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Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer

Received: 24 February 2019    Accepted: 2 April 2019    Published: 22 April 2019
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Abstract

This paper presented the arsenic determination in four different brands of cosmetic face-creams to provide valuable information on the safety levels for consumers. The cosmetic samples were decomposed by acidic digestion method and then taken for arsenic quantification using inductively coupled atomic emission spectrometry (ICP-AES). The digestion efficiency of acid mixtures including concentrated HNO3, HNO3–HClO4, HNO3–H2O2 and aqua regia was discussed in terms of digestion loss and time consumption. The ICP-AES analyzing results, with determination recoveries of 95.4% ~ 105.2% and relative standard deviations less than 3.0% (n = 5), revealed arsenic contents in the face-creams are in the ranges of 0.68 ~ 3.28 mg·kg−1. Obviously, the arsenic contents in some of the studied brands exceed the maximum recommended value of 2.0 mg·kg−1 set by China. These results lead to the conclusion that constant control of arsenic content in cosmetics should be seriously considered. The successful arsenic determination in cosmetic face-creams by digestion pattern of concentrated HNO3, with simplicity, higher efficiency, less reagent consumption and less analytical time well demonstrates the good analytical capability of this method, promising a great possibility for large batches of cosmetic toxic metal monitoring.

Published in American Journal of Applied Chemistry (Volume 7, Issue 1)
DOI 10.11648/j.ajac.20190701.14
Page(s) 35-41
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Safety Assessment, Cosmetic Face-Creams, Arsenic Determination, Acidic Digestion, ICP-AES

References
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Cite This Article
  • APA Style

    Xijuan Tan, Hong Liu, Zhuming Wang, Minwu Liu. (2019). Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer. American Journal of Applied Chemistry, 7(1), 35-41. https://doi.org/10.11648/j.ajac.20190701.14

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    ACS Style

    Xijuan Tan; Hong Liu; Zhuming Wang; Minwu Liu. Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer. Am. J. Appl. Chem. 2019, 7(1), 35-41. doi: 10.11648/j.ajac.20190701.14

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    AMA Style

    Xijuan Tan, Hong Liu, Zhuming Wang, Minwu Liu. Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer. Am J Appl Chem. 2019;7(1):35-41. doi: 10.11648/j.ajac.20190701.14

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  • @article{10.11648/j.ajac.20190701.14,
      author = {Xijuan Tan and Hong Liu and Zhuming Wang and Minwu Liu},
      title = {Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer},
      journal = {American Journal of Applied Chemistry},
      volume = {7},
      number = {1},
      pages = {35-41},
      doi = {10.11648/j.ajac.20190701.14},
      url = {https://doi.org/10.11648/j.ajac.20190701.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20190701.14},
      abstract = {This paper presented the arsenic determination in four different brands of cosmetic face-creams to provide valuable information on the safety levels for consumers. The cosmetic samples were decomposed by acidic digestion method and then taken for arsenic quantification using inductively coupled atomic emission spectrometry (ICP-AES). The digestion efficiency of acid mixtures including concentrated HNO3, HNO3–HClO4, HNO3–H2O2 and aqua regia was discussed in terms of digestion loss and time consumption. The ICP-AES analyzing results, with determination recoveries of 95.4% ~ 105.2% and relative standard deviations less than 3.0% (n = 5), revealed arsenic contents in the face-creams are in the ranges of 0.68 ~ 3.28 mg·kg−1. Obviously, the arsenic contents in some of the studied brands exceed the maximum recommended value of 2.0 mg·kg−1 set by China. These results lead to the conclusion that constant control of arsenic content in cosmetics should be seriously considered. The successful arsenic determination in cosmetic face-creams by digestion pattern of concentrated HNO3, with simplicity, higher efficiency, less reagent consumption and less analytical time well demonstrates the good analytical capability of this method, promising a great possibility for large batches of cosmetic toxic metal monitoring.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Safety Assessment of Arsenic in Cosmetic Face-creams by Inductively Coupled Plasma Atomic Emission Spectrometer
    AU  - Xijuan Tan
    AU  - Hong Liu
    AU  - Zhuming Wang
    AU  - Minwu Liu
    Y1  - 2019/04/22
    PY  - 2019
    N1  - https://doi.org/10.11648/j.ajac.20190701.14
    DO  - 10.11648/j.ajac.20190701.14
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 35
    EP  - 41
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20190701.14
    AB  - This paper presented the arsenic determination in four different brands of cosmetic face-creams to provide valuable information on the safety levels for consumers. The cosmetic samples were decomposed by acidic digestion method and then taken for arsenic quantification using inductively coupled atomic emission spectrometry (ICP-AES). The digestion efficiency of acid mixtures including concentrated HNO3, HNO3–HClO4, HNO3–H2O2 and aqua regia was discussed in terms of digestion loss and time consumption. The ICP-AES analyzing results, with determination recoveries of 95.4% ~ 105.2% and relative standard deviations less than 3.0% (n = 5), revealed arsenic contents in the face-creams are in the ranges of 0.68 ~ 3.28 mg·kg−1. Obviously, the arsenic contents in some of the studied brands exceed the maximum recommended value of 2.0 mg·kg−1 set by China. These results lead to the conclusion that constant control of arsenic content in cosmetics should be seriously considered. The successful arsenic determination in cosmetic face-creams by digestion pattern of concentrated HNO3, with simplicity, higher efficiency, less reagent consumption and less analytical time well demonstrates the good analytical capability of this method, promising a great possibility for large batches of cosmetic toxic metal monitoring.
    VL  - 7
    IS  - 1
    ER  - 

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Author Information
  • Laboratory of Mineralization and Dynamics, Chang’an University, Xi’an, China

  • Perkin Elmer Management (Shanghai) Co., Ltd, Shanghai, China

  • Laboratory of Mineralization and Dynamics, Chang’an University, Xi’an, China

  • Laboratory of Mineralization and Dynamics, Chang’an University, Xi’an, China

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