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Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped

Received: 27 October 2016     Accepted: 10 November 2016     Published: 30 December 2016
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Abstract

In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.

Published in International Journal of Science and Qualitative Analysis (Volume 2, Issue 3)
DOI 10.11648/j.ijsqa.20160203.13
Page(s) 36-40
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Li (Ni1/3Co1/3Mn1/3) OH2, Battery Li-ion, LiCoO2, α-Type Layer NaFeO2

References
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Cite This Article
  • APA Style

    Gharibi El Khadir, Hatim Oumaima, El Bekkaye Yousfi, Oumnih Safae, Abou-salama Mohamed. (2016). Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. International Journal of Science and Qualitative Analysis, 2(3), 36-40. https://doi.org/10.11648/j.ijsqa.20160203.13

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    ACS Style

    Gharibi El Khadir; Hatim Oumaima; El Bekkaye Yousfi; Oumnih Safae; Abou-salama Mohamed. Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. Int. J. Sci. Qual. Anal. 2016, 2(3), 36-40. doi: 10.11648/j.ijsqa.20160203.13

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    AMA Style

    Gharibi El Khadir, Hatim Oumaima, El Bekkaye Yousfi, Oumnih Safae, Abou-salama Mohamed. Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped. Int J Sci Qual Anal. 2016;2(3):36-40. doi: 10.11648/j.ijsqa.20160203.13

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  • @article{10.11648/j.ijsqa.20160203.13,
      author = {Gharibi El Khadir and Hatim Oumaima and El Bekkaye Yousfi and Oumnih Safae and Abou-salama Mohamed},
      title = {Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped},
      journal = {International Journal of Science and Qualitative Analysis},
      volume = {2},
      number = {3},
      pages = {36-40},
      doi = {10.11648/j.ijsqa.20160203.13},
      url = {https://doi.org/10.11648/j.ijsqa.20160203.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsqa.20160203.13},
      abstract = {In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped
    AU  - Gharibi El Khadir
    AU  - Hatim Oumaima
    AU  - El Bekkaye Yousfi
    AU  - Oumnih Safae
    AU  - Abou-salama Mohamed
    Y1  - 2016/12/30
    PY  - 2016
    N1  - https://doi.org/10.11648/j.ijsqa.20160203.13
    DO  - 10.11648/j.ijsqa.20160203.13
    T2  - International Journal of Science and Qualitative Analysis
    JF  - International Journal of Science and Qualitative Analysis
    JO  - International Journal of Science and Qualitative Analysis
    SP  - 36
    EP  - 40
    PB  - Science Publishing Group
    SN  - 2469-8164
    UR  - https://doi.org/10.11648/j.ijsqa.20160203.13
    AB  - In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.
    VL  - 2
    IS  - 3
    ER  - 

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Author Information
  • Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco

  • Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco

  • Superior Institution of Health Professions and Nursing Techniques, Oujda, Morocco

  • Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco

  • Multidisciplinary Faculty of Nador, Nador, Morocco

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