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Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil

Received: 28 October 2021    Accepted: 23 November 2021    Published: 24 November 2021
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Abstract

With the promoting of transmission voltage level and the continuous fluctuation of operating conditions by connecting renewable energy into the power system, more stringent requirements have been placed on the operation reliability of transformers and other large electrical equipment. Transformer oil, as the main liquid insulating medium in large power equipment, the modification of its insulating performance has always been research focus in dielectric field. Studies have proved that TiO2 nanomaterials can not only enhance the AC and positive impulse breakdown voltage of transformer oil, but also significantly improve the aging resistance of transformer oil. However, the DC breakdown voltage of transformer oil has not been greatly increased yet, and sometime even weakened. In this paper, TiO2 hollow nanoparticles were prepared by hard template method to modify transformer oil. AC and DC breakdown voltage and dielectric permittivity of transformer oil before and after modification were measured and analyzed. The results show that the AC breakdown voltage of the transformer oil can be increased by 32.5%. DC breakdown voltage was increased first and then reduced with the increasing of nanoparticle concentration, while no obvious improvemnet was observed. Based on breakdown mechanism and permittivity of transformer oil, we think the hollow structure of the nanoparticles can significantly enlarge the interface between particle and oil, which greatly promotes the capturing capability to fast electrons and inhibit their migration in the oil, so the AC breakdown voltage are significantly increased. Under DC stress, nanoparticles can capture electrons and meanwhile migrate along fixed direction, which increased electrical conductivity of oil and resulted in lowering of DC breakdown voltage with the increase of nanoparticle concentration.

Published in Science Discovery (Volume 9, Issue 6)
DOI 10.11648/j.sd.20210906.27
Page(s) 375-378
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

TiO2, Hollow Structure, Transformer Oil, Breakdown Voltage

References
[1] 魏振,齐波,左健,李成榕.基于局部放电图像特征的换流变压器油纸绝缘缺陷诊断方法[J].电网技术,2015,39(04):1160-1166。
[2] Shuai Y, Han X, Zhang L, et al. Major insulation design consideration of converter transformer [C]// International Conference on Condition Monitoring & Diagnosis. IEEE, 2016.
[3] 董明,李阳,戴建卓,王健一,李金忠.纳米改性液体电介质研究现状与进展[J].绝缘材料,2016,49(12):1-7。
[4] 司马文霞,曹雪菲,杨庆,余斐,施健,宋鹤.冲击电压下3种纳米改性变压器油击穿特性的比较和分析[J].高电压技术,2015,41(02):374-381。
[5] 杜岳凡. TiO2纳米粒子对变压器油绝缘和电荷输运特性的影响[D].华北电力大学,2013。
[6] 周游,陈牧天,吕玉珍,王蔚,李成榕. TiO2纳米粒子对高水分变压器油中电荷输运的影响[J].电工技术学报,2014,29(12):236-241。
[7] Bhunia M M, Panigrahi K, Naskar C B, et al. 2D square nanosheets of Anatase TiO2: A surfactant free nanofiller for transformer oil nanofluids [J]. Journal of Molecular Liquids, 2020, 325:115000.
[8] Lv Y, Du Y, Li C, et al. TiO2 nanoparticle induced space charge decay in thermal aged transformer oil [J]. Applied Physics Letters, 2013, 102 (13): 6-9.
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[10] Hwang J G, Zahn M, FM O’Sullivan, et al. Effects of nanoparticle charging on streamer development in transformer oil-based nanofluids [J]. Journal of Applied Physics, 2010, 107 (1): 416-622.
[11] Du Y, Lv Y, Li C, et al. Effect of electron shallow trap on breakdown performance of transformer oil-based nanofluids [J]. Journal of Applied Physics, 2011, 110 (10): 104104.
[12] Du Y. Effect of semiconductive nanoparticles on insulating performances of transformer oil[J]. IEEE Transactions on Dielectrics & Electrical Insulation, 2012, 19 (3): 770-776.
[13] Beroual A, Khaled U, Alghamdi A M. DC Breakdown Voltage of Synthetic Ester Liquid-Based Nanofluids[J]. IEEE Access, 2020, PP (99): 1-1.
[14] 董明、杨凯歌、马馨逸、胡一卓、谢佳成、徐广昊.纳米改性变压器油中载流子输运特性分析[J]电工技术学报, 2020,35(21):12。
[15] 王磊,牛铭康,李超,吕玉珍,黄猛,李成榕.TiO2纳米变压器油击穿和电导特性的微观模型[J].高电压技术,2019,45(10):3350-3356。
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Cite This Article
  • APA Style

