Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K

Sujit Kumar Shah; Ajaya Bhattarai; Sujeet Kumar Chatterjee

doi:doi:10.11648/j.ajche.20140206.12

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Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K

Sujit Kumar Shah, Ajaya Bhattarai, Sujeet Kumar Chatterjee

Published in American Journal of Chemical Engineering (Volume 2, Issue 6)

Received: 14 October 2014 Accepted: 27 October 2014 Published: 30 October 2014

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Abstract

The densities of dodecyltrimethylammonium bromide in pure water and in methanol + water mixed solvent media containing (0.10, 0.20, 0.30, and 0.40) volume fractions of methanol were measured at (298.15, 308.15, 318.15, and 323.15) K. The concentrations are varied from (0.4 10-1 to 1.2 10-1) mol kg-1. The results showed almost increase on the densities with increasing surfactant concentration. Also, the densities are found to decrease with increasing temperature over the entire concentration range investigated in a given mixed solvent medium and these values are found to decrease with increasing methanol content in the solvent composition. The effects of concentration, solvent composition and temperature on the partial molar volumes are discussed.

Published in	American Journal of Chemical Engineering (Volume 2, Issue 6)
DOI	10.11648/j.ajche.20140206.12
Page(s)	76-85
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

DTAB, Solvent Composition, Methanol-Water Mixed Solvent Media

References

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APA Style

Sujit Kumar Shah, Ajaya Bhattarai, Sujeet Kumar Chatterjee. (2014). Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. American Journal of Chemical Engineering, 2(6), 76-85. https://doi.org/10.11648/j.ajche.20140206.12

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ACS Style

Sujit Kumar Shah; Ajaya Bhattarai; Sujeet Kumar Chatterjee. Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. Am. J. Chem. Eng. 2014, 2(6), 76-85. doi: 10.11648/j.ajche.20140206.12

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AMA Style

Sujit Kumar Shah, Ajaya Bhattarai, Sujeet Kumar Chatterjee. Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. Am J Chem Eng. 2014;2(6):76-85. doi: 10.11648/j.ajche.20140206.12

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@article{10.11648/j.ajche.20140206.12,
  author = {Sujit Kumar Shah and Ajaya Bhattarai and Sujeet Kumar Chatterjee},
  title = {Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K},
  journal = {American Journal of Chemical Engineering},
  volume = {2},
  number = {6},
  pages = {76-85},
  doi = {10.11648/j.ajche.20140206.12},
  url = {https://doi.org/10.11648/j.ajche.20140206.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20140206.12},
  abstract = {The densities of dodecyltrimethylammonium bromide in pure water and in methanol + water mixed solvent media containing (0.10, 0.20, 0.30, and 0.40) volume fractions of methanol were measured at (298.15, 308.15, 318.15, and 323.15) K. The concentrations are varied from (0.4 10-1 to 1.2 10-1) mol kg-1. The results showed almost increase on the densities with increasing surfactant concentration. Also, the densities are found to decrease with increasing temperature over the entire concentration range investigated in a given mixed solvent medium and these values are found to decrease with increasing methanol content in the solvent composition. The effects of concentration, solvent composition and temperature on the partial molar volumes are discussed.},
 year = {2014}
}

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TY  - JOUR
T1  - Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K
AU  - Sujit Kumar Shah
AU  - Ajaya Bhattarai
AU  - Sujeet Kumar Chatterjee
Y1  - 2014/10/30
PY  - 2014
N1  - https://doi.org/10.11648/j.ajche.20140206.12
DO  - 10.11648/j.ajche.20140206.12
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 76
EP  - 85
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20140206.12
AB  - The densities of dodecyltrimethylammonium bromide in pure water and in methanol + water mixed solvent media containing (0.10, 0.20, 0.30, and 0.40) volume fractions of methanol were measured at (298.15, 308.15, 318.15, and 323.15) K. The concentrations are varied from (0.4 10-1 to 1.2 10-1) mol kg-1. The results showed almost increase on the densities with increasing surfactant concentration. Also, the densities are found to decrease with increasing temperature over the entire concentration range investigated in a given mixed solvent medium and these values are found to decrease with increasing methanol content in the solvent composition. The effects of concentration, solvent composition and temperature on the partial molar volumes are discussed.
VL  - 2
IS  - 6
ER  -

