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Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits

Received: 31 October 2021    Accepted: 13 November 2021    Published: 17 November 2021
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Abstract

Previous studies on molybdenite are mainly focused on Re-Os dating for a deposit, by contrast there have relatively little on trace elements in molybdenite. On the basis of statistical summarizing the previous research results, this paper discusses the variation of trace elements of molybdenite in various deposits and the combination of the different trace elements in molybdenite of different deposits, which is expected to expand its application in mineral deposit science. The results show that Re and W contents in molybdenite have the potential to be used as tracer to trace its sources. Molybdenite in different types of deposits has different trace elements composition and content, which mainly depends on the ore-forming fluids. Trace elements exist in various states in molybdenite, including isomorphic substitution, inclusion, adsorption and so on. Elements such as Re, W, Se, Te and Nb can enter the molybdenite lattice by replacing Mo or S, while Pb, Zr, Fe and REE those elements mainly appear as mineral inclusions. Most trace elements (for Fe, Cu, Te, etc.) are positively correlated, which may indicate that their sources are in similiar among each other. A few trace elements were negatively correlated with each other, which may reflect the different in their sources.

Published in Science Discovery (Volume 9, Issue 6)
DOI 10.11648/j.sd.20210906.20
Page(s) 335-339
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Molybdenite, Deposit, Trace Elements, Occurrence, Source Material

