Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of  β-MnO<sub>2</sub> Nanorods

Afef Bayoudh; Noureddine Etteyeb; Faouzi Sediri

doi:doi:10.11648/j.ajn.20160201.11

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Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO₂ Nanorods

Afef Bayoudh, Noureddine Etteyeb, Faouzi Sediri

Published in American Journal of Nanosciences (Volume 2, Issue 1)

Received: 30 August 2016 Accepted: 7 October 2016 Published: 17 October 2016

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Abstract

A simple hydrothermal method was developed for the synthesis ofpyrolosite β-MnO₂ nanorods, using potassium permanganate (KMnO₄), manganese sulfate (MnSO₄.H₂O) and oxalic acid (H₂C₂O₄). The effects of the reaction time, the hydrothermal temperature and the amount of H₂C₂O₄ on the structure and the morphology of the final products were studied. The β-MnO₂ nanorods are up to several micrometers in length and about 37 nm in average diameter. The samples were analyzed through X-ray diffraction (DRX), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Electrochemical measurements of thin film of β-MnO₂ nanorods have revealed reversible redox behavior with charge-discharge cycling processes corresponding to reversible cations intercalation/deintercalation into the crystal lattice. This process is easier for the small Li⁺ to the larger Na⁺ one and to the largest K⁺ cation.

Published in	American Journal of Nanosciences (Volume 2, Issue 1)
DOI	10.11648/j.ajn.20160201.11
Page(s)	1-7
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Nanostructures, Hydrothermal Synthesis, X-ray Diffraction, Electrochemical Properties

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APA Style

Afef Bayoudh, Noureddine Etteyeb, Faouzi Sediri. (2016). Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. American Journal of Nanosciences, 2(1), 1-7. https://doi.org/10.11648/j.ajn.20160201.11

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ACS Style

Afef Bayoudh; Noureddine Etteyeb; Faouzi Sediri. Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. Am. J. Nanosci. 2016, 2(1), 1-7. doi: 10.11648/j.ajn.20160201.11

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AMA Style

Afef Bayoudh, Noureddine Etteyeb, Faouzi Sediri. Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. Am J Nanosci. 2016;2(1):1-7. doi: 10.11648/j.ajn.20160201.11

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@article{10.11648/j.ajn.20160201.11,
  author = {Afef Bayoudh and Noureddine Etteyeb and Faouzi Sediri},
  title = {Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of  β-MnO2 Nanorods},
  journal = {American Journal of Nanosciences},
  volume = {2},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajn.20160201.11},
  url = {https://doi.org/10.11648/j.ajn.20160201.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20160201.11},
  abstract = {A simple hydrothermal method was developed for the synthesis ofpyrolosite β-MnO2 nanorods, using potassium permanganate (KMnO4), manganese sulfate (MnSO4.H2O) and oxalic acid (H2C2O4). The effects of the reaction time, the hydrothermal temperature and the amount of H2C2O4 on the structure and the morphology of the final products were studied. The β-MnO2 nanorods are up to several micrometers in length and about 37 nm in average diameter. The samples were analyzed through X-ray diffraction (DRX), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Electrochemical measurements of thin film of β-MnO2 nanorods have revealed reversible redox behavior with charge-discharge cycling processes corresponding to reversible cations intercalation/deintercalation into the crystal lattice. This process is easier for the small Li+ to the larger Na+ one and to the largest K+ cation.},
 year = {2016}
}

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TY  - JOUR
T1  - Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of  β-MnO2 Nanorods
AU  - Afef Bayoudh
AU  - Noureddine Etteyeb
AU  - Faouzi Sediri
Y1  - 2016/10/17
PY  - 2016
N1  - https://doi.org/10.11648/j.ajn.20160201.11
DO  - 10.11648/j.ajn.20160201.11
T2  - American Journal of Nanosciences
JF  - American Journal of Nanosciences
JO  - American Journal of Nanosciences
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2575-4858
UR  - https://doi.org/10.11648/j.ajn.20160201.11
AB  - A simple hydrothermal method was developed for the synthesis ofpyrolosite β-MnO2 nanorods, using potassium permanganate (KMnO4), manganese sulfate (MnSO4.H2O) and oxalic acid (H2C2O4). The effects of the reaction time, the hydrothermal temperature and the amount of H2C2O4 on the structure and the morphology of the final products were studied. The β-MnO2 nanorods are up to several micrometers in length and about 37 nm in average diameter. The samples were analyzed through X-ray diffraction (DRX), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Electrochemical measurements of thin film of β-MnO2 nanorods have revealed reversible redox behavior with charge-discharge cycling processes corresponding to reversible cations intercalation/deintercalation into the crystal lattice. This process is easier for the small Li+ to the larger Na+ one and to the largest K+ cation.
VL  - 2
IS  - 1
ER  -