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Author Information

Sujit Kumar Shah

Department of Chemistry, M. M. A. M. C, Tribhuvan University, Biratnagar, Nepal
Ajaya Bhattarai

Department of Chemistry, M. M. A. M. C, Tribhuvan University, Biratnagar, Nepal
Sujeet Kumar Chatterjee

Department of Chemistry, M. M. A. M. C, Tribhuvan University, Biratnagar, Nepal

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APA Style

Sujit Kumar Shah, Ajaya Bhattarai, Sujeet Kumar Chatterjee. (2014). Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. American Journal of Chemical Engineering, 2(6), 76-85. https://doi.org/10.11648/j.ajche.20140206.12

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ACS Style

Sujit Kumar Shah; Ajaya Bhattarai; Sujeet Kumar Chatterjee. Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. Am. J. Chem. Eng. 2014, 2(6), 76-85. doi: 10.11648/j.ajche.20140206.12

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AMA Style

Sujit Kumar Shah, Ajaya Bhattarai, Sujeet Kumar Chatterjee. Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K. Am J Chem Eng. 2014;2(6):76-85. doi: 10.11648/j.ajche.20140206.12

Copy | Download

@article{10.11648/j.ajche.20140206.12,
  author = {Sujit Kumar Shah and Ajaya Bhattarai and Sujeet Kumar Chatterjee},
  title = {Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K},
  journal = {American Journal of Chemical Engineering},
  volume = {2},
  number = {6},
  pages = {76-85},
  doi = {10.11648/j.ajche.20140206.12},
  url = {https://doi.org/10.11648/j.ajche.20140206.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20140206.12},
  abstract = {The densities of dodecyltrimethylammonium bromide in pure water and in methanol + water mixed solvent media containing (0.10, 0.20, 0.30, and 0.40) volume fractions of methanol were measured at (298.15, 308.15, 318.15, and 323.15) K. The concentrations are varied from (0.4 10-1 to 1.2 10-1) mol kg-1. The results showed almost increase on the densities with increasing surfactant concentration. Also, the densities are found to decrease with increasing temperature over the entire concentration range investigated in a given mixed solvent medium and these values are found to decrease with increasing methanol content in the solvent composition. The effects of concentration, solvent composition and temperature on the partial molar volumes are discussed.},
 year = {2014}
}

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TY  - JOUR
T1  - Densities and Partial Molar Volumes of Dodecyltrimethylammonium Bromide in Binary Systems (Methanol+Water) at T=(298.15 to 323.15) K
AU  - Sujit Kumar Shah
AU  - Ajaya Bhattarai
AU  - Sujeet Kumar Chatterjee
Y1  - 2014/10/30
PY  - 2014
N1  - https://doi.org/10.11648/j.ajche.20140206.12
DO  - 10.11648/j.ajche.20140206.12
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 76
EP  - 85
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20140206.12
AB  - The densities of dodecyltrimethylammonium bromide in pure water and in methanol + water mixed solvent media containing (0.10, 0.20, 0.30, and 0.40) volume fractions of methanol were measured at (298.15, 308.15, 318.15, and 323.15) K. The concentrations are varied from (0.4 10-1 to 1.2 10-1) mol kg-1. The results showed almost increase on the densities with increasing surfactant concentration. Also, the densities are found to decrease with increasing temperature over the entire concentration range investigated in a given mixed solvent medium and these values are found to decrease with increasing methanol content in the solvent composition. The effects of concentration, solvent composition and temperature on the partial molar volumes are discussed.
VL  - 2
IS  - 6
ER  -

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