    Guangshuai Sun, Jiawei Liu, Binzhong Jia, Baixin Liu, Yuzhen Lv. (2021). Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil. Science Discovery, 9(6), 375-378. https://doi.org/10.11648/j.sd.20210906.27

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    ACS Style

    Guangshuai Sun; Jiawei Liu; Binzhong Jia; Baixin Liu; Yuzhen Lv. Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil. Sci. Discov. 2021, 9(6), 375-378. doi: 10.11648/j.sd.20210906.27

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    AMA Style

    Guangshuai Sun, Jiawei Liu, Binzhong Jia, Baixin Liu, Yuzhen Lv. Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil. Sci Discov. 2021;9(6):375-378. doi: 10.11648/j.sd.20210906.27

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  • @article{10.11648/j.sd.20210906.27,
      author = {Guangshuai Sun and Jiawei Liu and Binzhong Jia and Baixin Liu and Yuzhen Lv},
      title = {Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil},
      journal = {Science Discovery},
      volume = {9},
      number = {6},
      pages = {375-378},
      doi = {10.11648/j.sd.20210906.27},
      url = {https://doi.org/10.11648/j.sd.20210906.27},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20210906.27},
      abstract = {With the promoting of transmission voltage level and the continuous fluctuation of operating conditions by connecting renewable energy into the power system, more stringent requirements have been placed on the operation reliability of transformers and other large electrical equipment. Transformer oil, as the main liquid insulating medium in large power equipment, the modification of its insulating performance has always been research focus in dielectric field. Studies have proved that TiO2 nanomaterials can not only enhance the AC and positive impulse breakdown voltage of transformer oil, but also significantly improve the aging resistance of transformer oil. However, the DC breakdown voltage of transformer oil has not been greatly increased yet, and sometime even weakened. In this paper, TiO2 hollow nanoparticles were prepared by hard template method to modify transformer oil. AC and DC breakdown voltage and dielectric permittivity of transformer oil before and after modification were measured and analyzed. The results show that the AC breakdown voltage of the transformer oil can be increased by 32.5%. DC breakdown voltage was increased first and then reduced with the increasing of nanoparticle concentration, while no obvious improvemnet was observed. Based on breakdown mechanism and permittivity of transformer oil, we think the hollow structure of the nanoparticles can significantly enlarge the interface between particle and oil, which greatly promotes the capturing capability to fast electrons and inhibit their migration in the oil, so the AC breakdown voltage are significantly increased. Under DC stress, nanoparticles can capture electrons and meanwhile migrate along fixed direction, which increased electrical conductivity of oil and resulted in lowering of DC breakdown voltage with the increase of nanoparticle concentration.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Modification Effect of TiO2 Hollow Nanoparticles on Insulating Properties of Transformer Oil
    AU  - Guangshuai Sun
    AU  - Jiawei Liu
    AU  - Binzhong Jia
    AU  - Baixin Liu
    AU  - Yuzhen Lv
    Y1  - 2021/11/24
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sd.20210906.27
    DO  - 10.11648/j.sd.20210906.27
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 375
    EP  - 378
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20210906.27
    AB  - With the promoting of transmission voltage level and the continuous fluctuation of operating conditions by connecting renewable energy into the power system, more stringent requirements have been placed on the operation reliability of transformers and other large electrical equipment. Transformer oil, as the main liquid insulating medium in large power equipment, the modification of its insulating performance has always been research focus in dielectric field. Studies have proved that TiO2 nanomaterials can not only enhance the AC and positive impulse breakdown voltage of transformer oil, but also significantly improve the aging resistance of transformer oil. However, the DC breakdown voltage of transformer oil has not been greatly increased yet, and sometime even weakened. In this paper, TiO2 hollow nanoparticles were prepared by hard template method to modify transformer oil. AC and DC breakdown voltage and dielectric permittivity of transformer oil before and after modification were measured and analyzed. The results show that the AC breakdown voltage of the transformer oil can be increased by 32.5%. DC breakdown voltage was increased first and then reduced with the increasing of nanoparticle concentration, while no obvious improvemnet was observed. Based on breakdown mechanism and permittivity of transformer oil, we think the hollow structure of the nanoparticles can significantly enlarge the interface between particle and oil, which greatly promotes the capturing capability to fast electrons and inhibit their migration in the oil, so the AC breakdown voltage are significantly increased. Under DC stress, nanoparticles can capture electrons and meanwhile migrate along fixed direction, which increased electrical conductivity of oil and resulted in lowering of DC breakdown voltage with the increase of nanoparticle concentration.
    VL  - 9
    IS  - 6
    ER  - 

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Author Information
  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, China

  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, China

  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, China

  • School of Electrical and Information Engineering, Tianjin University, Tianjin, China

  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, China

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