Applied and Computational Mathematics

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Mathematical Modelling and Kinetics of Microchannel Reactor

Received: 19 December 2016    Accepted: 5 January 2017    Published: 23 January 2017
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Abstract

The coupled nonlinear system of differential equations in 1-butanol dehydration under atmospheric and isothermal conditions are solved analytically for the microchannel reactor. Approximate analytical expressions of concentrations of 1-butanol, 1-butene, water and dibutyl ether are presented by using homotopy analysis method. The homotopy analysis method eliminated the classical perturbation method problem, because of the existence a small parameter in the equation. The analytical results are compared with the numerical solution and experimental results, satisfactory agreement is noted.

DOI 10.11648/j.acm.20160506.12
Published in Applied and Computational Mathematics (Volume 5, Issue 6, December 2016)
Page(s) 234-246
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Mathematical Modelling, Homotopy Analysis Method, 1-Butanol Dehydration, Microchannel Reactor, Channel Electrode, Non Linear Equation

References
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[3] Walter, S., S, Malmberg., B, Schmidt., M. A. Liauw., 2005. Mass transfer limitations in micro channel reactors. Catal. Today, 110: 15–25.
[4] Görke, O., P, Pfeifer., K, Schubert., 2009. Kinetic study of ethanol reforming in a microreactor. Appl. Catal. A: Gen., 360: 232–241.
[5] Schmidt, S. A., N, Kumar., A, Reinsdorf., K, Eränen., J, Wärnå., D. Y Murzin., T, Salmi., 2013. Methyl chloride synthesis over Al2O3 catalyst coated micro strucured reactor thermo dynamics. kinetics and mass transfer, Chem. Eng. Sci., 95: 232–245.
[6] Baker, G. A and P, Graves-Morris., in Rota, G. C.(Ed.), 1981. Encyclopaedia of Mathematics, Vol. 13, Pade Approximants, Part II, Addison-Wesley, Reading, MA, Chapter 1.
[7] Rajendran, L., 2000. Padé approximation for ECE and DISP processes at channel electrodes. Electrochemistry Communication, 2: 186-189.
[8] Loghambal, S and L, Rajendran., 2010. Analysis of Amperometric Enzyme electrodes in the homogeneous mediated mechanism using Variational iteration method. Int. J. Electrochem. Sci., 5: 327-343.
[9] Liao, S., 2004. On the homotopy analysis method for nonlinear problems. Applied Mathematics and Computation, 147: 499–513.
[10] Meena, A and Rajendran, L., 2010. Analysis of pH-Based Potentiometric Biosensor using Homotopy perturbation method. Chemical Engineering & Technology, 33: 1-10.
[11] Yusufoglu, E., 2009. An improvement to homotopy perturbation method for solving system of linear equations. Computers and Mathematics with Applications, 58: 2231-2235.
[12] Rajendran, L and S, Anitha., 2013. Reply to-Comments on analytical solution of amperometric enzymatic reactions based on Homotopy perturbation method, by Ji-Huan He, Lu-Feng Mo [Electrochim. Acta (2013)]. Electrochimica Acta, 102: 474– 476.
[13] Sen, A. K., 1988. An application of the Adomian decomposition method to the transient behavior of a model biochemical reaction, Journal of Mathematical analysis and applications, 131: 232–245.
[14] El-Sayed, S. M., 2002. The modified decomposition method for solving nonlinear algebraic equations. Applied Mathematics and Computation, 132: 589–597.
[15] Liao, S. J., 1992. The Proposed Homotopy Analysis Technique for the Solution of Nonlinear Problems, Ph. D. Thesis, Shanghai Jiao Tong University.
[16] Liao, S. J., 1997. An approximate solution technique which does not depend upon small parameters (part 2): an application in fluid mechanics. Int. J. Nonlinear. Mech., 32 (5): 815–822.
[17] Liao, S. J., 2003. Beyond Perturbation: Introduction to the Homotopy Analysis Method. CRC Press, Boca Raton: Chapman & Hall.
[18] Jafari, H., M, Saeidy., J. V. Ahidi., 2009. The homotopy analysis method for solving fuzzy system of linear equations. Int. J. Fuzzy. Syst., 11 (4): 308–313.
[19] Jafari, H., M, Saeidy., M. A. Firoozjaee, 2009. The Homotopy Analysis Method for Solving Higher Dimensional Initial Boundary Value Problems of Variable Coefficients. Numerical Methods for Partial Differential Equations, 26 (5): 1021-1032.
[20] Manimozhi, P and L, Rajendran., 2013. Analytical expression of substrate and enzyme concentration in the Henri-Michaelis-Menten model using Homotopy analysis method. International Journal of Mathematical Archive, 4 (10): 204-214.
[21] Ananthaswamy, V., S. P. Ganesan., L, Rajendran., 2013. Approximate analytical solution of non-linear reaction-diffusion equation in microwave heating model in a slab: Homotopy analysis method. International Journal of Mathematical Archive, 4 (7): 178-189.
[22] Ananthaswamy, V., S, Kala., L, Rajendran., 2014. Approximate analytical solution of non-linear initial value problem for an autocatalysis in a continuous stirred tank reactor: Homotopy analysis method. Int. Journal of Mathematical Archive, 5 (4): 1-12.
[23] Subha M., V, Ananthaswamy., L, Rajendran., 2014. A comment on Liao’s Homotopy analysis method. International Journal of Applied Sciences and Engineering Research, 3 (1): 177-186.
[24] Berteau, P., M, Ruwet., B, Delmon., 1985. Reaction path ways in 1-butanol dehydration on γ-alumina, Bull. Des Sociétés Chim. Belges, 94 (11–12): 859–868.
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  • APA Style

