American Journal of Nano Research and Applications

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Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles

Received: 21 October 2013    Accepted:     Published: 20 November 2013
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Abstract

Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.

DOI 10.11648/j.nano.20130104.12
Published in American Journal of Nano Research and Applications (Volume 1, Issue 4, November 2013)
Page(s) 83-86
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Pb, Ni, Nano-Particle, Solid Phase Extraction, Layered Double Hydroxide (LDH)

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Author Information
  • Laboratory Expert, Mashhad University of Medical Science, Khorasan-Razavi, Iran

  • Department of Pharmacutical Chemistry, Faculty of Pharmacy, Zabol University of Medical Sciences, Zabol, Iran

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    Saeedeh sepehrikiya, Donya arefi. (2013). Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. American Journal of Nano Research and Applications, 1(4), 83-86. https://doi.org/10.11648/j.nano.20130104.12

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    Saeedeh sepehrikiya; Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am. J. Nano Res. Appl. 2013, 1(4), 83-86. doi: 10.11648/j.nano.20130104.12

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    AMA Style

    Saeedeh sepehrikiya, Donya arefi. Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles. Am J Nano Res Appl. 2013;1(4):83-86. doi: 10.11648/j.nano.20130104.12

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  • @article{10.11648/j.nano.20130104.12,
      author = {Saeedeh sepehrikiya and Donya arefi},
      title = {Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles},
      journal = {American Journal of Nano Research and Applications},
      volume = {1},
      number = {4},
      pages = {83-86},
      doi = {10.11648/j.nano.20130104.12},
      url = {https://doi.org/10.11648/j.nano.20130104.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.nano.20130104.12},
      abstract = {Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.},
     year = {2013}
    }
    

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  • TY  - JOUR
    T1  - Determination of Pb and Ni in Natural Water Samples after Solid Phase Extraction with Layered Double Hydroxide (LDH) Nano-Particles
    AU  - Saeedeh sepehrikiya
    AU  - Donya arefi
    Y1  - 2013/11/20
    PY  - 2013
    N1  - https://doi.org/10.11648/j.nano.20130104.12
    DO  - 10.11648/j.nano.20130104.12
    T2  - American Journal of Nano Research and Applications
    JF  - American Journal of Nano Research and Applications
    JO  - American Journal of Nano Research and Applications
    SP  - 83
    EP  - 86
    PB  - Science Publishing Group
    SN  - 2575-3738
    UR  - https://doi.org/10.11648/j.nano.20130104.12
    AB  - Due to the industrialization, especially in the developing countries, the emission of the heavy metals as lead, cadmium, chromium, nickel, arsenic, and mercury are highly concerned to public and aquatic health. Lead is released with the effluent from the paint, batteries, and automobiles manufacturing units. Lead is one of the toxic metals and largely affects the central, peripheral nervous system. In this study, a suitable and reliable method for the direct determination of Pb and Ni ions in environmental water is proposed. Pb and Ni ions were extracted and precocentrated with layered double hydroxides (LDHs) nano-particles. LDHs, relatively inexpensive and simply prepared material, was synthesized and used as a solid phase extraction (SPE) adsorbent to quantitatively determine the concentration of Pb and Ni ions in natural water samples. Several factors affecting the extraction efficiency, such as, eluent type, eluent volume, flow rate of sample, sample volume, and amount of adsorbent, were investigated and optimized in detail. Pb and Ni ions can be quantitatively retained by LDH nano-particles, then eluted completely by 1 mL of CO32- (1.5 mol L‒1) and1mL EtOH (65% v/v), respectively. The detection limit of this method for Pb and Ni ions was 17 ng mL−1with an enrichment factor of 100, and the relative standard deviation (RSD) was 1.4%.
    VL  - 1
    IS  - 4
    ER  - 

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