References
[1] Ciobanu C L, Cook N J, Kelson C R, Guerin R, Kalleske N, Danyushevsky L. 2013. Trace element heterogeneity in molybdenite fingerprints stages of mineralization. Chemical Geology. 347: 175-189.
[2] Stein H J. 2006. Low-rhenium molybdenite by metamorphism in northern Sweden: Recognition, genesis, and global implications. Lithos, 87: 300-327.
[3] 李超,屈文俊,杜安道,周利敏.2012.含有普通锇的辉钼矿Re-Os同位素定年研究.岩石学报,28(2):702-708。
[4] 黄凡,王登红,陈毓川,王成辉,唐菊兴,陈郑辉,王立强,刘善宝,李建康.2013.中国钼矿中辉钼矿的稀土元素地球化学及其应用.中国地质,40(1):287-301。
[5] 王登红,李超,陈郑辉,王成辉,黄凡,屈文俊.2012.辉钼矿在矿床学研究中的新用途(I):稀土元素示踪.吉林大学学报(地球科学版),42(6):1647-1655。
[6] Giles D L, Schiling J H. 1972. Variation in rhenium content of molybdenite. Proc. Internat. Geol. Congr. 24th Session. Section, 10, 145-152.
[7] Newberry R J. 1979. Polytypism in molybdenite (II); Relationships between polytypism, ore deposition/alteration stages and rhenium contents. American mineralogist, 64 (7-8), 768-775.
[8] Todorov T, Staikov M. 1985. Rhenium content in molybdenite from ore mineralizations in Bulgaria. Geologica Balcanica 15 (6), 45-58.
[9] Ishihara S. 1988. Rhenium contents of molybdenites in granitoid-series rocks in Japan. Economic Geology, 83 (5), 1047-1051.
[10] Xiong Y, Wood SA. 2001. Hydrothermal transport and deposition of rhenium under subcritical conditions (up to 200°C) in light of experimental studies. Econ Geol 96: 1429-1444.
[11] Xiong Y, Wood S A. 2002. Experimental determination of the hydrothermal solubility of ReS2 and the Re–ReO2 buffer assemblage and transport of rhenium under supercritical conditions. Geochemical Transactions, 3 (1): 1-10.
[12] Berzina A N, Sotnikov V I, Economou-Eliopoulos M, Eliopoulos D G. 2005. Distribution of rhenium in molybdenite from porphyry Cu–Mo and Mo–Cu deposits of Russia (Siberia) and Mongolia. Ore Geology Reviews, 26 (1-2), 91-113.
[13] McCandless T E, Ruiz J, Campbell A R. 1993. Rhenium behavior in molybdenite in hypogene and near-surface environments: Implications for Re-Os geochronometry. Geochimica et Cosmochimica Acta, 57 (4), 889-905.
[14] Grabezhev A I, Voudouris P C. 2014. Rhenium distribution in molybdenite from the Vosnesensk porphyry Cu±(Mo, Au) deposit (southern Urals, Russia). The Canadian Mineralogist, 52 (4), 671-686.
[15] Stein H J, Markey R J, Morgan J W, Hannah J L, Scherstén A. 2001. The remarkable Re–Os chronometer in molybdenite: how and why it works. Terra Nova, 13 (6): 479-486.
[16] Stein H J, Schersten A, Hannah J, Markey R. 2003. Subgrain-scale decoupling of Re and 187Os and assessment of laser ablation ICP-MS spot dating in molybdenite. Geochimica et Cosmochimica Acta, 67 (19): 3673-3686.
[17] Mao J W, Zhang Z C, Zhang Z H, Du A D. 1999. Re-Os isotopic dating of molybdenites in the Xiaoliugou W (Mo) deposit in the northern Qilian mountains and its geological significance [J]. Geochimica et Cosmochimica Acta, 63 (11-12): 1815-1818.
[18] Blevin P L. 2004. Redox and compositional parameters for interpreting the granitoid metallogeny of eastern Australia: Implications for gold-rich ore systems. Resource Geology, 54 (3), 241-252.
[19] Mao Z H, Cheng Y B, Liu J J, Yuan S D, Wu S H, Xiang X K, Luo X H. 2013. Geology and molybdenite Re-Os age of the Dahutang granite-related veinlets-disseminated tungsten ore field in the Jiangxin province, China. Ore Geol Rev 53: 422-433.
[20] 黄凡,王登红,陈毓川,王成辉,唐菊兴,陈郑辉,王立强,刘善宝,李建康,张长青,应立娟,王永磊,李立兴,李超.2014.中国内生钼矿床辉钼矿的微量元素特征研究. 矿床地质,33(6):1193-1212。
[21] Mao G, Hua R, Gao J, Li W, Zhao K. 2009. Existing forms of REE in gold-bearing pyrite of the Jinshan gold deposit, Jiangxi Province, China. Journal of Rare Earths, 27 (6): 1079-1087.
[22] Sasmaz A, Yavuz F, Sagiroglu A, Akgul B. 2005. Geochemical patterns of the Akdagmadeni (Yozgat,Central Turkey) fluorite deposits and implications.Journal of Asian Earth Sciences, 24 (4): 469-479.
[23] 毕献武,胡瑞忠,彭建堂,吴开兴.2004.黄铁矿微量元素地球化学特征及其对成矿流体性质的指示.矿物岩石地球化学通报,23(1),1-4.
[24] Blevin P, Jackson S. 1998. Potential applications of LAM-ICP-MS technology in economic geology: a preliminary study of molybdenite and pyrite. (Abstract, 14th) Australian Geological Convention, Townsville, pp. 6-10.
