Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS
International Journal of Nutrition and Food Sciences
Volume 7, Issue 4, July 2018, Pages: 129-133
Received: Jun. 5, 2018;
Accepted: Jun. 22, 2018;
Published: Jul. 17, 2018
Views 1144 Downloads 106
Zhaofeng Wu, China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China
Xiaoyan Peng, China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China
Sheng Chen, China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China
Zhanteng Zeng, China Customs Guangdong Inspection and Quarantine Technology Center, Guangzhou, China
To establish the GPC - GC - MS detection method for determination of organochlorine pesticide residues in milk powder. After simple processing samples, concentration with multi-position concentrator, and online cleaning with GPC-GC-MS, injection into the mass spectrometer for analysis. Results showed that in the linear range of 5～100 ug/L, the correlation coefficient were >0.998, and the method detection limits (MDLs) were <0.5 ug/kg. The spiked recoveries at three levels of 10, 50, 100 ug/kg were in the range of 70 ~ 95%, the relative standard deviations (RSDs) (n=6) were<10%. This method had advantages of good accuracy and precision, simple operation, rapid, and was suitable for routine analysis.
Determination of 19 Organochlorine Pesticides Residues in Milk Powder by GPC-GC-MS, International Journal of Nutrition and Food Sciences.
Vol. 7, No. 4,
2018, pp. 129-133.
Copyright © 2018 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/
) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Fu Yao, Yu Chao, Xu Chen, et al. Research progress on determination methods of organochlorine pesticide residues in food [J]. Beijing Agriculture, 2014, 12 (4): 9~11.
Wu minglai. Exploration of pretreatment methods for detection of organochlorine and pyrethroid pesticide residues in vegetables [J]. Anhui Agricultural Science Bulletin, 2012, 18 (13): 197~198.
Liu Yi, Zheng Guocan, Wang Jing, et al. Determination of 20 Organochlorine Pesticides Residues in Milk by Gas Chromatography-Tandem Mass Spectrometry [J]. Journal of Inspection and Quarantine, 2012, 4 (22): 38~45.
Deng Xiaojuan, Li Wenbin, Jin Lichuan, et al. Determination of 24 Organochlorine and Pyrethroid Pesticide Residues in Milk by Modified QuEChERS Method and Gas Chromatography [J]. Food Science, 2016, 18 (37): 141~145.
GB/T 23210—2008, Determination of 511 pesticides and related chemicals residues in milk and milk powder GC-MS method [S].
GB/T 23211-2008, Determination of 493 pesticides and related chemicals residues in milk and milk powder LC-MS-MS method [S].
Yan Hui, Zhang Wen-li, Jiang Jia-xiao, et al. Determination of 20 organochlorine pesticides in soils using gas chromatography-tandem mass spectrometry combined with accelerated solvent extraction and gel permeation chromatography [J]. Chinese Journal of Analysis Laboratory, 2015, 34(6): 722~726.
Su Jian-feng, Zhong Mao-sheng, Chen Jing, et al. Multi-residue Determination of 295 Pesticides in Tea and Its Products by Gas Chromatography-Mass Spectrometry and Gas Chromatography [J]. Journal of Instrumental Analysis, 2015, 34 (6): 625~638.
Wang Bo, Li Xian-liang, Zhang Lei, et al. Simultaneous Determination of Organochlorine and Pyrethroid Pesticide Residues in Hotpot Condiment by Gas Chromatography [J]. Chinese Journal of Analytical Chemistry, 2010, 38 (10): 1433~1438.
Zhang Yuan, Zhang Qi, Wang Xian-qin. SPE-GC/MS determination of 19 organophosphorus pesticide residues and organochlorine pesticide residues in Rhizoma Curcumae [J]. Chin J Pharm Anal, 2012, 32(1): 95~98.
Fu Wenwen, Luo Tong, Zhu Ying, et al. Determination of Organochlorine Pesticides and Polychlorinated Biphenyls in Milk by QuEChERS-Gas Chromatography-Tandem Mass Spectrometry [J]. Food Science, 2018, 8(39): 309~313.
Xue Haiquan, Cui Zhaojie, Du Shi-yong. Determination of organochlorine pesticides and polychlorinated biphenyls in wheat by gas chromatography with accelerated solvent extraction and gel permeation chromatography cleanup [J]. Journal of Shandong University (Natural Science), 2011, 46(1): 11~15.
Du Juan, Lv Bing, Zhu Pan. et al. Determination of 30 organochlorine pesticides in animal-originated food products using combined purification by gel permeation chromatography and solid-phase extraction coupled with gas chromatography-mass spectrometry [J]. Chinese Journal of Chromatography, 2013, 31(8): 739~746.
Chen Meiyu. Study and Application of Analytical Method for Pesticide Residue in Food by Gas Chromatography-Mass Spectrometry and Gas Chromatography-Tandem Mass Spectrometry [D]. Xiamen: Xiamen University, 2007.
Zheng Junhong. Determination of multiple pesticides residue in milk and milk powder by LC-MS/MS [D]. Shandong: Shandong Agricultural University, 2009.
Chu Chun, Wang Bin. Detection of plasticizer in oil-bearing samples by gel chromatography purification system [A]. 7th chromatography symposium in northwest China 12th annual chromatography conference in Gansu province [C]. Beijing: Beijing Polytech Instrument co., LTD., 2012. 183~185
GB 23200. 86-2016, National food safety standards-Determination of multiple residue of organochlorine pesticides in milk and dairy products Gas chromatography-mass spectrometry [S].
GB 2763-2014, National food safety standard Maximum residue limits for pesticides in food [S].