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Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles

Received: 7 January 2019     Accepted: 11 February 2019     Published: 5 March 2019
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Abstract

This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.

Published in American Journal of Polymer Science and Technology (Volume 5, Issue 1)
DOI 10.11648/j.ajpst.20190501.11
Page(s) 1-8
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Radical Copolymerization, AA, HEMA, MNPs

References
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Cite This Article
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    Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. (2019). Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. American Journal of Polymer Science and Technology, 5(1), 1-8. https://doi.org/10.11648/j.ajpst.20190501.11

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    ACS Style

    Tania Tofaz; Dhananjoy Chandra Mahanto; Shamima Akhter; Md. Mahbubor Rahman; M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am. J. Polym. Sci. Technol. 2019, 5(1), 1-8. doi: 10.11648/j.ajpst.20190501.11

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    AMA Style

    Tania Tofaz, Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif. Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles. Am J Polym Sci Technol. 2019;5(1):1-8. doi: 10.11648/j.ajpst.20190501.11

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  • @article{10.11648/j.ajpst.20190501.11,
      author = {Tania Tofaz and Dhananjoy Chandra Mahanto and Shamima Akhter and Md. Mahbubor Rahman and M. Abdul Latif},
      title = {Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles},
      journal = {American Journal of Polymer Science and Technology},
      volume = {5},
      number = {1},
      pages = {1-8},
      doi = {10.11648/j.ajpst.20190501.11},
      url = {https://doi.org/10.11648/j.ajpst.20190501.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20190501.11},
      abstract = {This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles
    AU  - Tania Tofaz
    AU  - Dhananjoy Chandra Mahanto
    AU  - Shamima Akhter
    AU  - Md. Mahbubor Rahman
    AU  - M. Abdul Latif
    Y1  - 2019/03/05
    PY  - 2019
    N1  - https://doi.org/10.11648/j.ajpst.20190501.11
    DO  - 10.11648/j.ajpst.20190501.11
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 1
    EP  - 8
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20190501.11
    AB  - This paper covers the targetable magnetic iron oxide core and biodegradable, cost-effective, eco-friendly polymer shell considering their versatile and extensive use in various fields. In this work, poly (acrylic acid–co-2-hydroxyethylmethacrylate) [P (AA-co-HEMA)] magnetic composite polymer particles were synthesized by the method of two-stage solution polymerization in aqueous media. At first synthesis, the Fe3O4 particles by a traditional co-precipitation method and in the second stage occurs the formation of the polymer using acrylic acid (AA) as monomer and 2-hydroxyethyl methacrylate (HEMA) as co-monomer. Finally, the synthesized iron oxide particles encapsulated by a polymer to modify the surface of composite particles. The modified composite particles were then characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffractometry (XRD), Dynamic Light Scattering (DLS), Thermo Gravimetric Analysis (TGA) and Vibrating Sample Magnetometry (VSM). The existence of carboxyl (-COOH) & hydroxyl (-OH) groups in the composite particles was confirmed by FTIR. XRD indicated the crystalline cubic spinel structure of magnetic composite particles. VSM results showed that the synthesized coated composite particles were paramagnetic in nature magnetic saturation is obtained 72.72 emu/g and 97.9 emu/g for bare Fe3O4 and coated magnetic composite particles respectively.
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

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