for their synthesis. The hazardous, time and energy consuming nature of conventional techniques necessitates the search for alternative methods of synthesis that ensures the desired size, shape and dispersity is achieved. The use of aqueous plant extracts to reduce toxic heavy metals is a spontaneous, cost effective, eco-friendly method used in the synthesis of nanoparticles. Microwave catalysis have also gained acceptance as another green method for material synthesis due to its high reaction rates and shortened reaction times. This study was embarked on to develop a rapid and eco-friendly method for synthesizing silver nanoparticles (AgNPs), stabilized within a biocompatible matrix using orange peel extracts, starch and a microwave. Data obtained revealed from the characterization of the synthesized AgNPs revealed that the surface plasmon resonance (SPR) peaked at 408nm using a UV-Visible Spectrophotometer. The EDX spectrum of the solution containing silver nanoparticles confirmed the presence of an elemental silver signal. SEM and HR-TEM images suggest that the nanoparticles were of spherical shape. HR- TEM particle size range was 7-17.31±0.84nm. FT-IR spectroscopy analysis of synthesized AgNPs indicated a slight shift at the O-H absorption bands of starch. PXRD confirmed the reflections of silver nanoparticles at corresponding 2θ values respectively. The results obtained suggested that rapid catalysis of AgNPs using plant extracts is further boosted using microwave enhanced catalysis whereby the functional biomolecules from the plant extract is retained, altogether forming stable AgNPs.
    VL  - 1
    IS  - 1
    ER  - 

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Author Information
  • Cordination Technical Research Programme, Agricultural Research Council of Nigeria (ARCN), Mabushi, Abuja, Nigeria

  • Biotechnology Advanced Research Centre, Sheda Science and Technology Complex (SHESTCO), Abuja, Nigeria

  • Chemistry Advanced Research Centre, Sheda Science and Technology Complex (SHESTCO), Abuja, Nigeria

  • Biotechnology Advanced Research Centre, Sheda Science and Technology Complex (SHESTCO), Abuja, Nigeria

  • Raw Materials Research and Development Council (RMRDC), Maitama, Abuja, Nigeria

  • Biotechnology Advanced Research Centre, Sheda Science and Technology Complex (SHESTCO), Abuja, Nigeria

  • Chemistry Department & Centre for Agrochemical Technology, University of Agriculture, Makurdi, Benue State, Nigeria

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