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Study of Potential Adsorption of Glyphosate on Iron-textured Soil

Received: 22 November 2021     Accepted: 21 December 2021     Published: 31 December 2021
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Abstract

The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5.

Published in American Journal of Applied Chemistry (Volume 9, Issue 6)
DOI 10.11648/j.ajac.20210906.15
Page(s) 213-220
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Pesticides, Iron Oxides, Adsorption Phenomenon, Kinetics, Isotherm, pH

References
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Cite This Article
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    Kouakou Yao Urbain, Kambiré Ollo, Kouakou Kpan Kpan Gains, Trokourey Albert. (2021). Study of Potential Adsorption of Glyphosate on Iron-textured Soil. American Journal of Applied Chemistry, 9(6), 213-220. https://doi.org/10.11648/j.ajac.20210906.15

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    ACS Style

    Kouakou Yao Urbain; Kambiré Ollo; Kouakou Kpan Kpan Gains; Trokourey Albert. Study of Potential Adsorption of Glyphosate on Iron-textured Soil. Am. J. Appl. Chem. 2021, 9(6), 213-220. doi: 10.11648/j.ajac.20210906.15

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    AMA Style

    Kouakou Yao Urbain, Kambiré Ollo, Kouakou Kpan Kpan Gains, Trokourey Albert. Study of Potential Adsorption of Glyphosate on Iron-textured Soil. Am J Appl Chem. 2021;9(6):213-220. doi: 10.11648/j.ajac.20210906.15

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  • @article{10.11648/j.ajac.20210906.15,
      author = {Kouakou Yao Urbain and Kambiré Ollo and Kouakou Kpan Kpan Gains and Trokourey Albert},
      title = {Study of Potential Adsorption of Glyphosate on Iron-textured Soil},
      journal = {American Journal of Applied Chemistry},
      volume = {9},
      number = {6},
      pages = {213-220},
      doi = {10.11648/j.ajac.20210906.15},
      url = {https://doi.org/10.11648/j.ajac.20210906.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20210906.15},
      abstract = {The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Study of Potential Adsorption of Glyphosate on Iron-textured Soil
    AU  - Kouakou Yao Urbain
    AU  - Kambiré Ollo
    AU  - Kouakou Kpan Kpan Gains
    AU  - Trokourey Albert
    Y1  - 2021/12/31
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajac.20210906.15
    DO  - 10.11648/j.ajac.20210906.15
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 213
    EP  - 220
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20210906.15
    AB  - The main goal of this study is to evaluate the potential for glyphosate to contaminate water and ground water. For this purpose, the adsorption of glyphosate on a soil of culture in West of Côte d’Ivoire is investigated. The chemical composition of the soil, the different materials that compose it as well as the pH of zero charge of this soil were determined. The results revealed that the soil sample was rich in iron oxide mainly goethite, phengite and anatase. Adsorption kinetics was studied and the rate of sorption was found to conform to pseudo-second-order kinetics with 90 min as equilibrium time. Equilibrium isotherm data were analyzed according to Langmuir and Freundlich models. The two models describe the adsorption phenomenon well. The soil is heterogeneous with a good affinity between the metal oxides of the soil and the glyphosate. The maximum adsorption capacities were determined to be 2.68 mg/g. Parameters such as the initial pH of the solution, the mass of soil and the temperature were well investigated. It is observed that the adsorbed amount of glyphosate increases with temperature, reflecting the endothermic nature of the adsorption. The maximum amount of glyphosate adsorbed at 40°C is approximately 3 mg/g. The amount of glyphosate adsorbed increases with the initial concentration and decreases with the increase of pH. The optimal pH is therefore 5.
    VL  - 9
    IS  - 6
    ER  - 

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Author Information
  • UFR Sciences et Technologies, Université de Man, Man, C?te d'Ivoire

  • UFR Sciences et Technologies, Université de Man, Man, C?te d'Ivoire

  • Laboratoire National d'Appui au Développement Agricole (LANADA), Abidjan, C?te d’Ivoire

  • Laboratoire de Constitution et Réaction de la Matière, UFR SSMT, Université Félix Houphou?t-Boigny de Cocody, Abidjan, C?te d’Ivoire

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