Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments

Bappah Adamu Umar; Haruna Adamu

doi:doi:10.11648/j.ajep.20140304.13

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Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments

Bappah Adamu Umar, Haruna Adamu

Published in American Journal of Environmental Protection (Volume 3, Issue 4)

Received: 4 August 2014 Accepted: 13 August 2014 Published: 20 August 2014

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Abstract

The mobility of Pb binding in mine-affected soils to aqueous environments was studied using a combination of chemical and mineralogical methods. Leaching test was supplemented by mineralogical investigation of both soil samples and Pb mineral fractions using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The level of Pb determined by ICP-MS showed maximum concentration of 2.550 ppm and 3225 mg/kg Pb, which is far higher than the World Health Organization (WHO) and Soil Guidelines Value (SGV) for water and soil, respectively. Thus, the leachability of Pb in the area established. Concomitantly, the potential release of Pb into the environment was further revealed by SEM XRD for mineralogical analysis of Pb forms and soil components. The results showed that Anglesite among the five lead-bearing phases observed was the most abundant pool of soil Pb and most soluble fraction. Thus, the geochemical partitioning, potential mobility and bioavailability of soil-associated Pb are established, which perhaps accounted for the transportation of Pb to nearby river water. However, XRD showed high proportion of quartz (81%), aluminosilicates (14%) and traces of feldspars, of which aluminosilicates perhaps cause the retention of some forms of Pb in the area.

Published in	American Journal of Environmental Protection (Volume 3, Issue 4)
DOI	10.11648/j.ajep.20140304.13
Page(s)	185-197
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Mobility, Solubility, Mineralogy, Rhandirmwyn, Environment, Pollution

