Zinc oxide with neodymium ions nanomaterials were synthesized by using the chemical synthesis method. The materials were characterized by XRD, FTIR, TEM, SEM and spectral analysis. From XRD, TEM and SEM images, the estimated average particle size are 20, 100 and 200nm respectively. Nearly hexagonal shapes for the dark spots in the TEM images indicate that the ZnO nanoparticles are almost hexagonal. SEM demonstrates clearly the formation of cluster type of ZnO nanoparticles and change of the morphology of the nanoparticles with the Nd3+ different ions concentration. UV- Visible absorption spectrum of the ZnO:Nd3+ nanomaterial was analyzed on the basis of Judd-Ofelt (J-O) theory. Nine absorption and four fluorescence bands have been observed at room temperature. Energy interaction and intensity parameters have been computed Fluorescence band have been assigned to transitions 4F3/2 → 4I9/2, 4F3/2 →4I11/2, 4F3/2 →4I13/2, and 4F3/2 →4I15/2. The radiative properties were computed using the J-O intensity parameters and fluorescence data. The value of emission cross-section is an important parameter and signifies the rate of energy extraction from the optical material.
| Published in | American Journal of Nanosciences (Volume 7, Issue 3) |
| DOI | 10.11648/j.ajn.20210703.11 |
| Page(s) | 49-53 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Absorption and Fluorescence Spectrum, Judd-Ofelt (J-O) Parameters, Radiative Properties
| [1] | Erik Gregersen, Vitalij K. Pecharsky, Encyclopedia Britannica; (Jan 17, 2019). |
| [2] | Wang Y. S., Thomas P. J., and ’Brien P. O.: J. Phys. Chem. B, 110, 21412, (2006). |
| [3] | Greene L., Law M., Tan D. H., Goldberger J., Yang P.: Nano Lett., 1231, (2005). |
| [4] | Suchea M., Christoulakis, Moschovis S., Katsarakis K., Kiriakidis N.: ZnO transparent thin films for gas sensor applications. Thin Solid Films. 515, 551, (2006). |
| [5] | Ashour A., Kaid M. A., El-Syed N. Z., Ibrahim A. A.: Physical properties of ZnO thin films deposited by spray pyrolysis technique. Appl. Surf. Sci. 252, 7844–7848, (2006). |
| [6] | Chen J. C., Tang C. T.: Preparation and application of granular ZnO/Al2O3 catalyst for the removal of hazardous trichloroethylene. J. Hazard. Mater. 142, 88–9, (2007). |
| [7] | Judd B. R.: Phys. Rev., 12, 750-761, (1962). |
| [8] | Ofelt G. S.: J. Chem. Phys., 37, 511-520, (1962). |
| [9] | Shinde K. N.: Phosphate Phosphors for Solid-State Lighting, Springer Series in Materials Science 174, (2013). |
| [10] | Daksh D. and Agrawal Y. K.: Rare Earth-Doped Zinc Oxide Nanostructures: A Review; American scientific publishers; Reviews in Nanoscience and Nanotechnology; Vol. 5, pp. 1–27, (2016). |
| [11] | Urban J., Haram S. K., Gosavi S. W. and Kulkarni S. K.: Pramana, 65, 615, (2005). |
| [12] | Koch U., Fojtik A., Weller H. and englein A.: Chem. Phys. Lett., 122, 507, (1985). |
| [13] | Sharma K. Y., Pal S., GoyalP. and Bind C. U.: AIP Conference Proceedings 1728-1732 (2016). |
| [14] | Zhang J., Deng J. S., Liu Y. S., Chen M. J., Han Q. B., Wang Y. and Wang D. Y.: Preparation and photocatalytic activity of Nd doped ZnO nanoparticles, Advanced Performance Materials Volume 29 (2014). |
| [15] | Mai M. A. Ahmed, Wael Z. Tawfik, M. A. K. Elfayoum; Tailoring the optical and physical properties of La doped ZnO nanostructured thin films, journal of alloy and compound, Volume 791, Pages 586-592 (2019). |
| [16] | Prathibha Vasudevan, Viji Vidyadharan, Sanu Mathew Simon, Unnikrishnan N. V; Phytochemical mediated synthesis of ZnO:Dy3+ nanophosphors: JuddeOfelt analysis, structural and spectroscopic properties; Journal of Science: Advanced Materials and Devices (in press -Accepted 3 May 2020). |
| [17] | Anwar F. and Farrrukh A. M: “Synthesis, Charactrization and Photocatalytic Application of Gd Doped ZnO Nanoparticles”, Asian journal of Chemistry, Vol. 27 No. 10, 3571-3574, 10 (2015). |
| [18] | Odireleng Martin Ntwaeaborwad, Sefako J. Mofokenga, Vinod Kumarb, Robin E. Kroon; Structural, optical and photoluminescence properties of Eu3+ doped ZnO nanoparticles, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 42-49, 182 (2017). |
| [19] | K. Ravichandrika, P. Kiranmayi, R. V. S. S. N. Ravikumar, Synthesis, characterization andantibacterial activity of ZnO nanoparticles, Int. J. Pharm. Pharm. Sci. 4 (4) 336–338 (2012). |
| [20] | X. Liu, J. Zhang, L. Wang, T. Yang, X. Guo, S. Wu, S. Wang, 3D hierarchically porousZnO structures and their functionalization by au nanoparticles for gas sensors, J. Mater. Chem. 21 349–356 (2011). |
| [21] | S. Husain, F. Rahman, N. Ali, P. A. Alvi, Nickel sub-lattice effects on the optical prop-erties of ZnO nanocrystals, J. Optoelectron. Eng. 1 (1) 28–32 (2013). |
| [22] | Sharma Y. K., Pal S., Goyal P. and Verma L. P.: “Fluorescence Studies of ZnO Nanomaterial with Samarium Ion” J. Chem. Eng. Chem. Res. Vol. 3, No. 11, 2016, pp. 1027-1030 (2016). |
