| Peer-Reviewed

Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions

Received: 31 May 2019     Accepted: 3 July 2019     Published: 22 July 2019
Views:       Downloads:
Abstract

Triazine-based dendrimer 2,4,6-tris(di-acetamido)-1,3,5-triazine encapsulated heterogeneous Co-Pd bimetallic nanoparticles (NPS) were prepared through sequential loading method from the dendrimer which was synthesized directly between the reaction of 2,4,6-triamino-1,3,5-triazine and acetyl chloride at room temperature about 2 hours. The physicochemical characteristics of Co-Pd bimetallic NPS were studied with the aid of EDX, XRD, TG& DSC techniques. The presence of cobalt was 55.75% and palladium was 9.40% of the mass of the 2,4,6-tris(di-acetamido)-1,3,5-triazine assisted Co-Pd Bimetallic NPs 4 observed from EDX analysis. The TG& DSC analysis curves indicated the thermal stability up to 320°C which is a very important steadiness key for catalytic effectiveness of the prepared Co-Pd Bimetallic NPs 4. The nano-shape FCC structure of Co-Pd bimetallic NPs was confirmed by XRD analysis. The average size of Co-Pd bimetallic NPs of 17.50 nm length was calculated through the Debye-Scherrer formula while TEM analysis showed the average particle size was 14.50 nm. The dendrimer was also analyzed by IR, 1HNMR, 13CNMR and elemental analysis. The catalytic performance of these nanoparticles' catalyst was explored for C–C coupling reactions such as Suzuki–Miyaura at moderate reaction conditions whereas the reusing potential of the catalyst was evaluated without noticeable loss of activity for five successive runs. All the results of the analysis of this catalyst make it a cost-effective and highly active catalyst for the carbon-carbon cross-coupling reactions which are demand in chemical and pharmaceutical industries.

Published in American Journal of Nanosciences (Volume 5, Issue 1)
DOI 10.11648/j.ajn.20190501.11
Page(s) 1-8
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Bimetallic Nanoparticles (NPs), Triazine, Dendrimer and Suzuki–Miyaura Reaction