References

[1]	Selim, M. and Spark, H. 2001. Heavy metals release in soil. CRC Press LLC, Lewis Publishers, USA.
[2]	Jo, K. W. and Park, J.H. 2010. Rapid Release and Changing Sources of Pb in a Mountainous Watershed during Extreme Rainfall Events. Environ. Sci. Technol., 44 (24): 9324–9329.
[3]	Adamu, H., Luter, L., Lawan, M. M. and Umar, B. A. 2013. Chemical speciation: A strategic pathway for insightful risk assessment and decision making for remediation of toxic metal contamination. Environment and Pollution; 2(3): 92-99.
[4]	Haruna, A., Uzairu, A. and Harrison, G.F.S. 2011. Chemical fractionation of trace metals in sewage water – irrigated soils. Int. J. Environ. Res., 5(3): 733-744.
[5]	Lancaster, C.D. and Beutel, M.W. 2011. Fate and Transport of Metals and Particulates within the Roadside Environment – A Review. Water Res. Manag., 1(3): 37-46.
[6]	Rattan, R.K., Datta, S.P., Chhonkar, P.K., Saribatu, K. and Singh, A.K. 2005. Long – term impact of irrigation with sewage effluent on heavy metal content in soils, crops and ground water- A case study. Agric. Ecosys. Environ., 109 (3-4): 310-322.
[7]	Gee, C., Rimsay, M. H., Maskall, J. and Thornton, I. 1997. Mineralogy and weathering processes in historical smelting slags and their effect on mobilisation of lead. J. Geochem. Explor., 58(2-3): 249-257.
[8]	Sauve, S., Hendershot, W., and Allen, H.E. 2000. Solid-solution partitioning of metals in contaminated soils: Dependence on pH, total metal burden, and organic matter. Environmental Science and Technology; 34: 1125-1131.
[9]	Ma, L.Q. and Dong, Y. 2004. Effects of incubation on solubility and mobility of trace metals in two contaminated soils. Environ. Pollut.;130:301-307.
[10]	Hughes, S. 1992. Nantymwyn mine, Northern mines research society. British Mining 49: 87 – 110.
[11]	Thornton, I., Rautiu, R. and Brush, S. 2001. Lead The Facts. IC Consultants Ltd London.
[12]	Rees, F., Simonnot, M.O. and Morel, J.L. 2014. Short-term effects of biochar on soil heavy metal mobility are controlled by intra-particle diffusion and soil pH Increase. European Journal of Soil Science, 65, 149–161.
[13]	Mclean, J.E. and Bledsoe, B.E. 1992. Behaviour of metals in soils.www.epa.gov/superfund/remedy tech/tsp/download/issue14.pdf. Accessed on 15/10/2013.
[14]	Puls, R.W., Powell, R.M, Clark, D.A. and Paul, C.J. 1991. Facilitated transport of inorganic contaminants in ground water: Part II, colloidal transport. EPA/600/M-91/040. U.S. EPA, Robert S. Kerr, Environ. Res. Lab., Ada, OK.
[15]	www.environmental-agency.gov.uk/clea. Soil guideline values for residential and commercial or industrial. Accessed on 24/10/13.
[16]	Palumbo-Roe, B., Klinck, B., Banks, V. and Quigley, S. 2009. Prediction of the long-term performance of abandoned lead zinc mine tailings in a Welsh catchment. J. Geochem. Explor., 100(2):169-181.
[17]	Kovacs, E., Williams, E.D. and Tams, J. 2006. Influence of hydrology on heavy metal speciation and mobility in a Pb–Zn mine tailing. Environ. Pollution, 141: 310-320.
[18]	Bevins, R.E., Young, B., Mason, J.S., Manning, D.A.C. and Symes, R.F. 2010. Mineralization of England and Wales, geological conservation review series, No. 36, joint nature conservation committee, Peterborough, 598.
[19]	Read, H.H., 1970. Rutley’s Elements of Mineralogy, Six edn. Geoge Allen and Unwin Ltd London.
[20]	Hester, R.E. and Moore D.M. 1997. X-Ray Diffraction and the Identification and Analysis of Clay Minerals, 2nd ed. Oxford, New York University Press.
[21]	Hester, R.E. and Harrison, R.M. 1997. Contaminated land and its reclamation. Issues in environmental science and technology. The royal Society of Chemistry, pp. 92-96.
[22]	Nriagu, J. and Moore, P. 1984. Phosphate minerals. Sprinter, New York, p. 318.
[23]	Generalic, E., 2003. Solubility product constants. www.kft-split.hr/periodni/en/abc/kpt.html. Accessed on 21/10/2013.
[24]	Johnson, D.B., 2003. Chemical and Biological Characteristics of mineral spoils and drainage waters at abandoned Coal and Mineral Mines. Water Air and Soil Pollution 3 (1), 47-66.
[25]	Jambor, J.L. 2000. The relation of mineralogy to acid and neutralization potential values in ADR. In: Cotter–Howells, J.D., Campbell, L.S., Valsami-Jones, E., Batchalder, M. (Eds), Environmental Mineralogy: Microbial interactions, anthropogenic influences, contaminated land and waste management. Mineralogical Society Series 9. Mineralogical Society of Great Britain and Ireland, London, pp. 141-159.
[26]	Puura, E., Neretnieks, I., (2000). Atmospheric oxidation of pyritic waste rock in Maardu, Estonia, 2: An assessment of Aluminosilicates buffering potential, Environmental Geology 39 (6): 560-566.
[27]	Salomons, W. 1995. Environmental impact of metals derived from mining activities: Processes, predictions, prevention. J. Geochem. Explor. 52: 5-23.
[28]	Flis, J., Manecki, M. and Badja, T. 2011. Solubility of pyromorphite-mimetite solid solution series. Geochimica et Cosmochimica Acta, 75: 1858-1868.
[29]	Alloway, B.J. and Ayres, D.C. 1993. Chemical Principles of Environmental Pollution, Blackie Academic Professional, London.
[30]	Maskall, J.E. and Thornton, I. 1998. Chemical partition of heavy metals in soils, clays and rocks at historical lead smelting sites. Water, Air and Soil Pollution, 108: 391-409.
[31]	Maskall, J.E., Whitehead, K. and Thornton, I. 1995. Heavy metal migration in soils and rocks at historical lead smelting sites. Environ. Geochem. Health, 17: 127-138.
[32]	Joeng, G.Y. and Lee, B.Y. 2003. Secondary mineralogy and microtextures of weathered sulphides and manganoan carbonates in mine waste-rock dumps, with implications for heavy metal fixation. Amirican Mineralogist, 88: 11-12.
[33]	Polyanskiy, N.G. 1986. Fillipova, N. A. ed. Аналитическая химия элементов: Свинец [Analytical Chemistry of the Elements: Lead] (in Russian), Nauka.
[34]	Casas, J. and Sordo, J. 2006. Lead chemistry, Analytical aspect. Environmental impacts and health effects, Elsevier, Amsterdam, Netherland.
[35]	Harter, R. D. 1983. Effect of soil pH on adsorption of lead, copper, zinc and nickel. Soil Sci. Am. J., 47: 47-51.