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Author Information

Afef Bayoudh

Unité de recherche de Nanomatériaux et Environnement (UR15ES01), IPEIT, Université de Tunis, Tunisie, Tunisia
Noureddine Etteyeb

Unité de recherche de Nanomatériaux et Environnement (UR15ES01), IPEIT, Université de Tunis, Tunisie, Tunisia
Faouzi Sediri

Unité de recherche de Nanomatériaux et Environnement (UR15ES01), IPEIT, Université de Tunis, Tunisie, Tunisia; Département de Chimie, Faculté des Sciences de Tunis, Université Tunis El Manar, Tunisie, Tunisia

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APA Style

Afef Bayoudh, Noureddine Etteyeb, Faouzi Sediri. (2016). Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. American Journal of Nanosciences, 2(1), 1-7. https://doi.org/10.11648/j.ajn.20160201.11

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ACS Style

Afef Bayoudh; Noureddine Etteyeb; Faouzi Sediri. Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. Am. J. Nanosci. 2016, 2(1), 1-7. doi: 10.11648/j.ajn.20160201.11

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AMA Style

Afef Bayoudh, Noureddine Etteyeb, Faouzi Sediri. Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of β-MnO2 Nanorods. Am J Nanosci. 2016;2(1):1-7. doi: 10.11648/j.ajn.20160201.11

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@article{10.11648/j.ajn.20160201.11,
  author = {Afef Bayoudh and Noureddine Etteyeb and Faouzi Sediri},
  title = {Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of  β-MnO2 Nanorods},
  journal = {American Journal of Nanosciences},
  volume = {2},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.ajn.20160201.11},
  url = {https://doi.org/10.11648/j.ajn.20160201.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20160201.11},
  abstract = {A simple hydrothermal method was developed for the synthesis ofpyrolosite β-MnO2 nanorods, using potassium permanganate (KMnO4), manganese sulfate (MnSO4.H2O) and oxalic acid (H2C2O4). The effects of the reaction time, the hydrothermal temperature and the amount of H2C2O4 on the structure and the morphology of the final products were studied. The β-MnO2 nanorods are up to several micrometers in length and about 37 nm in average diameter. The samples were analyzed through X-ray diffraction (DRX), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Electrochemical measurements of thin film of β-MnO2 nanorods have revealed reversible redox behavior with charge-discharge cycling processes corresponding to reversible cations intercalation/deintercalation into the crystal lattice. This process is easier for the small Li+ to the larger Na+ one and to the largest K+ cation.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Hydrothermal Synthesis, Physico-Chemical Characterization and Electrochemical Behavior of  β-MnO2 Nanorods
AU  - Afef Bayoudh
AU  - Noureddine Etteyeb
AU  - Faouzi Sediri
Y1  - 2016/10/17
PY  - 2016
N1  - https://doi.org/10.11648/j.ajn.20160201.11
DO  - 10.11648/j.ajn.20160201.11
T2  - American Journal of Nanosciences
JF  - American Journal of Nanosciences
JO  - American Journal of Nanosciences
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2575-4858
UR  - https://doi.org/10.11648/j.ajn.20160201.11
AB  - A simple hydrothermal method was developed for the synthesis ofpyrolosite β-MnO2 nanorods, using potassium permanganate (KMnO4), manganese sulfate (MnSO4.H2O) and oxalic acid (H2C2O4). The effects of the reaction time, the hydrothermal temperature and the amount of H2C2O4 on the structure and the morphology of the final products were studied. The β-MnO2 nanorods are up to several micrometers in length and about 37 nm in average diameter. The samples were analyzed through X-ray diffraction (DRX), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and Raman spectroscopy. Electrochemical measurements of thin film of β-MnO2 nanorods have revealed reversible redox behavior with charge-discharge cycling processes corresponding to reversible cations intercalation/deintercalation into the crystal lattice. This process is easier for the small Li+ to the larger Na+ one and to the largest K+ cation.
VL  - 2
IS  - 1
ER  -

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