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Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example

Received: 22 November 2018    Accepted: 17 December 2018    Published: 22 January 2019
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Abstract

In order to study on the unorganized emissions characteristics of volatile organic compounds (VOCs) of Tianjin chemical industry, three plants located in a chemical park in Tianjin were chosen. Air samples on the plant boundary and within the enterprise were collected through air bag, and the VOCs emission levels and component characteristics were measured using proton transfer reaction time of flight mass spectrometer (PTR-TOF-MS). The analysis results showed that, (1) the emission level of VOCs of three plants were different. The level of VOCs in tank area was directly related to the tank type, and the level in storage tank area was related to whether it was sealed, (2) the components of VOCs emitted from unorganized sources mainly were saturated alkanes represented by C2, C2, C8, C9 and C11 and oxygenated volatile organic compounds (OVOCs) represented by CH4O, (3) it was found that alkane substance was a large class of VOCs component in chemical industry plant, so alkanes should be controlled in priority.

Published in American Journal of Environmental Science and Engineering (Volume 2, Issue 4)
DOI 10.11648/j.ajese.20180204.15
Page(s) 79-84
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Volatile Organic Compounds, Chemical Industry, Unorganized Emissions, Emission Levels, Component Characteristics

References
[1] Wang Ning, Liu Wei, Zheng Wei, Ning Miao. Thoughts on prevention and control of VOCs in key industries during the “13th Five-year Plan” period [J]. Environmental Impact Assessment, 2018, 40: 6-8.
[2] Chen Ying. Study on current and future industrial emissions volatile organic compounds in China [D]. Guangzhou: South China University of Technology College of Enivironmental Science and Engineering, 2011.
[3] Qiu K, Yang L, Lin J, et al. Historical industrial emissions of non-methane volatile organic compounds in China for the period of 1980-2010 [J]. Atmospheric Environment, 2014, 86: 102-112.
[4] Wei W, Wang S, Hao J, et al. Projection of anthropogenic volatile organic compounds (VOCs) emissions in China for the period 2010-2020 [J]. Atmospheric Environment, 2011, 45 (38): 6 863-6 871.
[5] Cetin E, Odabasi M, Seyfioglu R. Ambient volatile organic compound (VOC) concentrations around a petrochemical complex and a petroleum refinery [J]. Science of The Total Environment, 2003, 312 (1-3): 103-112.
[6] Watson J G, Chow J C, Fujita E M. Review of volatile organic compound source apportionment by chemical mass balance [J]. Atmospheric Environment, 2001, 35 (9): 1 567-1 584.
[7] Wang Peng. Discussion on estimation of emission sources and quantity of VOC from petrochemical enterprises. Petrochemical Safety Technology, 2013 (1): 59-62.
[8] Yu Yufan, Lu Qing, Zheng Junyu. VOC emission inventory and its uncertainty of the key VOC-related industries in the Pearl River Delta Region. China Enviromental Science, 2011 (2): 195-201.
[9] Ras M R, Marce R M, Borrull F. Characterization of ozone precursor volatile organic compounds in urban atmospheres and around the petrochemical industry in the Tarragona region [J]. Science of the Total Environment, 2009, 407 (14): 4 312-4 319.
[10] Huang C, Chen C H, Li L, et al. Emission inventory of anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China [J]. Atmospheric Chemistry and Physics, 2011, 11 (9): 4 105-4 120.
[11] Liu B S, Liang D N, Yang J M, et al. Characterization and source apportionment of volatile organic compounds based on 1-year of observational data in Tianjin, China [J]. Environmental Pollution, 2016, 218: 757-769.
[12] State Department of Environmental Conservation. HJ/T55-2000 Technical guidelines for fugitive emission monitoring of air pollutants [s]. Beijing: China Environmental Science Press, 2001.
[13] State Statistics Bureau. GB/T4754-2011 Industrial classification for national econmic activities [s]. Beijing: State Administration for Quality Supervision and Inspection and Quarantine and National standardization committee, 2011.
[14] Zhan Xianhui, Tong Dongchao, Shao Yanshan, Ma Xin, Lian Jingyan. Comprehensive evaluation on sampling methods of volatile organic compounds [J]. Journal of Tianjin University of Technology, 2015 (4): 61-64.
[15] Zhan Xuefang, Duan Yixiang. Proton transfer online analysis of reaction—mass spectrometry for trace volatile organic compounds [J]. Chinese Journal of Analytical Chemistry, 2011 (10): 1 611-1 618.
[16] Wei W Cheng S Y, Li G H, et al. Characteristics of volatile organic compounds (VOCs) emitted from a petroleum refinery in Beijing, China [J]. Atmospheric Environment, 2014, 89: 358-366.
[17] Mo Z, Shao M, Lu S, et al. Process- specific emission characteristics of volatile organic compounds (VOCs) from petrochemical facilities in the Yangtze River Delta, China [J]. Science of The Total Environment, 2015, 533: 422-431.
[18] Wei Wei. Study on current and future anthropogenic emissions of volatile organic compounds in China [D]. Beijing: Tsinghua University College of Environmental, 2009.
[19] Liu Y, Shao M, Fu L L, et al. Source profiles of volatile organic compounds (VOCs) measured in China: Part I. [J]. Atmospheric Environment, 2008, 42 (25): 6247-60.
[20] Li Qinqin, Zhang Zhijuan, Li Yang, Gong Daocheng, Gao Jie, Zhang Chunlin, Wang Boguang. Characteristics and ozone formation potential of fugitive volatile organic compounds (VOCs) emitted from petrochemical industry in Pearl River Delta [J]. China Environmental Science, 2016 (5): 1 323-1 331.
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    Xie Tian, Yang Wen, Guo Ting, Bai Zhipeng, Tang Jiayi. (2019). Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example. American Journal of Environmental Science and Engineering, 2(4), 79-84. https://doi.org/10.11648/j.ajese.20180204.15