References
[1] A. Archut and F. Vo¨gtle, Handbook of Nanostructured Materials and Nanotechnology, H. S. Nalwa (ed.), Academic Press, San Diego, 5, 333, (2000).
[2] M. Fischer and F. Vögtle, Dendrimers: from design to application—a progress report, Angewandte Chemie International Edition, 38(7), 884-905, (1999).
[3] R. M. Crooks, M. Zhao, L. Sun, V. Chechik and L. K. Yeung, Dendrimer-encapsulated metal nanoparticles: synthesis, characterization, and applications to catalysis, Accounts of chemical research, 34(3), 181-190, (2001).
[4] R. W. Scott, H. Ye, R. R. Henriquez and R. M. Crooks, Synthesis, characterization, and stability of dendrimer-encapsulated palladium nanoparticles. Chemistry of Materials, 15(20), 3873-3878, (2003).
[5] M. Pittelkow, K. Moth-Poulsen, U. Boas and J. B. Christensen, Poly (amidoamine)-dendrimer-stabilized Pd (0) nanoparticles as a catalyst for the Suzuki reaction. Langmuir, 19(18), 7682-7684, (2003).
[6] F. Zeng and S. C. Zimmerman, Dendrimers in supramolecular chemistry: from molecular recognition to self-assembly. Chemical reviews, 97(5), 1681-1712, (1997).
[7] O. A. Matthews, A. N. Shipway and J. F. Stoddart, Dendrimers-branching out from curiosities into new technologies. Progress in polymer science, 23(1), 1-56, (1998).
[8] R. Andres, E. de Jesus and J. C. Flores, Catalysts based on palladium dendrimers, New Journal of Chemistry, 31(7), 1161-1191, (2007).
[9] R. M. Crooks, M. Zhao, L. Sun, V. Chechik and L. K. Yeung, Dendrimer-encapsulated metal nanoparticles: synthesis, characterization, and applications to catalysis, Accounts of chemical research, 34(3), 181-190, (2001).
[10] W. Hui, L. R. garry, Bimetallic Dendrimer-Encapsulated Nanoparticle Catalyst. Polymer reviews, 56(3), 486-511, (2016).
[11] J. K. Nørskov, F. Abild-Pedersen, F. Studt, and T. Bligaard. Density functional theory in surface chemistry and catalysis. Proceedings of the National Academy of Sciences, 108(3), 937-943, (2011).
[12] W. M. Haynes, and D. R. Lide, 2012. CRC handbook of physics and chemistry.
[13] Y. S. Feng, X. Y. Lin, J. Hao and H. J. Xu, Pd–Co bimetallic nanoparticles supported on graphene as a highly active catalyst for Suzuki–Miyaura and Sonogashira cross-coupling reactions. Tetrahedron, 70(34), 5249-5253, (2014).
[14] Z. Zhang and Z. Wang, Diatomite-supported Pd nanoparticles: an efficient catalyst for Heck and Suzuki reactions. The Journal of organic chemistry, 71(19), 7485-7487, (2006).
[15] A. Kashif, T. Iqbal, U. S. Solat and M. Muhammad. Green synthesis of cobalt nanoparticles by using methanol extract of plant leaf as reducing agent. Pure and Applied Biology. Pure and Applied Biology 5(3), 453-457, (2016).
[16] D. Sengupta J. Saha, G. De, B. Basu, Pd/Cu bimetallic nanoparticles embedded in macroporous ion-exchange resins: an excellent heterogeneous catalyst for the Sonogashira reaction. J Mater Chem A 2(11), 3986-92, (2014).
[17] S. Yaşar, Ç. Şahin, M. Arslan, and İ. Özdemir, Synthesis, characterization and the Suzuki–Miyaura coupling reactions of N-heterocyclic carbene–Pd (II)–pyridine (PEPPSI) complexes. Journal of Organometallic Chemistry, 776, 107-112, (2015).
[18] C. A. Fleckenstein, and H. Plenio, Highly efficient Suzuki–Miyaura coupling of heterocyclic substrates through rational reaction design. Chemistry–A European Journal, 14(14), 4267-4279, (2008).
Cite This Article
  • APA Style

    Mohammad Sayedul Islam, Mohammad Wahab Khan. (2019). Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions. American Journal of Nanosciences, 5(1), 1-8. https://doi.org/10.11648/j.ajn.20190501.11

    Copy | Download

    ACS Style

    Mohammad Sayedul Islam; Mohammad Wahab Khan. Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions. Am. J. Nanosci. 2019, 5(1), 1-8. doi: 10.11648/j.ajn.20190501.11

    Copy | Download

    AMA Style

    Mohammad Sayedul Islam, Mohammad Wahab Khan. Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions. Am J Nanosci. 2019;5(1):1-8. doi: 10.11648/j.ajn.20190501.11

