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Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Received: 15 April 2017     Accepted: 5 May 2017     Published: 21 June 2017
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Abstract

Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.

Published in American Journal of Chemical Engineering (Volume 5, Issue 4)
DOI 10.11648/j.ajche.20170504.11
Page(s) 49-55
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Facilitated Transport, Supported Liquid Membranes, Permeability, Flux, Activation Parameters

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    Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. (2017). Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. American Journal of Chemical Engineering, 5(4), 49-55. https://doi.org/10.11648/j.ajche.20170504.11

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    ACS Style

    Oussama Kamal; Tarik Eljaddi; Habib Mouadili; El Houssaine EL Atmani; Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am. J. Chem. Eng. 2017, 5(4), 49-55. doi: 10.11648/j.ajche.20170504.11

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    AMA Style

    Oussama Kamal, Tarik Eljaddi, Habib Mouadili, El Houssaine EL Atmani, Laurent Lebrun, et al. Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism. Am J Chem Eng. 2017;5(4):49-55. doi: 10.11648/j.ajche.20170504.11

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  • @article{10.11648/j.ajche.20170504.11,
      author = {Oussama Kamal and Tarik Eljaddi and Habib Mouadili and El Houssaine EL Atmani and Laurent Lebrun and Miloudi Hlaïbi},
      title = {Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism},
      journal = {American Journal of Chemical Engineering},
      volume = {5},
      number = {4},
      pages = {49-55},
      doi = {10.11648/j.ajche.20170504.11},
      url = {https://doi.org/10.11648/j.ajche.20170504.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20170504.11},
      abstract = {Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism
    AU  - Oussama Kamal
    AU  - Tarik Eljaddi
    AU  - Habib Mouadili
    AU  - El Houssaine EL Atmani
    AU  - Laurent Lebrun
    AU  - Miloudi Hlaïbi
    Y1  - 2017/06/21
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajche.20170504.11
    DO  - 10.11648/j.ajche.20170504.11
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 49
    EP  - 55
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.20170504.11
    AB  - Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J0)), as well as microscopic parameters (association constants (Kass), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.
    VL  - 5
    IS  - 4
    ER  - 

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Author Information
  • Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco

  • Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco

  • Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco

  • Laboratory of Materials Engineering for the Environment and Valuation, Faculty of Sciences A?n Chock, University Hassan II, Casablanca, Morocco

  • Laboratory of Polymeres Biopolymeres Surfaces, Faculty des Sciences, University of Rouen, Mont-Saint-Aignan, France

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