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APA Style

Bappah Adamu Umar, Haruna Adamu. (2014). Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. American Journal of Environmental Protection, 3(4), 185-197. https://doi.org/10.11648/j.ajep.20140304.13

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ACS Style

Bappah Adamu Umar; Haruna Adamu. Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. Am. J. Environ. Prot. 2014, 3(4), 185-197. doi: 10.11648/j.ajep.20140304.13

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AMA Style

Bappah Adamu Umar, Haruna Adamu. Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. Am J Environ Prot. 2014;3(4):185-197. doi: 10.11648/j.ajep.20140304.13

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@article{10.11648/j.ajep.20140304.13,
  author = {Bappah Adamu Umar and Haruna Adamu},
  title = {Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments},
  journal = {American Journal of Environmental Protection},
  volume = {3},
  number = {4},
  pages = {185-197},
  doi = {10.11648/j.ajep.20140304.13},
  url = {https://doi.org/10.11648/j.ajep.20140304.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajep.20140304.13},
  abstract = {The mobility of Pb binding in mine-affected soils to aqueous environments was studied using a combination of chemical and mineralogical methods. Leaching test was supplemented by mineralogical investigation of both soil samples and Pb mineral fractions using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The level of Pb determined by ICP-MS showed maximum concentration of 2.550 ppm and 3225 mg/kg Pb, which is far higher than the World Health Organization (WHO) and Soil Guidelines Value (SGV) for water and soil, respectively. Thus, the leachability of Pb in the area established. Concomitantly, the potential release of Pb into the environment was further revealed by SEM XRD for mineralogical analysis of Pb forms and soil components. The results showed that Anglesite among the five lead-bearing phases observed was the most abundant pool of soil Pb and most soluble fraction.  Thus, the geochemical partitioning, potential mobility and bioavailability of soil-associated Pb are established, which perhaps accounted for the transportation of Pb to nearby river water. However, XRD showed high proportion of quartz (81%), aluminosilicates (14%) and traces of feldspars, of which aluminosilicates perhaps cause the retention of some forms of Pb in the area.},
 year = {2014}
}

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TY  - JOUR
T1  - Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments
AU  - Bappah Adamu Umar
AU  - Haruna Adamu
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajep.20140304.13
DO  - 10.11648/j.ajep.20140304.13
T2  - American Journal of Environmental Protection
JF  - American Journal of Environmental Protection
JO  - American Journal of Environmental Protection
SP  - 185
EP  - 197
PB  - Science Publishing Group
SN  - 2328-5699
UR  - https://doi.org/10.11648/j.ajep.20140304.13
AB  - The mobility of Pb binding in mine-affected soils to aqueous environments was studied using a combination of chemical and mineralogical methods. Leaching test was supplemented by mineralogical investigation of both soil samples and Pb mineral fractions using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The level of Pb determined by ICP-MS showed maximum concentration of 2.550 ppm and 3225 mg/kg Pb, which is far higher than the World Health Organization (WHO) and Soil Guidelines Value (SGV) for water and soil, respectively. Thus, the leachability of Pb in the area established. Concomitantly, the potential release of Pb into the environment was further revealed by SEM XRD for mineralogical analysis of Pb forms and soil components. The results showed that Anglesite among the five lead-bearing phases observed was the most abundant pool of soil Pb and most soluble fraction.  Thus, the geochemical partitioning, potential mobility and bioavailability of soil-associated Pb are established, which perhaps accounted for the transportation of Pb to nearby river water. However, XRD showed high proportion of quartz (81%), aluminosilicates (14%) and traces of feldspars, of which aluminosilicates perhaps cause the retention of some forms of Pb in the area.
VL  - 3
IS  - 4
ER  -