    Kirthiga Murali, Chitra Devi Mohan, Meena Athimoolam, Rajendran Lakshmanan. (2017). Mathematical Modelling and Kinetics of Microchannel Reactor. Applied and Computational Mathematics, 5(6), 234-246. https://doi.org/10.11648/j.acm.20160506.12

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    ACS Style

    Kirthiga Murali; Chitra Devi Mohan; Meena Athimoolam; Rajendran Lakshmanan. Mathematical Modelling and Kinetics of Microchannel Reactor. Appl. Comput. Math. 2017, 5(6), 234-246. doi: 10.11648/j.acm.20160506.12

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    AMA Style

    Kirthiga Murali, Chitra Devi Mohan, Meena Athimoolam, Rajendran Lakshmanan. Mathematical Modelling and Kinetics of Microchannel Reactor. Appl Comput Math. 2017;5(6):234-246. doi: 10.11648/j.acm.20160506.12

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  • @article{10.11648/j.acm.20160506.12,
      author = {Kirthiga Murali and Chitra Devi Mohan and Meena Athimoolam and Rajendran Lakshmanan},
      title = {Mathematical Modelling and Kinetics of Microchannel Reactor},
      journal = {Applied and Computational Mathematics},
      volume = {5},
      number = {6},
      pages = {234-246},
      doi = {10.11648/j.acm.20160506.12},
      url = {https://doi.org/10.11648/j.acm.20160506.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.acm.20160506.12},
      abstract = {The coupled nonlinear system of differential equations in 1-butanol dehydration under atmospheric and isothermal conditions are solved analytically for the microchannel reactor. Approximate analytical expressions of concentrations of 1-butanol, 1-butene, water and dibutyl ether are presented by using homotopy analysis method. The homotopy analysis method eliminated the classical perturbation method problem, because of the existence a small parameter in the equation. The analytical results are compared with the numerical solution and experimental results, satisfactory agreement is noted.},
     year = {2017}
    }
    

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    T1  - Mathematical Modelling and Kinetics of Microchannel Reactor
    AU  - Kirthiga Murali
    AU  - Chitra Devi Mohan
    AU  - Meena Athimoolam
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    T2  - Applied and Computational Mathematics
    JF  - Applied and Computational Mathematics
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    PB  - Science Publishing Group
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    UR  - https://doi.org/10.11648/j.acm.20160506.12
    AB  - The coupled nonlinear system of differential equations in 1-butanol dehydration under atmospheric and isothermal conditions are solved analytically for the microchannel reactor. Approximate analytical expressions of concentrations of 1-butanol, 1-butene, water and dibutyl ether are presented by using homotopy analysis method. The homotopy analysis method eliminated the classical perturbation method problem, because of the existence a small parameter in the equation. The analytical results are compared with the numerical solution and experimental results, satisfactory agreement is noted.
    VL  - 5
    IS  - 6
    ER  - 

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Author Information
  • Department of Mathematics, Sethu Institute of Technology, Kariapatti, Tamil Nadu, India

  • Department of Mathematics, Sethu Institute of Technology, Kariapatti, Tamil Nadu, India

  • Department of Mathematics, Saraswathi Narayanan College, Perungudi, Tamil Nadu, India

  • Department of Mathematics, Sethu Institute of Technology, Kariapatti, Tamil Nadu, India

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