Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes
Colloid and Surface Science
Volume 3, Issue 2, June 2018, Pages: 12-21
Received: Apr. 27, 2018;
Accepted: May 31, 2018;
Published: Sep. 13, 2018
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Olaseni Segun Esan, Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
Bankole Owolabi Mutolib, Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
Aboluwoye Christopher Olumuyiwa, Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
Owoyomi Olarenwaju, Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria
Oyeneyin Oluwatoba Emmanuel, Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria
The current research work centred on the micellization of binary system of Cetylpyridinium chloride (CpyCl) and cetyltrimethylammonium bromide (CTABr) in the absence and presence of nonionic hydrotropes (i.e urea and resorcinol) using conductometric technique. The critical micelle concentrations (CMC), at different mixed mole fraction of mixed surfactant were evaluated. Activity coefficient, ideal CMC, micellar mole fraction, interaction and thermodynamic parameters were obtained using theoretical Clint and Rubingh models.Addition of hydrotropes lowered the CMC values than the ideal CMC values and the individual components which is an indication of positive synergistic interaction in CpyCl/CTABr mixed micelle formation. The interaction parameter values were all negative, signifying strong interaction between the mixed surfactant. The evaluated thermodynamic parameters were all negative, indicating spontaneity and stability of the mixed micelle formed.
Olaseni Segun Esan,
Bankole Owolabi Mutolib,
Aboluwoye Christopher Olumuyiwa,
Oyeneyin Oluwatoba Emmanuel,
Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes, Colloid and Surface Science.
Vol. 3, No. 2,
2018, pp. 12-21.
Mandeep SB, Singh J, Kulbir S, Kaur G Mixed micelles of cationic gemini with tetraalkyl ammonium and phosphonium surfactants: the head group and hydrophobic tail contributions. J. Colloids and Surfaces A: Physicochem. Eng. Aspects. 2004; 234: 77–84.
Christian SD, Scamhorn JF. Solubilization in Surfactant Aggregates, volume 55, Dekker, New York, 1995.
Haque ME, Das AR, Rakshit AK, Moulik SP. Properties of Mixed Micelles of Binary Surfactant Combinations. Langmnir 1996; 12: 4084-4089.
Ali A, Nabi F, Malik NA, Tasneem S, Uzairs.Study of micellization of sodium dodecyl sulfate in non-aqueous media containing lauric acid and dimethylsulfoxide. J. Surfactants Deterg 2014; 17: 151-160.
Ali A, Malik NA, Farooq U, Tasneem S, Nabi F. Interaction of cetrimide with nonionic surfactant-Triton X-100 and Brijj-35: A Conductrimetric and Tensiometric study. J. Surfact Deterg 2016; 29: 527-442.
Junquera E, Lourdes P, Emilio A. Micellar Behavior of the Aqueous Solutions of Dodecylethyldimethylammonium Bromide. A Characterization Study in the Presence and Absence of Hydroxypropyl-β-cyclodextrin. Langmuir 1997; 13: 219-224.
Rosen MJ.Synergism in mixtures containing zwitterionic surfactants. Langmuir 1991; 7:885–888.
Tsujii K, Saito N, Takeuchi T.Krafft points of anionic surfactants and their mixtures with special attention to their applicability in hard water. J Phys Chem 1980; 84:2287–2291.
Osborne-Lee IW, Schechter RS, Wade WH, Barakat Y.A new theory and new results for mixed nonionic-anionic micelles. J Colloid Interface Sci 1985; 108:60–74.
Holland PM, Rubingh DN (eds) (1992) Mixed surfactant systems. American Chemical Society, Washington DC.
Amante JC, Scamehorn JF, Harwell JH.Precipitation of mixtures of anionic and cationic surfactants. II. Effect of surfactant structure, temperature, and pH. J Colloid Interface Sci 1991; 144:243–253.
Picullel L, Lindman B.Association and segregation in aqueous polymer/polymer, polymer/surfactant, and surfactant/surfactant mixtures: similarities and differences. Adv Colloid Interface Sci 1992; 41:149–178.
Attwood D, Patel HK.Mixed micelles of alkyltrimethylammonium bromides and chlorhexidine digluconate in aqueous solution. J Colloid Interface Sci 1989; 129:222–230.
