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Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution

Received: 23 August 2022     Accepted: 6 September 2022     Published: 26 September 2022
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Abstract

Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE).

Published in American Journal of Applied Chemistry (Volume 10, Issue 5)
DOI 10.11648/j.ajac.20221005.12
Page(s) 120-128
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Vitamins, Aluminium, Gravimetric, Hydrochloric Acid, Density Functional Theory

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    Mamadou Yeo, Mougo Andre Tigori, M’Bouille Cisse, Paulin Marius Niamien. (2022). Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution. American Journal of Applied Chemistry, 10(5), 120-128. https://doi.org/10.11648/j.ajac.20221005.12

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    Mamadou Yeo; Mougo Andre Tigori; M’Bouille Cisse; Paulin Marius Niamien. Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution. Am. J. Appl. Chem. 2022, 10(5), 120-128. doi: 10.11648/j.ajac.20221005.12

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    AMA Style

    Mamadou Yeo, Mougo Andre Tigori, M’Bouille Cisse, Paulin Marius Niamien. Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution. Am J Appl Chem. 2022;10(5):120-128. doi: 10.11648/j.ajac.20221005.12

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  • @article{10.11648/j.ajac.20221005.12,
      author = {Mamadou Yeo and Mougo Andre Tigori and M’Bouille Cisse and Paulin Marius Niamien},
      title = {Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution},
      journal = {American Journal of Applied Chemistry},
      volume = {10},
      number = {5},
      pages = {120-128},
      doi = {10.11648/j.ajac.20221005.12},
      url = {https://doi.org/10.11648/j.ajac.20221005.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221005.12},
      abstract = {Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE).},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution
    AU  - Mamadou Yeo
    AU  - Mougo Andre Tigori
    AU  - M’Bouille Cisse
    AU  - Paulin Marius Niamien
    Y1  - 2022/09/26
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajac.20221005.12
    DO  - 10.11648/j.ajac.20221005.12
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 120
    EP  - 128
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20221005.12
    AB  - Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE).
    VL  - 10
    IS  - 5
    ER  - 

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Author Information
  • Laboratory of Constitution and Reaction of Matter, University of Felix Houphouet Boigny, Abidjan, Ivory Coast

  • Department of Mathematics, Physics and Chemistry, University of Jean Lorougnon Guede, Daloa, Ivory Coast

  • Department of Mathematics, Physics and Chemistry, University of Jean Lorougnon Guede, Daloa, Ivory Coast

  • Laboratory of Constitution and Reaction of Matter, University of Felix Houphouet Boigny, Abidjan, Ivory Coast

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