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The Potential of Minjingu Phosphate Rock for Water Defluoridation

Received: 1 January 2016    Accepted: 11 January 2016    Published: 25 January 2016
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Abstract

In some parts of Tanzania, fluoride ion concentrations in potable water are higher than recommended by WHO. Consequently, searches for economically and technically viable strategies are required to address this problem. This work aims to determine the potential of phosphate rock mined from Minjingu area in Northern Tanzania as water de-fluoridatant. The results obtained are reported herein. The rock particles were chemically activated and then characterised by XRF, XRD and nitrogen physisorption. Results showed that the main component of chemically activated rock particles was calcium hydroxyapatite with Ca/P ratio of 1.55 whereas the main component of non-activated particles was calcium fluoroapatite (Ca/P ratio of 1.66). The results also indicated that activated rock material was mesoporous with a BET surface area of 57.4 m2/g. Results for water defluoridation showed that the material had a fluoride ion percentage removal of about 90%, when the adsorbent dose was 8 g, contact time of 30 minutes, initial fluoride ion concentration 5 mg/L, pH values of 6.0 to 7.2 and batch volume of 50 mL. The material could be regenerated using 1% NaOH and reused in the water defluoridation process. Therefore, Minjingu Phosphate Rock (MPR) is potential water de-fluoridatant.

Published in International Journal of Science, Technology and Society (Volume 4, Issue 1)
DOI 10.11648/j.ijsts.20160401.11
Page(s) 1-6
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Water Defluoridation, Minjingu Phosphate Rock, Potable Water, Adsorption-Desorption Isotherms, Tanzania

References
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[2] Roy S. and Dass G. (2013) Fluorine Contamination in Drinking Water. Resour. Environ. 3: 53-58.
[3] Tiemann M. (2013) Fluoride in Drinking Water: A Review of Fluoridation and Regulations Issues: Report for Congress Congressional Research Services, pp 1–21.
[4] WHO (2004) Fluoride in Drinking-water. Background Document for Development of WHO Guidelines for Drinking-water Quality. World Health Organization: Geneva, pp. 1–7.
[5] WHO (1994) Fluorides and Oral Health. Report of a WHO Expert Committee on Oral Health Status and Fluoride Use. WHO Technical Report Series 846. WHO, Geneva, pp 1–34.
[6] Ghiglieri G., Balia R., Ogiano G., and Pittalis D. (2010) Prospecting for Safe (low fluoride) Groundwater in the Eastern African Rift Valley: the Arumeru District Northern Tanzania. Hydrol. Earth. Syst. Sci. 14: 1081–1091.
[7] Fawell J., Bailey K., Chilton J., Dahi E., Fewtrell L. and Magara Y. (2006) Fluoride in Drinking Water, World Health Organization. IWA Publishing, London, pp 1–134.
[8] Gumbo F. J. and Mkongo G. (1995) Defluoridation for Rural Fluoride Affected Communities in Tanzania. Proceedings of the 1st international workshop on fluorosis and defluoridation of water, Ngurdoto, Tanzania, pp 109–114.
[9] Feenstra L., Vasak L. and Griffioen J. (2007) Fluoride in Groundwater. Overview and Evaluation of Removal Methods, Report SP 2007-1. International Groundwater Resource Assessment Centre, Utrecht, Netherland, pp 1–21.
[10] Thole B. (2013) Ground Water Contamination with Fluoride and Potential Fluoride Removal Technologies for East and Southern Africa; Perspectives in Water Pollution, Ahmad I (Ed.), pp 65–91.
[11] Bjorvatn K. and Bårdsen A. (1995) Use of Activated Clay for Defluoridation of Water. Proceedings of the 1st International Workshop on Fluorosis and Defluoridation of Water, Ngurdoto, Tanzania, pp 49–55.
[12] Meenekshi and Maheshwari R. C. (2006) Fluoride in Drinking Water and its Removal, J. Hazard. Mater, pp 456–463.
[13] Kaseva E. M. (2006) Optimization of Regenerated Bone Char for Fluoride Removal in Drinking Water: A Case Study in Tanzania: J. Water Health, pp 139–147.
[14] Dahi E., Mtalo F., Njau B. and Bregnhj H. (1996) Defluoridation Using the Nalgonda Technique in Tanzania. Proceedings of the 2nd WEDC Conference, New Delhi, pp 266–268.
[15] Renuka, P. and Pushpanjal, K. (2013) Review on Defluoridation Technologies of Water. Int. J. Eng. Sci. 2: 86–94.
[16] Mumtaz, N., Pandey, G. and Labhasetwar, P. K. (2014) Assessment of electrolytic process for water defluoridation. Int. J. Environ. Res. Public Health, pp 175-182.
[17] Khairnar M. R., Dodamani, A. S., Jadhav, H. C., Naik, R. G. and Deshmukh, M. A. (2015) Mitigation of Fluorosis - A Review. J. Clin. Diagn. Res. pp 5-9.
Cite This Article
  • APA Style