Bury R, Treiner C, Chevalet C, Makayssi A.Peculiar solubilization thermodynamics of pentan-1-ol in mixed surfactant solutions of benzyldimethyltetradecylammonium chloride and trimethyltetradecylammonium chloride: a calorimetric investigation. Anal Chim Acta 1991; 251:69–77.
Chakraborty T, Ghosh S, Moulik SP. Micellization and Related Behavior of Binary and Ternary Surfactant Mixtures in Aqueous Medium: Cetyl Pyridinium Chloride (CPC), Cetyl Trimethyl Ammonium Bromide (CTAB), and Polyoxyethylene (10) Cetyl Ether (Brij-56) Derived System. J. Phys. Chem. B 2005; 109: 14813-14823.
Aswal VK, Goyal PS. Small-Angle Neutron-Scattering and Viscosity Studies of CTAB/NaSal Viscoelastic Micellar Solutions. J. Phys. Chem. B 1998; 102: 2469-2473.
Kim WJ, Yang SM. Effects of Sodium Salicylate on the Microstructure of an Aqueous Micellar Solution and Its Rheological Responses. J. Colloid Interface Sci. 2000; 232: 225-234.
Hassan PA, Raghavan SR, Kaler EW. Microstructural Changes in SDS Micelles Induced by Hydrotropic Salt. Langmuir 2002; 18:2543-2548.
Garg G,Hassan PA,Aswal VK, Kulshreshtha SK. Tuning the Structure of SDS Micelles by Substituted Anilinium Ions. J. Phys. Chem. B 2005; 109: 1340-1346.
Influence of ionic and nonionic hydrotropes on micellar behavior of a cationic gemini surfactant butanediyl-1,4-bis(dimethylcetylammonium bromide). J. Colloid Interface Sci. 2011; 359:467–473.
Clint JH. Micellization of mixed nonionic surface active agents. J Chem Soc Faraday Trans I 1975; 71: 1327-1334.
Rubingh DN. Mixed micelle solutions. In: Mittal KL (ed) Solution chemistry of surfactants. Plenum, New York, 1979; p 337.
Rosen MJ, Dahanayake M.Industrial utilization of surfactant Principles and practice. AOCS press, Champaign, IL, 2000.
Kabir-Ud D, Koya PA. Effect of acetrinitride on the micellization and the thermodynamic parameters of tetradecyltrimethylammonium bromide: Conductometric and fluorimetric studies. J.Mol. Liq. 2011; 158:111-116.
Khan F, Mohamad SS, Malik AR, Naved A, Asiri AM. (2016) Antidepressant drug amitriptyline hydrochloride (AMT) interaction with anionic surfactant sodiumdodecyl sulfate in aqueous / brine / urea. J. Mol. Liq. 2016; 222:1020-1030
Rosen M.J. Surfactant and interfacial phenomena, 3rd edn, Wiley-interscience, New York, 2004.
Hao LS, Deng YT, Zhou LS, Ye H, Nan YQ, Hu P. mixed micellization and the dissociated Margules model for cationic / anionic surfactant systems. J. Phys. Chem B 2012; 116: 5213-5225.
Nabel AN, Ahmed MES. Interaction between cationic and convectional nonionic surfactants in mixed micelle and monolayer formed in aqueous medium. Quim. Nova 2011; 34: 1007-1013.
Romsted LS, Zhang J,Politi IM, Chaimorich H.Concentration of Urea in Interfacial Regions of Aqueous Cationic, Anionic, and Zwitterionic Micelles Determined by Chemical Trapping.Langmuir 2003; 19: 9179-9190.
Romsted LS Do Amphiphile Aggregate Morphologies and Interfacial Compositions Depend Primarily on Interfacial Hydration and Ion-Specific Interactions? The Evidence from Chemical Trapping. Langmuir 2007; 23: 414-424.
Clint JH, Walker TJ.Thermodynamics of micellization of homologous series of n-alkyl methyl sulphoxides and n-alkyl(dimethyl)phosphine oxides J. Chem. Soc. Faraday Trans. 1975;71: 946-954.