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    ACS Style

    Xie Tian; Yang Wen; Guo Ting; Bai Zhipeng; Tang Jiayi. Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example. Am. J. Environ. Sci. Eng. 2019, 2(4), 79-84. doi: 10.11648/j.ajese.20180204.15

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    AMA Style

    Xie Tian, Yang Wen, Guo Ting, Bai Zhipeng, Tang Jiayi. Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example. Am J Environ Sci Eng. 2019;2(4):79-84. doi: 10.11648/j.ajese.20180204.15

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  • @article{10.11648/j.ajese.20180204.15,
      author = {Xie Tian and Yang Wen and Guo Ting and Bai Zhipeng and Tang Jiayi},
      title = {Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example},
      journal = {American Journal of Environmental Science and Engineering},
      volume = {2},
      number = {4},
      pages = {79-84},
      doi = {10.11648/j.ajese.20180204.15},
      url = {https://doi.org/10.11648/j.ajese.20180204.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajese.20180204.15},
      abstract = {In order to study on the unorganized emissions characteristics of volatile organic compounds (VOCs) of Tianjin chemical industry, three plants located in a chemical park in Tianjin were chosen. Air samples on the plant boundary and within the enterprise were collected through air bag, and the VOCs emission levels and component characteristics were measured using proton transfer reaction time of flight mass spectrometer (PTR-TOF-MS). The analysis results showed that, (1) the emission level of VOCs of three plants were different. The level of VOCs in tank area was directly related to the tank type, and the level in storage tank area was related to whether it was sealed, (2) the components of VOCs emitted from unorganized sources mainly were saturated alkanes represented by C2, C2, C8, C9 and C11 and oxygenated volatile organic compounds (OVOCs) represented by CH4O, (3) it was found that alkane substance was a large class of VOCs component in chemical industry plant, so alkanes should be controlled in priority.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Study on the Characteristics of Unorganized Emission of Volatile Organic Compounds in Chemical Industry--Taking Tianjin Chemical Enterprises as an Example
    AU  - Xie Tian
    AU  - Yang Wen
    AU  - Guo Ting
    AU  - Bai Zhipeng
    AU  - Tang Jiayi
    Y1  - 2019/01/22
    PY  - 2019
    N1  - https://doi.org/10.11648/j.ajese.20180204.15
    DO  - 10.11648/j.ajese.20180204.15
    T2  - American Journal of Environmental Science and Engineering
    JF  - American Journal of Environmental Science and Engineering
    JO  - American Journal of Environmental Science and Engineering
    SP  - 79
    EP  - 84
    PB  - Science Publishing Group
    SN  - 2578-7993
    UR  - https://doi.org/10.11648/j.ajese.20180204.15
    AB  - In order to study on the unorganized emissions characteristics of volatile organic compounds (VOCs) of Tianjin chemical industry, three plants located in a chemical park in Tianjin were chosen. Air samples on the plant boundary and within the enterprise were collected through air bag, and the VOCs emission levels and component characteristics were measured using proton transfer reaction time of flight mass spectrometer (PTR-TOF-MS). The analysis results showed that, (1) the emission level of VOCs of three plants were different. The level of VOCs in tank area was directly related to the tank type, and the level in storage tank area was related to whether it was sealed, (2) the components of VOCs emitted from unorganized sources mainly were saturated alkanes represented by C2, C2, C8, C9 and C11 and oxygenated volatile organic compounds (OVOCs) represented by CH4O, (3) it was found that alkane substance was a large class of VOCs component in chemical industry plant, so alkanes should be controlled in priority.
    VL  - 2
    IS  - 4
    ER  - 

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Author Information
  • College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, China

  • Institute of Atmospheric Environment, Chinese Research Academy of Environmental Science, Beijing, China

  • College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, China

  • Institute of Atmospheric Environment, Chinese Research Academy of Environmental Science, Beijing, China

  • College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, China

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