    Francisco Lucas Olambo, Joseph Yoeza Naimani Philip, James Epiphan Gabriel Mdoe. (2016). The Potential of Minjingu Phosphate Rock for Water Defluoridation. International Journal of Science, Technology and Society, 4(1), 1-6. https://doi.org/10.11648/j.ijsts.20160401.11

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    ACS Style

    Francisco Lucas Olambo; Joseph Yoeza Naimani Philip; James Epiphan Gabriel Mdoe. The Potential of Minjingu Phosphate Rock for Water Defluoridation. Int. J. Sci. Technol. Soc. 2016, 4(1), 1-6. doi: 10.11648/j.ijsts.20160401.11

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    AMA Style

    Francisco Lucas Olambo, Joseph Yoeza Naimani Philip, James Epiphan Gabriel Mdoe. The Potential of Minjingu Phosphate Rock for Water Defluoridation. Int J Sci Technol Soc. 2016;4(1):1-6. doi: 10.11648/j.ijsts.20160401.11

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  • @article{10.11648/j.ijsts.20160401.11,
      author = {Francisco Lucas Olambo and Joseph Yoeza Naimani Philip and James Epiphan Gabriel Mdoe},
      title = {The Potential of Minjingu Phosphate Rock for Water Defluoridation},
      journal = {International Journal of Science, Technology and Society},
      volume = {4},
      number = {1},
      pages = {1-6},
      doi = {10.11648/j.ijsts.20160401.11},
      url = {https://doi.org/10.11648/j.ijsts.20160401.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.20160401.11},
      abstract = {In some parts of Tanzania, fluoride ion concentrations in potable water are higher than recommended by WHO. Consequently, searches for economically and technically viable strategies are required to address this problem. This work aims to determine the potential of phosphate rock mined from Minjingu area in Northern Tanzania as water de-fluoridatant. The results obtained are reported herein. The rock particles were chemically activated and then characterised by XRF, XRD and nitrogen physisorption. Results showed that the main component of chemically activated rock particles was calcium hydroxyapatite with Ca/P ratio of 1.55 whereas the main component of non-activated particles was calcium fluoroapatite (Ca/P ratio of 1.66). The results also indicated that activated rock material was mesoporous with a BET surface area of 57.4 m2/g. Results for water defluoridation showed that the material had a fluoride ion percentage removal of about 90%, when the adsorbent dose was 8 g, contact time of 30 minutes, initial fluoride ion concentration 5 mg/L, pH values of 6.0 to 7.2 and batch volume of 50 mL. The material could be regenerated using 1% NaOH and reused in the water defluoridation process. Therefore, Minjingu Phosphate Rock (MPR) is potential water de-fluoridatant.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - The Potential of Minjingu Phosphate Rock for Water Defluoridation
    AU  - Francisco Lucas Olambo
    AU  - Joseph Yoeza Naimani Philip
    AU  - James Epiphan Gabriel Mdoe
    Y1  - 2016/01/25
    PY  - 2016
    N1  - https://doi.org/10.11648/j.ijsts.20160401.11
    DO  - 10.11648/j.ijsts.20160401.11
    T2  - International Journal of Science, Technology and Society
    JF  - International Journal of Science, Technology and Society
    JO  - International Journal of Science, Technology and Society
    SP  - 1
    EP  - 6
    PB  - Science Publishing Group
    SN  - 2330-7420
    UR  - https://doi.org/10.11648/j.ijsts.20160401.11
    AB  - In some parts of Tanzania, fluoride ion concentrations in potable water are higher than recommended by WHO. Consequently, searches for economically and technically viable strategies are required to address this problem. This work aims to determine the potential of phosphate rock mined from Minjingu area in Northern Tanzania as water de-fluoridatant. The results obtained are reported herein. The rock particles were chemically activated and then characterised by XRF, XRD and nitrogen physisorption. Results showed that the main component of chemically activated rock particles was calcium hydroxyapatite with Ca/P ratio of 1.55 whereas the main component of non-activated particles was calcium fluoroapatite (Ca/P ratio of 1.66). The results also indicated that activated rock material was mesoporous with a BET surface area of 57.4 m2/g. Results for water defluoridation showed that the material had a fluoride ion percentage removal of about 90%, when the adsorbent dose was 8 g, contact time of 30 minutes, initial fluoride ion concentration 5 mg/L, pH values of 6.0 to 7.2 and batch volume of 50 mL. The material could be regenerated using 1% NaOH and reused in the water defluoridation process. Therefore, Minjingu Phosphate Rock (MPR) is potential water de-fluoridatant.
    VL  - 4
    IS  - 1
    ER  - 

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Author Information
  • Tanzania Industrial Research and Development Organization, Dar es Salaam, Tanzania

  • Chemistry Department, University of Dar es Salaam, Dar es Salaam, Tanzania

  • Chemistry Department, University of Dar es Salaam, Dar es Salaam, Tanzania

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