    Copy | Download

  • @article{10.11648/j.ajn.20190501.11,
      author = {Mohammad Sayedul Islam and Mohammad Wahab Khan},
      title = {Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions},
      journal = {American Journal of Nanosciences},
      volume = {5},
      number = {1},
      pages = {1-8},
      doi = {10.11648/j.ajn.20190501.11},
      url = {https://doi.org/10.11648/j.ajn.20190501.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20190501.11},
      abstract = {Triazine-based dendrimer 2,4,6-tris(di-acetamido)-1,3,5-triazine encapsulated heterogeneous Co-Pd bimetallic nanoparticles (NPS) were prepared through sequential loading method from the dendrimer which was synthesized directly between the reaction of 2,4,6-triamino-1,3,5-triazine and acetyl chloride at room temperature about 2 hours. The physicochemical characteristics of Co-Pd bimetallic NPS were studied with the aid of EDX, XRD, TG& DSC techniques. The presence of cobalt was 55.75% and palladium was 9.40% of the mass of the 2,4,6-tris(di-acetamido)-1,3,5-triazine assisted Co-Pd Bimetallic NPs 4 observed from EDX analysis. The TG& DSC analysis curves indicated the thermal stability up to 320°C which is a very important steadiness key for catalytic effectiveness of the prepared Co-Pd Bimetallic NPs 4. The nano-shape FCC structure of Co-Pd bimetallic NPs was confirmed by XRD analysis. The average size of Co-Pd bimetallic NPs of 17.50 nm length was calculated through the Debye-Scherrer formula while TEM analysis showed the average particle size was 14.50 nm. The dendrimer was also analyzed by IR, 1HNMR, 13CNMR and elemental analysis. The catalytic performance of these nanoparticles' catalyst was explored for C–C coupling reactions such as Suzuki–Miyaura at moderate reaction conditions whereas the reusing potential of the catalyst was evaluated without noticeable loss of activity for five successive runs. All the results of the analysis of this catalyst make it a cost-effective and highly active catalyst for the carbon-carbon cross-coupling reactions which are demand in chemical and pharmaceutical industries.},
     year = {2019}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Synthesis of Dendrimer Assisted Co-Pd Bimetallic Nanoparticles and Catalytic Activity for Suzuki–Miyaura Coupling Reactions
    AU  - Mohammad Sayedul Islam
    AU  - Mohammad Wahab Khan
    Y1  - 2019/07/22
    PY  - 2019
    N1  - https://doi.org/10.11648/j.ajn.20190501.11
    DO  - 10.11648/j.ajn.20190501.11
    T2  - American Journal of Nanosciences
    JF  - American Journal of Nanosciences
    JO  - American Journal of Nanosciences
    SP  - 1
    EP  - 8
    PB  - Science Publishing Group
    SN  - 2575-4858
    UR  - https://doi.org/10.11648/j.ajn.20190501.11
    AB  - Triazine-based dendrimer 2,4,6-tris(di-acetamido)-1,3,5-triazine encapsulated heterogeneous Co-Pd bimetallic nanoparticles (NPS) were prepared through sequential loading method from the dendrimer which was synthesized directly between the reaction of 2,4,6-triamino-1,3,5-triazine and acetyl chloride at room temperature about 2 hours. The physicochemical characteristics of Co-Pd bimetallic NPS were studied with the aid of EDX, XRD, TG& DSC techniques. The presence of cobalt was 55.75% and palladium was 9.40% of the mass of the 2,4,6-tris(di-acetamido)-1,3,5-triazine assisted Co-Pd Bimetallic NPs 4 observed from EDX analysis. The TG& DSC analysis curves indicated the thermal stability up to 320°C which is a very important steadiness key for catalytic effectiveness of the prepared Co-Pd Bimetallic NPs 4. The nano-shape FCC structure of Co-Pd bimetallic NPs was confirmed by XRD analysis. The average size of Co-Pd bimetallic NPs of 17.50 nm length was calculated through the Debye-Scherrer formula while TEM analysis showed the average particle size was 14.50 nm. The dendrimer was also analyzed by IR, 1HNMR, 13CNMR and elemental analysis. The catalytic performance of these nanoparticles' catalyst was explored for C–C coupling reactions such as Suzuki–Miyaura at moderate reaction conditions whereas the reusing potential of the catalyst was evaluated without noticeable loss of activity for five successive runs. All the results of the analysis of this catalyst make it a cost-effective and highly active catalyst for the carbon-carbon cross-coupling reactions which are demand in chemical and pharmaceutical industries.
    VL  - 5
    IS  - 1
    ER  - 

    Copy | Download

Author Information
  • Department of Chemistry, Faculty of Engineering, Bangladesh University of Engineering and Technology (BUET), Dhaka, Bangladesh

  • Department of Chemistry, Faculty of Engineering, Bangladesh University of Engineering and Technology (BUET), Dhaka, Bangladesh

  • Sections