Colloid and Surface Science
Volume 2, Issue 4, December 2017, Pages: 137-142
Received: May 22, 2017;
Accepted: May 25, 2017;
Published: Oct. 13, 2017
Views 2073 Downloads 148
Omer Ahmed, Nanotechnology and MEMS Laboratory, Department of Mechanical, Industrial, and Manufacturing Engineering (MIME), The University of Toledo, Toledo, USA
Sorin Cioc, Nanotechnology and MEMS Laboratory, Department of Mechanical, Industrial, and Manufacturing Engineering (MIME), The University of Toledo, Toledo, USA
Carmen Cioc, Department of Engineering Technology, The University of Toledo, Toledo, USA
Ahalaptiya H. Jayatissa, Nanotechnology and MEMS Laboratory, Department of Mechanical, Industrial, and Manufacturing Engineering (MIME), The University of Toledo, Toledo, USA
This paper presents tribological behavior of titanium nitride and molybdenum sulfide thin film coatings on a workpiece. The titanium nitride films were coated by RF magnetron sputtering method and molybdenum sulfide films were coated by vacuum thermal evaporation. Titanium nitride is a hard ceramic materials, which has excellent mechanical properties. However, the friction coefficient of titanium nitride is rather high. To improve the tribological properties of the titanium nitride films, a thin layer of molybdenum sulfide was coated as a solid lubricant. The results showed a substantial decrease in the coefficient of friction of dual-layered MoS2 over TiN compared with the titanium nitride film or as-received aluminum substrate. The low coefficient of friction can directly be correlated to the MoS2 layer whereas the TiN film acts as a robust and durable base material. The coefficient of friction was measured using a pin on a disc tribometer with a steel pin as the counter face. Our results demonstrated that the coating of MoS2 over TiN has a low coefficient of friction. In addition, it was also found that wear resistance of MoS2 coated TiN was better than both MoS2 and TiN films.
Ahalaptiya H. Jayatissa,
Tribological Properties of Multilayer TiN and MoS2 Thin Films, Colloid and Surface Science.
Vol. 2, No. 4,
2017, pp. 137-142.
X. T. Zenga, S. Zhangb, C. Q. Sunc, Y. C. Liua, Nanometric-layered CrN/TiN thin films: mechanical strength and thermal stability, Thin Solid Films, 424 (2003) 99–102
J. Li, X. Zeng, T. Ren and E. Heide, The Preparation of Graphene Oxide and Its Derivatives and Their Application in Bio-Tribological Systems, Lubricants 2 (2014)137-161.
Muratore, C., Voevodin, A. A., Hu, J. J., Zabinski, J. S.: Multilayered YSZ-Ag-Mo/TiN adaptive tribological nanocomposite coatings. Tribology Letters 24, 201-206 (2006).
S. K. Field, M. Jarratt, D. G. Teer, Tribological properties of graphite-like and diamond-like carbon coatings, Tribology International, 37 (2004) 949–956.
Abadias, G., Michel, A., Tromas, C., Jaouen, C., Dub, S. N.: Stress, interfacial effects and mechanical properties of nanoscale multilayered coatings. Surface & Coatings technology 202, 844-853 (2007).
G. Ma, L. Wang, H. Gao, J. Zhang, and T. Reddyhoff, The friction coefficient evolution of a TiN coated contact during sliding wear, Applied Surface Science, 345 (2015) 109–115.
J. L. Mo and M. H. Zhu, Tribological oxidation behaviour of PVD hard coatings. Tribology International 42(2009)1758-1764.
M. Gubischa, Y. Liub, L. Spiessa, H. Romanusa, S. Krischokb, G. Eckec, J. A. Schaeferb, Ch. Knedlika, Nanoscale multilayer WC/C coatings developed for nanopositioning: Part I. Microstructures and mechanical properties, Thin Solid Films, 488 (2005) 132–139
Rivera-Tello, C. D., Broitman, E., Flores-Ruiz, F. J., Jimenez, O., Flores, M.: Mechanical properties and tribological behavior at micro and macro-scale of WC/WCN/W hierarchical multilayer coatings. Tribology International 101, 194-203 (2016).
Sangiovanni, D. G.: Transition metal nitrides: Alloy design and surface transport properties using Ab-initio and classical computational methods. Linkoping Studies in Science and Technology, dissertation no. 1513 (2013).
Kelly, P. J., Braucke, T., Liu, Z., Arnell, R. D., Doyle, E. D.: Pulsed DC titanium nitride coatings for improved tribological performance and tool life. Surface & Coatings Technology 202, 774-780 (2007).
Haider, J., Rahman, M., Corcoran, B., Hashmi, M. S. J.: Deposition and characterization of hard- solid lubricant coating by closed field magnetron sputtering. Surface & Coatings Technology 200, 1080-1083 (2005).
Shriver, D. F., Atkins, P. W., Overton, T. L., Rourke, J. P., Weller, M. T., Armstrong, F. A.: Inorganic Chemistry. New York: W. H. Freeman (2006).
Gangopadhyay, S., Acharya, R., Chattopadhyay, A. K., Paul, S.: Effect of substrate bias voltage on structural and mechanical properties of pulsed DC magnetron sputtered TiN-MoSx composite coatings. Vacuum 84, 843-850 (2010).
Rahman, M., Haider. J., Dowling, D. P., Duggan, P., Hashmi, M. S. J.: Deposition of magnetron sputtered TiN + MoSx coating with Ti-TiN graded interlayer. Surface & Coatings Technology 200, 1071-1075 (2005).
Jing, Y., Luo, J., Pang, S.: Effect of Ti or TiN co deposition on the performance of MoS2-based composite coatings. Thin Solid Films 461, 288–293 (2004).
Bhaduri, D., Kumar, R., Jain, A. K., Chattopadhyay, A. K.: On tribological behavior and application of TiN and MoS2-Ti composite coating for enhancing performance of monolayer cBN grinding wheel. Wear 268, 1053-1065 (2010).
Xu, G., Zhou, Z., Liu, J., Ma, X.: An investigation of fretting behavior of ion-plated TiN, magnetron sputtered MoS2 and their composite coatings. Wear 225-229, 46-52 (1999).
C. G. Dunckle, M. Aggleton, J. Glassman, P. Taborek, Friction of molybdenum sulfide–titanium films under cryogenic vacuum conditions, Tribology International 44 (2011) 1819–1826
Goller, R., Torri, P., Baker, M. A., Gilmore, R., Gissler W.: The deposition of low friction TiN-MoSx hard coatings by a combined arc evaporation and magnetron sputter process. Surface coatings and technology 120-121, 453-457 (1999).
Budynas, R., Nisbett, K.: Shigley’s mechanical engineering design. McGraw-Hill series in mechanical engineering, 10th edition, 3.19 (2014).
Avallone, E., Baumeister, T: Mark’s standard handbook for mechanical engineers, 10th Ed., McGraw Hill, 6-53 – 6-60.