[25] Pašava, J., Svojtka, M., Veselovský, F., Ďurišová, J., Ackerman, L., Pour, O.,... & Haluzová, E. 2016. Laser ablation ICPMS study of trace element chemistry in molybdenite coupled with scanning electron microscopy (SEM)—an important tool for identification of different types of mineralization. Ore Geology Reviews, 72, 874-895.
[26] Zhao X Y, Zhong H, Mao W, Bai Z J, Xue K. 2020. Molybdenite Re-Os dating and LA-ICP-MS trace element study of sulfide minerals from the Zijinshan high-sulfidation epithermal Cu-Au deposit, Fujian Province, China. Ore Geology Reviews, 118, 103363.
[27] Drummond S E, Ohmoto H. 1985. Chemical evolution and mineral deposition in boiling hydrothermal systems. Economic Geology, 80 (1): 126-147.
[28] Tuomo O T, Randolph A K. 2005. Gold enrichment and the Bi–Au association in pyrrhotite-rich massive sulfide deposits, Escanaba Trough, Southern Gorda Ridge. Econ. Geol. 100, 1135-1150.
[29] Newberry, R.J., 1998. W- and Sn-skarn Deposits: A 1998 Status Report: Mineralogical Association of Canada Short Course Series, 26, pp. 289-335.
[30] Wang P, Pan Z L, Weng L B. 1982. Systematic Mineralogy, vol. I, Geological Publishing House, Beijing p. 666, (in Chinese).
[31] Ciobanu C L, Cook N J, Pring A, Brugger J, Danushevsky L, Shimizu M. 2009b. “Invisible gold” in bismuth chalcogenides. Geochimica et Cosmochimica Acta 73: 1970-1999.
[32] Drábek M, Kvaček M, Korečková J, Weiss D. 1989. Tellurium contents in molybdenites from the Bohemian Massif (in Czech). Věstn. Ústředního Ustavu Geol. 64: 43-46.
[33] Norman M, Bennett V, Blevin P, McCulloch M. 2004. New Re-Os ages of molybdenite. from granite-related deposits of Eastern Australia using an improved multi-collector. In Geological Society of Australia abstracts (Vol. 74, pp. 129-132). Geological Society of Australia; 1999.
[34] Voudouris P, Melfos V, Spry P G, Bindi L, Moritz R, Ortelli M, Kartal T. 2013. Extremely Re-rich molybdenite from porphyry Cu-Mo-Au prospects in Northeastern Greece: mode of occurrence, causes of enrichment, and implications for gold exploration. Minerals, 3: 165-191.
[35] Cox R A, Bédard L P, Barnes S J, Constantin M. 2007. Selenium distribution inmagmatic sulfide minerals. DIVEX Rapport Annuel 2007, Project SC 26, 11 pp. Québec, Canada.
[36] Drábek M. 1995. The Mo-Se-S and Mo-Te-S systems. Neues Jb. Mineral. Abh. 169, 255-263.
[37] Povarennykh A S. 1972. Crystal Chemical Classification of Minerals. Plenum Press, New. York and London (766 pp.).
[38] Ødegård M. 1984. A selenium-rich sulphide assemblage in the Caledonides of northern. Norway. Nor. Geol. Tidsskr. 64, 187-292.
[39] Mao J W, Zhang Z H, Zhang Z C, Yang J M, Wang Z L, Du A D. 1999. Re-Os age dating of molybdenites in the Xiaoliugou tungsten deposit in the northern Qilian Mountains and its significance. Geological Review, 45 (4), 412-417.
[40] 孙鹏程,李超,周利敏,屈文俊,孙豪,李欣尉,赵鸿,杜安道.2021.中国斑岩铜(钼)矿床中辉钼矿Re含量变化及控制因素.矿床地质,40(2):273-292。
[41] Holland H D, Turekian K K. 2003. Treatise on geochemistry. Oxford: Elsevier-pergamon, 5: 348-349.
[42] Plotinskya O P, Abramova V D, Bondar D, Seltmann R, Spratt J. 2019. Porphyry Cu(Mo) deposits of the Urals: insights from molybdenite trace element geochemistry. Proceedings of the 15th SGA Biennial Meeting, 27-30 August 2019, Glasgow, Scotland. pp. 1019-1022.
[43] Frondel J W, Wickman F E. 1970. Molybdenite polytypes in theory and occurrence. II. Some naturally-occurring polytypes of molybdenite. Am. Mineral. 55: 1857-1875.
[44] Lin Y, Liu T, Yang Y, Wei G, Pan Z, Tan B. 2014. Petrogenesis of bismuth minerals in the dabaoshan pb-zn polymetallic massive sulfide deposit, northern guangdong province, china. Journal of Asian Earth Sciences, 82 (mar.15), 1-9.
[45] Liu Y J, Cao L M, Liu Z L. 1984. Elementary Geochemistry. Geological Publishing House, Beijing, p. 548, (in Chinese).
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    Sun Pengcheng, Li Chao, Zhou Limin, Qu Wenjun, Li Xinwei, et al. (2021). Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits. Science Discovery, 9(6), 335-339. https://doi.org/10.11648/j.sd.20210906.20

