American Journal of Environmental Protection
Volume 3, Issue 5, October 2014, Pages: 292-298
Received: Nov. 4, 2014;
Accepted: Nov. 15, 2014;
Published: Nov. 18, 2014
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Mohamed Sassi, Faculty of Nature and Life Sciences, Ibn Khaldoun University – Tiaret, Agro-biotechnology and Nutrition Laboratory in Semi-arid Zone, BP 78 ZAAROURA – 14000 Tiaret, Algeria
Benaouda Bestani, Laboratoire de Structure, Elaboration et Application des Matériaux Moléculaires, Université de Mostaganem, Mostaganem, Algeria
Eric Guibal, Ecole des Mines Alès, Engineering Laboratory of the Industrial Environment, 6 Avenue de Claviere, F-30319 Alès CEDEX, France
Dairy sludge was investigated as potential adsorbent for the removal of hazardous cationic dyes. Biosorption was studied as a function of solution initial pH, biosorbent dose, biosorbent particle diameter and initial dye ion concentration. These parameters were measured in batch experiments. Equilibrium uptake increased with increasing dye concentration with a maximum sorption capacity of a 178.6 mg g-1. Model equations such as Langmuir and Freundlich isotherms were used to analyze the adsorption equilibrium data and the best fits to the experimental data were provided by the first isotherm model. Scanning electron microscopy and energy-dispersive X-ray (SEM-EDX), Brunauer–Emett–Teller (BET), Fourier transform infrared analyses (FTIR) and microbiological characterisation were also performed to characterize the biosorbent. To describe the adsorption mechanism, kinetic models such as pseudo-second-order and the intra particle diffusion were applied.
Biosorption of an Industrial Dye (A-BG) by a Dairy Sludge, American Journal of Environmental Protection.
Vol. 3, No. 5,
2014, pp. 292-298.
Aksu Z., (2005). Application of biosorption for the removal of organic pollutants: a review. Process Biochemistry (40), 997–1026.
Attouti S., Bestani B., Benderdouche N., and Duclaux L., (2013). Application of Ulva lactuca and Systoceira stricta algae-based activated carbons to hazardous cationic dyes removal from industrial effluents, water research (47), 3375-3388.
Basibuyuk M. Forster C.F., (2003). An examination of the adsorption characteristics of a basic dye (Maxilon Red BL-N) on to live activated sludge system. Process Biochemistry (38), 1311/ 1316.
Birol K., (2011). Adsorption of textile dyes onto iron based waterworks sludge from aqueous solution; isotherm, kinetic and thermodynamic study. Chemical Engineering Journal (173), 782– 791.
Crini G., Badot P. M., (2008). Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature. Prog. Polym. Sci. (33), 399–447.
Demirbas E., Nas M.Z., (2009). Batch kinetic and equilibrium studies of adsorption of Reactive Blue 21 by fly ash and sepiolite. Desalination (243), 8–21.
Deniz F., Saygideger S.D, (2010). Equilibrium, kinetic and thermodynamic studies of Acid Orange 52 dye biosorption by Paulownia tomentosa Steud. Leaf powder as a low-cost natural biosorbent. Bioresour. Technol. (101), Issue 14, 5137-5143.
Duangrat I., Siritham S., (2004). Decolorization of basic,direct and reactive dyes by pre-treated narrow-leaved cattail (Typha angustifolia Linn.). Bioresource Technology (94), 299 –306.
Gibbs G., Tobin J. M., Guibal E., (2003). Sorption of Acid Green 25 on Chitosan:Infuence of Experimental Parameters on Uptake Kinetics and Sorption Isotherms. Journal of Applied Polymer Science, (90), 1073 –1080.
Gulnaz O., Kaya A., Matyar F., Arikan B., (2004). Sorption of basic dyes from aqueous solution by activated sludge. Journal of Hazardous Materials B (108), 183–188.
Gupta V.K., Suhas, (2009). Application of low-cost adsorbents for dye removal – A review. Journal of Environmental Management (90), 2313–2342.
Hameeda B.H., El-Khaiaryb M.I., (2008). Malachite green adsorption by rattan sawdust: Isotherm, kinetic and mechanism modeling. Journal of Hazardous Materials (159), 574–579.
Hameed B.H., (2008). Equilibrium and kinetic studies of methyl violet sorption by agricultural waste. Journal of Hazardous Materials, (154), 204-212.
Hameed B.H., Ahmad A.A., Aziz N., (2009). Adsorption of reactive dye on palm-oil industry waste: Equilibrium, kinetic and thermodynamic studies, Desalination (247) 551–560.
Ho, Y.S., McKay, G., (2000). The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research, (34) 735-742.
Ho Y.-S., (2004). Comment on “Sorption of basic dyes from aqueous solution by activated sludge”. Journal of Hazardous Materials B (114), 241–245.
Mall I. D., Srivastava V. C., Agarwal N. K., Mishra I. M., (2005). Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses. Colloids and Surfaces A: Physicochem. Eng. Aspects (264), 17–28.
Maurya N. S., Mittal A. K. and Cornel P., (2006). Bio sorption of dyes using dead macro fungi. Bioresource Technology (97), 512 –521.
Nemchi F., Bestani B., Benderdouch N., Belhakem M. and Charles de Minorval L., (2012). Adsorption of Supranol Yellow 4GL from Aqueous Solution onto Activated Carbons Prepared from Seawater Algae. Adsorption Science & Technology (30) 1, 81-95.
Otero M., Rozada F., Calvo L.F., Garc´ýa A.I., Morán A., (2003). Kinetic and equilibrium modelling of the methylene blue removal from solution by adsorbent materials produced from sewage sludges. Biochemical Engineering Journal (15), 59–68.
Pala A., Tokat E., (2002). Color removal from cotton textile industry wastewater in an activated sludge system with various additives. Technical note, Water Research (36), 2920–2925.
Sassi, M., Bestani, B., Hadj Said, A., Benderdouche, N., Guibal, E., (2010). Removal of heavy metal ions from aqueous solutions by a local dairy sludge as a biosorbent. Desalination 262 (1-3), 243-250.
Vasanth Kumar K., Sivanesan S., Ramamurthi V., (2005). Adsorption of malachite green onto Pithophora sp., a fresh water algae: Equilibrium and kinetic modeling. Process Biochemistry (40), 2865–2872.
Van der Zee F.P., (2002). Anaerobic azo dye reduction. Doctoral Thesis, Wageningen University, Wageningen, The Netherlands, 142 pages.
Vasanth Kumar K., Ramamurthi Sivanesan V., S., (2006). Biosorption of malachite green, a cationic dye onto Pithophora sp., a fresh water algae. Dyes and Pigments (69), 102-107.
Volesky B., (1995). Bio sorption of heavy metals. Biotech. Prog (11), 235-250. agricultural waste. Journal of Hazardous Materials (154) 204–212.
Waranusantigula P., Pokethitiyooka P., Kruatrachuea M., Upatham E.S., (2003). Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza). Environmental Pollution (125), 385–392.
Weng C. H. and Pan Y. F., (2006). Adsorption characteristics of methylene blue from aqueous solution by sludge ash. Colloids and Surfaces A: Physicochem. Eng. Aspects (274), 154–162.
Yeddou N. et Bensmaili A., (2006). Equilibrium and kinetic modelling of methylen blue biosorption by pretreated dead fugi. Chemical Engineering Journal (119), 119-125.