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Author Information

Bappah Adamu Umar

Department of Geology and Petroleum Geology, University of Aberdeen, Scotland, UK; National Centre for Petroleum Research and Development, Energy Commission of Nigeria, Abubakar Tafawa Balewa University Research Centre, Bauchi-Nigeria
Haruna Adamu

Department of Chemistry, University of Aberdeen, Scotland, UK; Department of Environmental Management Technology, Abubakar Tafawa Balewa University, Bauchi-Nigeria

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APA Style

Bappah Adamu Umar, Haruna Adamu. (2014). Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. American Journal of Environmental Protection, 3(4), 185-197. https://doi.org/10.11648/j.ajep.20140304.13

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ACS Style

Bappah Adamu Umar; Haruna Adamu. Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. Am. J. Environ. Prot. 2014, 3(4), 185-197. doi: 10.11648/j.ajep.20140304.13

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AMA Style

Bappah Adamu Umar, Haruna Adamu. Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments. Am J Environ Prot. 2014;3(4):185-197. doi: 10.11648/j.ajep.20140304.13

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@article{10.11648/j.ajep.20140304.13,
  author = {Bappah Adamu Umar and Haruna Adamu},
  title = {Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments},
  journal = {American Journal of Environmental Protection},
  volume = {3},
  number = {4},
  pages = {185-197},
  doi = {10.11648/j.ajep.20140304.13},
  url = {https://doi.org/10.11648/j.ajep.20140304.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajep.20140304.13},
  abstract = {The mobility of Pb binding in mine-affected soils to aqueous environments was studied using a combination of chemical and mineralogical methods. Leaching test was supplemented by mineralogical investigation of both soil samples and Pb mineral fractions using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The level of Pb determined by ICP-MS showed maximum concentration of 2.550 ppm and 3225 mg/kg Pb, which is far higher than the World Health Organization (WHO) and Soil Guidelines Value (SGV) for water and soil, respectively. Thus, the leachability of Pb in the area established. Concomitantly, the potential release of Pb into the environment was further revealed by SEM XRD for mineralogical analysis of Pb forms and soil components. The results showed that Anglesite among the five lead-bearing phases observed was the most abundant pool of soil Pb and most soluble fraction.  Thus, the geochemical partitioning, potential mobility and bioavailability of soil-associated Pb are established, which perhaps accounted for the transportation of Pb to nearby river water. However, XRD showed high proportion of quartz (81%), aluminosilicates (14%) and traces of feldspars, of which aluminosilicates perhaps cause the retention of some forms of Pb in the area.},
 year = {2014}
}

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TY  - JOUR
T1  - Chemical and Mineralogical Evidence for Solubility and Mobility of Lead from Lead Mine-Affected Soils to Aqueous Environments
AU  - Bappah Adamu Umar
AU  - Haruna Adamu
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajep.20140304.13
DO  - 10.11648/j.ajep.20140304.13
T2  - American Journal of Environmental Protection
JF  - American Journal of Environmental Protection
JO  - American Journal of Environmental Protection
SP  - 185
EP  - 197
PB  - Science Publishing Group
SN  - 2328-5699
UR  - https://doi.org/10.11648/j.ajep.20140304.13
AB  - The mobility of Pb binding in mine-affected soils to aqueous environments was studied using a combination of chemical and mineralogical methods. Leaching test was supplemented by mineralogical investigation of both soil samples and Pb mineral fractions using X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The level of Pb determined by ICP-MS showed maximum concentration of 2.550 ppm and 3225 mg/kg Pb, which is far higher than the World Health Organization (WHO) and Soil Guidelines Value (SGV) for water and soil, respectively. Thus, the leachability of Pb in the area established. Concomitantly, the potential release of Pb into the environment was further revealed by SEM XRD for mineralogical analysis of Pb forms and soil components. The results showed that Anglesite among the five lead-bearing phases observed was the most abundant pool of soil Pb and most soluble fraction.  Thus, the geochemical partitioning, potential mobility and bioavailability of soil-associated Pb are established, which perhaps accounted for the transportation of Pb to nearby river water. However, XRD showed high proportion of quartz (81%), aluminosilicates (14%) and traces of feldspars, of which aluminosilicates perhaps cause the retention of some forms of Pb in the area.
VL  - 3
IS  - 4
ER  -

Copy | Download