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Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste

Received: 10 May 2014    Accepted: 3 June 2014    Published: 20 June 2014
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Abstract

Anaerobic biodegradation of solid waste food-residues mixed with fruit-waste was carried out at mesophilic conditions. The goal was to model the sensitivity of biogas generation rate to initial-pH, leachate-level and ash-loading. Two process parameters were analyzed at centre-points while the third factor was set at low-, mid- and high-levels. The simulation results showed that at initial-pH of 5 (low-level), the biogas generation rate was more sensitive to ash-loading than at high-level of initial-pH values. The minimum and maximum attainable biogas generation rates due to perturbations in ash-loading were 0.79 and 1.89 mL/min, respectively, representing a difference of 1.10 mL/min. A comparison using sensitivity quotient revealed that decreasing leachate-level had a stronger effect on biogas generation rate than increasing it. It was also found that the biodegradation process was over four-times more sensitive to variations in initial-pH than in ash-loading while it was over seven-times more sensitive to variations in initial-pH than in leachate-level. It was concluded that the sensitivity of biogas generation rate was highest to variations in initial-pH and least to variations in leachate-level.

Published in American Journal of Chemical Engineering (Volume 2, Issue 3)
DOI 10.11648/j.ajche.20140203.11
Page(s) 21-27
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Modeling Biogas Generation, Anaerobic Biodegradation, Sensitivity, Mesophilic, Organic Solid Waste Decomposition

