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Synthesis and Study of Tetrathioarsenates of d10-Metals

Received: 7 July 2015    Accepted: 8 July 2015    Published: 23 July 2015
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Abstract

For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.

Published in Earth Sciences (Volume 4, Issue 5-1)

This article belongs to the Special Issue Modern Problems of Geography and Anthropology

DOI 10.11648/j.earth.s.2015040501.25
Page(s) 84-87
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Tetrathioarsenate, IR-spectra, X-ray Crystal Determination

References
[1] Masson J. Sur les arseniates de stroncium//Compt. rend. 1977, c.285, №12. pp. 389-392.
[2] Charles-Messance B., Duc Mauge C., Guerin H. Sur les arseniates de cobalt// Compt. rend. 1960, №3. pp. 2216-2217.
[3] Charles-Messance B., Duc Mauge C., Guerin H. Sur les arseniates de nikel// Bull. Soc. Chim. France. 1959. №1. pp. 121.
[4] Beilina A.Z., Jumanova K.M., Muldakhmetiov Z.M., Khalitiva R.C. About physical-chemical properties of the main arsenates of copper //J. Physichesko khimii. 1977, v. 51, 2. pp. 480-482.
[5] Jumanova K.M., Beilina A.Z., Muldakhmetiov Z.M. Investigation of the nickel arsenate compounds by the IR-spectroscopy, thermographic and roentgen-phase analysis methods. Karaganda, 1977, ВИНИТИ 20.09.77, 3713.
[6] Beilina A.Z., Jumanova K.M., Muldakhmetiov Z.M., Sargazina L.J. Investigations of arsenate compounds of copper, nickel, iron, titanium obtained in system M(OH)n-As2O5-H2O//Ximia i texnologia coedinrnii Arsenic and antimony. Alma-Ata, 1980, pp. 80-89.
[7] Makhmetov M.J., Sagadieva A.K., Chuprakov V.N. Investigations of solubility of iron arsenate. //J. Prikladnoi Ximii. 1981, v.54. №5, pp. 1009-1011.
[8] Stahl-Brasse R., Ariguib-kbir., Guerin H. Contribution a l′etude des arseniates tricalciques et des arseniates des calcium′apatitiques //Bull. Soc. chim. France. 1971. №8. pp. 2828-2832.
[9] Rukovodstvo po neorgznicheskomu sintezu. Pod red. G.M. Brower. T.2. Moskvs, 1985, 627 (Russian).Ewins E. //J. Chem. Soc. 1916, №135, pp. 189.
[10] Sharlo G. Methods of analytical chemistry. Quantitative analysis of inorganic compounds. M., Ximia. 1966, 975 pp.
[11] Gilebrand V.F., Lendel G.E., Brait G.A., Gofman D.I. Practical handbook on inorganic analysis. M., Ximia. 1966, 1111 pp.
[12] R.R. Shagidullin, S.V., Izosimova. Izv. AN SSSR. Ser. khim., 5, 1976, 1045-1048. In Russian.
[13] K. Nakamoto. Infrakrasnie spectry neorganicheskikh i koordinatsionnykh soedinenii. Moskva. 1966. 411. In Russian.
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  • APA Style

    I. Didbaridze, M. Rusia, K. Rukhaia. (2015). Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sciences, 4(5-1), 84-87. https://doi.org/10.11648/j.earth.s.2015040501.25

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    ACS Style

    I. Didbaridze; M. Rusia; K. Rukhaia. Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sci. 2015, 4(5-1), 84-87. doi: 10.11648/j.earth.s.2015040501.25

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    AMA Style

    I. Didbaridze, M. Rusia, K. Rukhaia. Synthesis and Study of Tetrathioarsenates of d10-Metals. Earth Sci. 2015;4(5-1):84-87. doi: 10.11648/j.earth.s.2015040501.25

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  • @article{10.11648/j.earth.s.2015040501.25,
      author = {I. Didbaridze and M. Rusia and K. Rukhaia},
      title = {Synthesis and Study of Tetrathioarsenates of d10-Metals},
      journal = {Earth Sciences},
      volume = {4},
      number = {5-1},
      pages = {84-87},
      doi = {10.11648/j.earth.s.2015040501.25},
      url = {https://doi.org/10.11648/j.earth.s.2015040501.25},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.earth.s.2015040501.25},
      abstract = {For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.},
     year = {2015}
    }
    

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    T1  - Synthesis and Study of Tetrathioarsenates of d10-Metals
    AU  - I. Didbaridze
    AU  - M. Rusia
    AU  - K. Rukhaia
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    AB  - For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag3AsS4 and M3(AsS4)2•H2O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.
    VL  - 4
    IS  - 5-1
    ER  - 

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Author Information
  • Chemical LAB, Ivane Javakhishvili Tbilisi State University, Tbilisi, Georgia

  • Kutaisi Technical University, Kutaisi, Georgia

  • Kutaisi Technical University, Kutaisi, Georgia

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