Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor

Noorain Khalifa; Shibin Jasper Thomas; Nithin Kota Vasudeva Upadhya; Sreeja Puthenveettil Balakrishnan

doi:doi:10.11648/j.ijctc.20190701.15

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Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor

Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan

Published in International Journal of Computational and Theoretical Chemistry (Volume 7, Issue 1)

Received: 29 January 2019 Accepted: 11 March 2019 Published: 25 March 2019

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Abstract

In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H₂L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H₂L, a change in colour was observed. The ¹H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.

Published in	International Journal of Computational and Theoretical Chemistry (Volume 7, Issue 1)
DOI	10.11648/j.ijctc.20190701.15
Page(s)	28-34
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Colorimetric Sensor, IR Sensing, Fluoride Anion Recognition, Hydrogen Bonding, DFT Calculations, Acoyl Hydrazones

References

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APA Style

Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. (2019). Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. International Journal of Computational and Theoretical Chemistry, 7(1), 28-34. https://doi.org/10.11648/j.ijctc.20190701.15

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ACS Style

Noorain Khalifa; Shibin Jasper Thomas; Nithin Kota Vasudeva Upadhya; Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int. J. Comput. Theor. Chem. 2019, 7(1), 28-34. doi: 10.11648/j.ijctc.20190701.15

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AMA Style

Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int J Comput Theor Chem. 2019;7(1):28-34. doi: 10.11648/j.ijctc.20190701.15

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@article{10.11648/j.ijctc.20190701.15,
  author = {Noorain Khalifa and Shibin Jasper Thomas and Nithin Kota Vasudeva Upadhya and Sreeja Puthenveettil Balakrishnan},
  title = {Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor},
  journal = {International Journal of Computational and Theoretical Chemistry},
  volume = {7},
  number = {1},
  pages = {28-34},
  doi = {10.11648/j.ijctc.20190701.15},
  url = {https://doi.org/10.11648/j.ijctc.20190701.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijctc.20190701.15},
  abstract = {In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.},
 year = {2019}
}

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TY  - JOUR
T1  - Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor
AU  - Noorain Khalifa
AU  - Shibin Jasper Thomas
AU  - Nithin Kota Vasudeva Upadhya
AU  - Sreeja Puthenveettil Balakrishnan
Y1  - 2019/03/25
PY  - 2019
N1  - https://doi.org/10.11648/j.ijctc.20190701.15
DO  - 10.11648/j.ijctc.20190701.15
T2  - International Journal of Computational and Theoretical Chemistry
JF  - International Journal of Computational and Theoretical Chemistry
JO  - International Journal of Computational and Theoretical Chemistry
SP  - 28
EP  - 34
PB  - Science Publishing Group
SN  - 2376-7308
UR  - https://doi.org/10.11648/j.ijctc.20190701.15
AB  - In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.
VL  - 7
IS  - 1
ER  -

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Author Information

Noorain Khalifa

Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India
Shibin Jasper Thomas

Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India
Nithin Kota Vasudeva Upadhya

Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India
Sreeja Puthenveettil Balakrishnan

Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India

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Plain Text BibTeX RIS

APA Style

Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. (2019). Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. International Journal of Computational and Theoretical Chemistry, 7(1), 28-34. https://doi.org/10.11648/j.ijctc.20190701.15

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ACS Style

Noorain Khalifa; Shibin Jasper Thomas; Nithin Kota Vasudeva Upadhya; Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int. J. Comput. Theor. Chem. 2019, 7(1), 28-34. doi: 10.11648/j.ijctc.20190701.15

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AMA Style

Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int J Comput Theor Chem. 2019;7(1):28-34. doi: 10.11648/j.ijctc.20190701.15

Copy | Download

@article{10.11648/j.ijctc.20190701.15,
  author = {Noorain Khalifa and Shibin Jasper Thomas and Nithin Kota Vasudeva Upadhya and Sreeja Puthenveettil Balakrishnan},
  title = {Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor},
  journal = {International Journal of Computational and Theoretical Chemistry},
  volume = {7},
  number = {1},
  pages = {28-34},
  doi = {10.11648/j.ijctc.20190701.15},
  url = {https://doi.org/10.11648/j.ijctc.20190701.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijctc.20190701.15},
  abstract = {In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor
AU  - Noorain Khalifa
AU  - Shibin Jasper Thomas
AU  - Nithin Kota Vasudeva Upadhya
AU  - Sreeja Puthenveettil Balakrishnan
Y1  - 2019/03/25
PY  - 2019
N1  - https://doi.org/10.11648/j.ijctc.20190701.15
DO  - 10.11648/j.ijctc.20190701.15
T2  - International Journal of Computational and Theoretical Chemistry
JF  - International Journal of Computational and Theoretical Chemistry
JO  - International Journal of Computational and Theoretical Chemistry
SP  - 28
EP  - 34
PB  - Science Publishing Group
SN  - 2376-7308
UR  - https://doi.org/10.11648/j.ijctc.20190701.15
AB  - In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.
VL  - 7
IS  - 1
ER  -

Copy | Download