References
[1] J.-J. Lay, Y.-Y. Li and T. Noike, "The Influence of pH and Ammonia Concentration on the Methane Production in High-Solids Digestion Processes," Water Environment Research, Vol. 70, pp. 1075-1082, 1998.
[2] F.M. Espinoza-Escalante, C. Pelayo-Ortíz, J. Navarro-Corona, Y. González-García, A. Bories and H. Gutiérrez-Pulido, "Anaerobic Digestion of the Vinasses from the Fermentation of< I> Agave Tequilana Weber to Tequila: The Effect of pH, Temperature and Hydraulic Retention Time on the Production of Hydrogen and Methane," Biomass and Bioenergy, Vol. 33, pp. 14-20, 2009.
[3] M. Hernández and M. Rodríguez, "Hydrogen Production by Anaerobic Digestion of Pig Manure: Effect of Operating Conditions," Renewable Energy, Vol. 53, pp. 187-192, 2013.
[4] J.J. Lay, Y.Y. Li and T. Noike, "Influences of pH and Moisture Content on the Methane Production in High-Solids Sludge Digestion," Water Research, Vol. 31, pp. 1518-1524, 1997.
[5] V. Vavilin, S. Rytov, L. Lokshina, S. Pavlostathis and M. Barlaz, "Distributed Model of Solid Waste Anaerobic Digestion: Effects of Leachate Recirculation and pH Adjustment," Journal of Biotechnology and Bioengineering, Vol. 81, pp. 66-73, 2003.
[6] P.J. He, X. Qu, L.M. Shao, G.J. Li and D.J. Lee, "Leachate Pretreatment for Enhancing Organic Matter Conversion in Landfill Bioreactor," Journal of Hazardous Materials, Vol. 142, pp. 288-296, 2007.
[7] F.G. Pohland, "Leachate Recycle as Landfill Management Option," Journal of the Environmental Engineering Division, Vol. 106, pp. 1057-1069, 1980.
[8] M.E. Tittlebaum, "Organic Carbon Content Stabilization through Landfill Leachate Recirculation," Journal (Water Pollution Control Federation), pp. 428-433, 1982.
[9] D. O'keefe and D. Chynoweth, "Influence of Phase Separation, Leachate Recycle and Aeration on Treatment of Municipal Solid Waste in Simulated Landfill Cells," Bioresource Technology, Vol. 72, pp. 55-66, 2000.
[10] P. Sosnowski, A. Klepacz-Smolka, K. Kaczorek and S. Ledakowicz, "Kinetic Investigations of Methane Co-Fermentation of Sewage Sludge and Organic Fraction of Municipal Solid Wastes," Bioresource Technology, Vol. 99, pp. 5731-5737, 2008.
[11] M.S. Bilgili, A. Demir and B. Özkaya, "Influence of Leachate Recirculation on Aerobic and Anaerobic Decomposition of Solid Wastes," Journal of Hazardous Materials, Vol. 143, pp. 177-183, 2007.
[12] D.R. Reinhart and A. Basel Al-Yousfi, "The Impact of Leachate Recirculation on Municipal Solid Waste Landfill Operating Characteristics," Waste Management &Research, Vol. 14, pp. 337-346, 1996.
[13] O. Stabnikova, X.Y. Liu and J.Y. Wang, "Anaerobic Digestion of Food Waste in a Hybrid Anaerobic Solid–Liquid System with Leachate Recirculation in an Acidogenic Reactor," Biochemical Engineering Journal, Vol. 41, pp. 198-201, 2008.
[14] K.K. Lee, H. Suk, S. Choi, C.H. Lee and S.Y. Chung, "Numerical Evaluation of Landfill Stabilization by Leachate Circulation," Journal of Environmental Engineering, Vol. 127, pp. 555-563, 2001.
[15] H. Belevi, D. Stämpfli and P. Baccini, "Chemical Behaviour of Municipal Solid Waste Incinerator Bottom Ash in Monofills," Waste Management &Research, Vol. 10, pp. 153-167, 1992.
[16] K. Das, N. Melear, J. Kastner and J. Buquoi, "Influence of Ash Amendment on Odor Emissions and Aerobic Biodegradation of Biosolids Mixes," Transactions of the ASAE, Vol. 46, pp. 1185-1191, 2003.
[17] E. Rendek, G. Ducom and P. Germain, "Assessment of Mswi Bottom Ash Organic Carbon Behavior: A Biophysicochemical Approach," Chemosphere, Vol. 67, pp. 1582-1587, 2007.
[18] B.B. Park, R.D. Yanai, J.M. Sahm, D.K. Lee and L.P. Abrahamson, "Wood Ash Effects on Plant and Soil in a Willow Bioenergy Plantation," Journal of Biomass and Bioenergy, Vol. 28, pp. 355-365, 2005.
[19] L. Etiegni and A. Campbell, "Physical and Chemical Characteristics of Wood Ash," Bioresource Technology, Vol. 37, pp. 173-178, 1991.
[20] J. Nkana, A. Demeyer and M. Verloo, "Effect of Wood Ash Application on Soil Solution Chemistry of Tropical Acid Soils: Incubation Study," Bioresource Technology, Vol. 85, pp. 323-325, 2002.
[21] L. Augusto, M. Bakker and C. Meredieu, "Wood Ash Applications to Temperate Forest Ecosystems—Potential Benefits and Drawbacks," Plant and Soil, Vol. 306, pp. 181-198, 2008.
[22] P.E. Rosenfeld and C.L. Henry, "Activated Carbon and Wood Ash Sorption of Wastewater, Compost, and Biosolids Odorants," Water Environment Research, pp. 388-393, 2001.
[23] A. Demeyer, J. Voundi Nkana and M. Verloo, "Characteristics of Wood Ash and Influence on Soil Properties and Nutrient Uptake: An Overview," Bioresource Technology, Vol. 77, pp. 287-295, 2001.
Cite This Article
  • APA Style

    William Wanasolo, Samwel Manyele, John Makunza. (2014). Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste. American Journal of Chemical Engineering, 2(3), 21-27. https://doi.org/10.11648/j.ajche.20140203.11

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    ACS Style

    William Wanasolo; Samwel Manyele; John Makunza. Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste. Am. J. Chem. Eng. 2014, 2(3), 21-27. doi: 10.11648/j.ajche.20140203.11