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    ACS Style

    Sun Pengcheng; Li Chao; Zhou Limin; Qu Wenjun; Li Xinwei, et al. Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits. Sci. Discov. 2021, 9(6), 335-339. doi: 10.11648/j.sd.20210906.20

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    AMA Style

    Sun Pengcheng, Li Chao, Zhou Limin, Qu Wenjun, Li Xinwei, et al. Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits. Sci Discov. 2021;9(6):335-339. doi: 10.11648/j.sd.20210906.20

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  • @article{10.11648/j.sd.20210906.20,
      author = {Sun Pengcheng and Li Chao and Zhou Limin and Qu Wenjun and Li Xinwei and Zhao Hong and Du Andao},
      title = {Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits},
      journal = {Science Discovery},
      volume = {9},
      number = {6},
      pages = {335-339},
      doi = {10.11648/j.sd.20210906.20},
      url = {https://doi.org/10.11648/j.sd.20210906.20},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20210906.20},
      abstract = {Previous studies on molybdenite are mainly focused on Re-Os dating for a deposit, by contrast there have relatively little on trace elements in molybdenite. On the basis of statistical summarizing the previous research results, this paper discusses the variation of trace elements of molybdenite in various deposits and the combination of the different trace elements in molybdenite of different deposits, which is expected to expand its application in mineral deposit science. The results show that Re and W contents in molybdenite have the potential to be used as tracer to trace its sources. Molybdenite in different types of deposits has different trace elements composition and content, which mainly depends on the ore-forming fluids. Trace elements exist in various states in molybdenite, including isomorphic substitution, inclusion, adsorption and so on. Elements such as Re, W, Se, Te and Nb can enter the molybdenite lattice by replacing Mo or S, while Pb, Zr, Fe and REE those elements mainly appear as mineral inclusions. Most trace elements (for Fe, Cu, Te, etc.) are positively correlated, which may indicate that their sources are in similiar among each other. A few trace elements were negatively correlated with each other, which may reflect the different in their sources.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Characteristics of Trace Elements in Molybdenite and Its Application in Mineral Deposits
    AU  - Sun Pengcheng
    AU  - Li Chao
    AU  - Zhou Limin
    AU  - Qu Wenjun
    AU  - Li Xinwei
    AU  - Zhao Hong
    AU  - Du Andao
    Y1  - 2021/11/17
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sd.20210906.20
    DO  - 10.11648/j.sd.20210906.20
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 335
    EP  - 339
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20210906.20
    AB  - Previous studies on molybdenite are mainly focused on Re-Os dating for a deposit, by contrast there have relatively little on trace elements in molybdenite. On the basis of statistical summarizing the previous research results, this paper discusses the variation of trace elements of molybdenite in various deposits and the combination of the different trace elements in molybdenite of different deposits, which is expected to expand its application in mineral deposit science. The results show that Re and W contents in molybdenite have the potential to be used as tracer to trace its sources. Molybdenite in different types of deposits has different trace elements composition and content, which mainly depends on the ore-forming fluids. Trace elements exist in various states in molybdenite, including isomorphic substitution, inclusion, adsorption and so on. Elements such as Re, W, Se, Te and Nb can enter the molybdenite lattice by replacing Mo or S, while Pb, Zr, Fe and REE those elements mainly appear as mineral inclusions. Most trace elements (for Fe, Cu, Te, etc.) are positively correlated, which may indicate that their sources are in similiar among each other. A few trace elements were negatively correlated with each other, which may reflect the different in their sources.
    VL  - 9
    IS  - 6
    ER  - 

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Author Information
  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

  • Key Laboratory of Re-Os Isotope Geochemistry, China Geological Survey, National Geological Experiment and Test Center, Beijing, China

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