| [23] | Shuichi Yamagata, Yusuke Hamba, Ko Nakanishi, Shigeaki Abe, Tsukasa Akasaka, Natsumi Ushijima, Motohiro Uo, Junichiro Iida, And Fumio Watari; Introduction of Rare-Earth-Element- Containing ZnO Nanoparticles into Orthodontic Adhesives, Nano Biomedicine 4 (1), 11-17, 2012. |
| [24] | Omata T., Fujiwara H., Otsuka- S. Yao-Matsuo, Ono N.: Appl. Phys. A, 71 609 (2000). |
| [25] | Sharma Y. K.,. Surana S. S. L,. Dubedi R. P and Joshi V.: Spectroscopic and radiative properties of Sm3+ doped zinc fluoride borophosphate glasses; Mat. Sci. and Engg. (France) B119, 131 (2005). |
| [26] | Sharma Y. K., Dubedi R. P., Joshi V., Karnataka K. B. and Surana S. S. L.: Absorption studies of tripositive praseodymium and neodymium doped zinc fluoride borophosphate (ZFBP) glasses; Indian J. Eng. and Mat. Sci. (India) 12, 65 (2005). |
| [27] | Surana S. S. L., Gehlot C. L., Tandon S. P. and. Sharma Y. K: Fluorescence of Sm3+, Eu3+, Tb3+, Ho3+ and Er3+ doped borophosphate glasses; Can. J. Analytical Sciences and Spectroscopy (Canada) 48, 285-294 (2003). |
APA Style
Sudha Pal, Yogesh Kumar Sharma, Jitendra Pal Singh. (2021). Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial. American Journal of Nanosciences, 7(3), 49-53. https://doi.org/10.11648/j.ajn.20210703.11
ACS Style
Sudha Pal; Yogesh Kumar Sharma; Jitendra Pal Singh. Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial. Am. J. Nanosci. 2021, 7(3), 49-53. doi: 10.11648/j.ajn.20210703.11
AMA Style
Sudha Pal, Yogesh Kumar Sharma, Jitendra Pal Singh. Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial. Am J Nanosci. 2021;7(3):49-53. doi: 10.11648/j.ajn.20210703.11
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Download@article{10.11648/j.ajn.20210703.11,
author = {Sudha Pal and Yogesh Kumar Sharma and Jitendra Pal Singh},
title = {Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial},
journal = {American Journal of Nanosciences},
volume = {7},
number = {3},
pages = {49-53},
doi = {10.11648/j.ajn.20210703.11},
url = {https://doi.org/10.11648/j.ajn.20210703.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20210703.11},
abstract = {Zinc oxide with neodymium ions nanomaterials were synthesized by using the chemical synthesis method. The materials were characterized by XRD, FTIR, TEM, SEM and spectral analysis. From XRD, TEM and SEM images, the estimated average particle size are 20, 100 and 200nm respectively. Nearly hexagonal shapes for the dark spots in the TEM images indicate that the ZnO nanoparticles are almost hexagonal. SEM demonstrates clearly the formation of cluster type of ZnO nanoparticles and change of the morphology of the nanoparticles with the Nd3+ different ions concentration. UV- Visible absorption spectrum of the ZnO:Nd3+ nanomaterial was analyzed on the basis of Judd-Ofelt (J-O) theory. Nine absorption and four fluorescence bands have been observed at room temperature. Energy interaction and intensity parameters have been computed Fluorescence band have been assigned to transitions 4F3/2 → 4I9/2, 4F3/2 →4I11/2, 4F3/2 →4I13/2, and 4F3/2 →4I15/2. The radiative properties were computed using the J-O intensity parameters and fluorescence data. The value of emission cross-section is an important parameter and signifies the rate of energy extraction from the optical material.},
year = {2021}
}
TY - JOUR T1 - Spectral, Structural and Characterization of NeodymiumIons Doped Zinc Oxide Nanomaterial AU - Sudha Pal AU - Yogesh Kumar Sharma AU - Jitendra Pal Singh Y1 - 2021/09/04 PY - 2021 N1 - https://doi.org/10.11648/j.ajn.20210703.11 DO - 10.11648/j.ajn.20210703.11 T2 - American Journal of Nanosciences JF - American Journal of Nanosciences JO - American Journal of Nanosciences SP - 49 EP - 53 PB - Science Publishing Group SN - 2575-4858 UR - https://doi.org/10.11648/j.ajn.20210703.11 AB - Zinc oxide with neodymium ions nanomaterials were synthesized by using the chemical synthesis method. The materials were characterized by XRD, FTIR, TEM, SEM and spectral analysis. From XRD, TEM and SEM images, the estimated average particle size are 20, 100 and 200nm respectively. Nearly hexagonal shapes for the dark spots in the TEM images indicate that the ZnO nanoparticles are almost hexagonal. SEM demonstrates clearly the formation of cluster type of ZnO nanoparticles and change of the morphology of the nanoparticles with the Nd3+ different ions concentration. UV- Visible absorption spectrum of the ZnO:Nd3+ nanomaterial was analyzed on the basis of Judd-Ofelt (J-O) theory. Nine absorption and four fluorescence bands have been observed at room temperature. Energy interaction and intensity parameters have been computed Fluorescence band have been assigned to transitions 4F3/2 → 4I9/2, 4F3/2 →4I11/2, 4F3/2 →4I13/2, and 4F3/2 →4I15/2. The radiative properties were computed using the J-O intensity parameters and fluorescence data. The value of emission cross-section is an important parameter and signifies the rate of energy extraction from the optical material. VL - 7 IS - 3 ER -
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