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    AMA Style

    William Wanasolo, Samwel Manyele, John Makunza. Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste. Am J Chem Eng. 2014;2(3):21-27. doi: 10.11648/j.ajche.20140203.11

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  • @article{10.11648/j.ajche.20140203.11,
      author = {William Wanasolo and Samwel Manyele and John Makunza},
      title = {Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste},
      journal = {American Journal of Chemical Engineering},
      volume = {2},
      number = {3},
      pages = {21-27},
      doi = {10.11648/j.ajche.20140203.11},
      url = {https://doi.org/10.11648/j.ajche.20140203.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20140203.11},
      abstract = {Anaerobic biodegradation of solid waste food-residues mixed with fruit-waste was carried out at mesophilic conditions. The goal was to model the sensitivity of biogas generation rate to initial-pH, leachate-level and ash-loading. Two process parameters were analyzed at centre-points while the third factor was set at low-, mid- and high-levels. The simulation results showed that at initial-pH of 5 (low-level), the biogas generation rate was more sensitive to ash-loading than at high-level of initial-pH values. The minimum and maximum attainable biogas generation rates due to perturbations in ash-loading were 0.79 and 1.89 mL/min, respectively, representing a difference of 1.10 mL/min.  A comparison using sensitivity quotient revealed that decreasing leachate-level had a stronger effect on biogas generation rate than increasing it. It was also found that the biodegradation process was over four-times more sensitive to variations in initial-pH than in ash-loading while it was over seven-times more sensitive to variations in initial-pH than in leachate-level. It was concluded that the sensitivity of biogas generation rate was highest to variations in initial-pH and least to variations in leachate-level.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Modeling and Analysis of Biogas Generation Rate Sensitivity to Initial-pH, Leachate-Level and Ash-Loading during Anaerobic Biodegradation of Organic Solid Waste
    AU  - William Wanasolo
    AU  - Samwel Manyele
    AU  - John Makunza
    Y1  - 2014/06/20
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ajche.20140203.11
    DO  - 10.11648/j.ajche.20140203.11
    T2  - American Journal of Chemical Engineering
    JF  - American Journal of Chemical Engineering
    JO  - American Journal of Chemical Engineering
    SP  - 21
    EP  - 27
    PB  - Science Publishing Group
    SN  - 2330-8613
    UR  - https://doi.org/10.11648/j.ajche.20140203.11
    AB  - Anaerobic biodegradation of solid waste food-residues mixed with fruit-waste was carried out at mesophilic conditions. The goal was to model the sensitivity of biogas generation rate to initial-pH, leachate-level and ash-loading. Two process parameters were analyzed at centre-points while the third factor was set at low-, mid- and high-levels. The simulation results showed that at initial-pH of 5 (low-level), the biogas generation rate was more sensitive to ash-loading than at high-level of initial-pH values. The minimum and maximum attainable biogas generation rates due to perturbations in ash-loading were 0.79 and 1.89 mL/min, respectively, representing a difference of 1.10 mL/min.  A comparison using sensitivity quotient revealed that decreasing leachate-level had a stronger effect on biogas generation rate than increasing it. It was also found that the biodegradation process was over four-times more sensitive to variations in initial-pH than in ash-loading while it was over seven-times more sensitive to variations in initial-pH than in leachate-level. It was concluded that the sensitivity of biogas generation rate was highest to variations in initial-pH and least to variations in leachate-level.
    VL  - 2
    IS  - 3
    ER  - 

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Author Information
  • Department of Chemical and Mining Engineering, College of Engineering and Technology, University of Dar es Salaam, Tanzania

  • Department of Chemical and Mining Engineering, College of Engineering and Technology, University of Dar es Salaam, Tanzania

  • Department of Structural and Construction Engineering, College of Engineering and Technology, University of Dar es Salaam, Tanzania

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