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Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene

Received: 9 November 2017     Accepted: 1 December 2017     Published: 21 December 2017
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Abstract

The long chain vinyl end-functional polystyrene has been synthesized in bulk polymerization method using atom transfer radical polymerization (ATRP) with Undecenyl-2-Bromopropionate (UnBP) and CuCl/bypyridine catalytic system. The polymerizations demonstrate an increase in molecular weight and conversion in direct proportion to the polymerization time by consumed monomer which exhibited first-order kinetics. This study concludes the simple kinetics of polystyrene synthesized by ATRP using initiator and ligand-to-copper(I) halide was found to be 1:2:1, which tentatively indicates that the coordination sphere of the active copper(I) center contains two bipyridine ligands. The propagation rate has been investigated for long range of time for ensuring that the rate of radical combination or disproportionation is sufficiently less.

Published in American Journal of Polymer Science and Technology (Volume 3, Issue 6)
DOI 10.11648/j.ajpst.20170306.12
Page(s) 103-107
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Polystyrene, Initiator, ATRP, Bulk Polymerization, Kinetics

References
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Cite This Article
  • APA Style

    Samiul Islam Chowdhury, Lamya Zahir, Tariqul Hasan. (2017). Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene. American Journal of Polymer Science and Technology, 3(6), 103-107. https://doi.org/10.11648/j.ajpst.20170306.12

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    ACS Style

    Samiul Islam Chowdhury; Lamya Zahir; Tariqul Hasan. Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene. Am. J. Polym. Sci. Technol. 2017, 3(6), 103-107. doi: 10.11648/j.ajpst.20170306.12

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    AMA Style

    Samiul Islam Chowdhury, Lamya Zahir, Tariqul Hasan. Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene. Am J Polym Sci Technol. 2017;3(6):103-107. doi: 10.11648/j.ajpst.20170306.12

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  • @article{10.11648/j.ajpst.20170306.12,
      author = {Samiul Islam Chowdhury and Lamya Zahir and Tariqul Hasan},
      title = {Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene},
      journal = {American Journal of Polymer Science and Technology},
      volume = {3},
      number = {6},
      pages = {103-107},
      doi = {10.11648/j.ajpst.20170306.12},
      url = {https://doi.org/10.11648/j.ajpst.20170306.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20170306.12},
      abstract = {The long chain vinyl end-functional polystyrene has been synthesized in bulk polymerization method using atom transfer radical polymerization (ATRP) with Undecenyl-2-Bromopropionate (UnBP) and CuCl/bypyridine catalytic system. The polymerizations demonstrate an increase in molecular weight and conversion in direct proportion to the polymerization time by consumed monomer which exhibited first-order kinetics. This study concludes the simple kinetics of polystyrene synthesized by ATRP using initiator and ligand-to-copper(I) halide was found to be 1:2:1, which tentatively indicates that the coordination sphere of the active copper(I) center contains two bipyridine ligands. The propagation rate has been investigated for long range of time for ensuring that the rate of radical combination or disproportionation is sufficiently less.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene
    AU  - Samiul Islam Chowdhury
    AU  - Lamya Zahir
    AU  - Tariqul Hasan
    Y1  - 2017/12/21
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    N1  - https://doi.org/10.11648/j.ajpst.20170306.12
    DO  - 10.11648/j.ajpst.20170306.12
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 103
    EP  - 107
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20170306.12
    AB  - The long chain vinyl end-functional polystyrene has been synthesized in bulk polymerization method using atom transfer radical polymerization (ATRP) with Undecenyl-2-Bromopropionate (UnBP) and CuCl/bypyridine catalytic system. The polymerizations demonstrate an increase in molecular weight and conversion in direct proportion to the polymerization time by consumed monomer which exhibited first-order kinetics. This study concludes the simple kinetics of polystyrene synthesized by ATRP using initiator and ligand-to-copper(I) halide was found to be 1:2:1, which tentatively indicates that the coordination sphere of the active copper(I) center contains two bipyridine ligands. The propagation rate has been investigated for long range of time for ensuring that the rate of radical combination or disproportionation is sufficiently less.
    VL  - 3
    IS  - 6
    ER  - 

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Author Information
  • Department of Chemistry, Bangladesh University of Textiles, Dhaka, Bangladesh

  • Department of Apparel Engineering, Bangladesh University of Textiles, Dhaka, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

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