| Peer-Reviewed

A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization

Received: 27 September 2015     Accepted: 14 October 2015     Published: 15 October 2015
Views:       Downloads:
Abstract

A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.

Published in American Journal of Polymer Science and Technology (Volume 1, Issue 2)
DOI 10.11648/j.ajpst.20150102.11
Page(s) 15-17
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Non-metallocene, Titanium, Ethylene Polymerization, Molecular Weight

References
[1] G. J. P. Britovsek, V. C. Gibson, D. F. Wass. Angew. Chem., Int. Ed., 1999, 38, 429.
[2] V. C. Gibson, S. K. Spitzmesser, Chem. Rev., 2003, 103, 283.
[3] M. Hong, B. Li, Y. Li. Chin. J. Polym. Sci., 2011, 29, 692,
[4] S. Yuan, S. Bai, D. Liu, W. H. Sun. Organometallics, 2010, 29, 2132.
[5] S. Yuan, X. Wei, H. Tong, L. Zhang, D. Liu, W. H. Sun. Organometallics, 2010, 29, 2085.
[6] S. Liu, W. Zuo, S. Zhang, P. Hao, D. Wang, W. H. Sun. J. Polym. Sci. A: Polym. Chem., 2008, 46, 3411.
[7] V. C. Gibson, B. S. Kimberley, A. J. P. White, D. J. Williams, P. Howard. Chem. Commun., 1998, 313.
[8] M. R. Mason, B. N. Fneich, K. Kirschbaum. Inorg. Chem., 2003, 42, 6592.
[9] J. D. Scollard, D. H. McConville. J. Am. Chem. Soc., 1996, 118, 10008.
[10] A. Shafir, J. Arnold. Organometallics, 2003, 22, 567.
[11] J. Jin, S. Tsubaki, T. Uozumi, T. Sano, K. Soga. Macromol. Rapid Commun., 1998, 19, 597.
[12] A. Linden, C. J. Schaverien, N. Meijboom, N. C. Ganter, A. G. Orpen. J. Am. Chem. Soc., 1995, 117, 3008.
[13] S. Fokken, T. P. Spaniol, J. Okuda. Organometallics, 1997, 16, 4240.
[14] J. Canich, H. W. Turner. 1992 PCT Int. Appl. 92/12162.
[15] K. Vijayakrishna, G. Sundararajan. Polymer, 2006, 47, 8289.
[16] T. Xu, W. Gao, Y. Mu, L. Ye. Polyhedron, 2007, 26, 3357.
[17] J. C. W. Chien, A. Razavi. J. Polym. Sci.: Part A: Polym. Chem., 1998, 26, 2369.
Cite This Article
  • APA Style

    Wei Wang, Changcheng Liu. (2015). A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. American Journal of Polymer Science and Technology, 1(2), 15-17. https://doi.org/10.11648/j.ajpst.20150102.11

    Copy | Download

    ACS Style

    Wei Wang; Changcheng Liu. A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. Am. J. Polym. Sci. Technol. 2015, 1(2), 15-17. doi: 10.11648/j.ajpst.20150102.11

    Copy | Download

    AMA Style

    Wei Wang, Changcheng Liu. A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. Am J Polym Sci Technol. 2015;1(2):15-17. doi: 10.11648/j.ajpst.20150102.11

    Copy | Download

  • @article{10.11648/j.ajpst.20150102.11,
      author = {Wei Wang and Changcheng Liu},
      title = {A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization},
      journal = {American Journal of Polymer Science and Technology},
      volume = {1},
      number = {2},
      pages = {15-17},
      doi = {10.11648/j.ajpst.20150102.11},
      url = {https://doi.org/10.11648/j.ajpst.20150102.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20150102.11},
      abstract = {A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.},
     year = {2015}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization
    AU  - Wei Wang
    AU  - Changcheng Liu
    Y1  - 2015/10/15
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ajpst.20150102.11
    DO  - 10.11648/j.ajpst.20150102.11
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 15
    EP  - 17
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20150102.11
    AB  - A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.
    VL  - 1
    IS  - 2
    ER  - 

    Copy | Download

Author Information
  • Institute of Materials Science, Beijing Research Institute of Chemical Industry (BRICI), Sinopec, Chao Yang District, Beijing

  • Institute of Materials Science, Beijing Research Institute of Chemical Industry (BRICI), Sinopec, Chao Yang District, Beijing

  • Sections