Advances in Materials
Volume 5, Issue 5, October 2016, Pages: 31-34
Received: Jul. 25, 2016;
Accepted: Aug. 5, 2016;
Published: Aug. 29, 2016
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Ezeoke Jonathan, Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria
Muhammad Yusuf Onimisi, Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria
Danladi Eli, Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria
The performance of dye sensitized solar cells (DSSCs), sensitized with natural pigments extracted from mango (mangifera indica), carica papaya, moringa oleifera leaves and bougainvillea flower was demonstrated. The photoactive electrodes of the various DSSCs were sensitized with aqueous extract of the natural pigments. The resulting photoelectrodes were successfully incorporated into the DSSCs. The photoelectrochemical perfomance of the DSSCs were evaluated under 100 mAcm-2 light intensity with open circuit voltage (VOC) ranging from 0.36 to 0.49 V and short circuit current density (JSC) ranging from 0.0134 to 0.1314 mAcm-2. From the photovoltaic performance of the extracts, the Mangifera Indica extract sensitized solar cell gave the best performance with Jsc of 0.1314 mAcm-2, Voc of 0.49 V, a fill factor (FF) of 0.59, and an overall solar energy conversion efficiency (η) of 0.038%. The sensitization performance related to the interaction between the dye and TiO2 surface is discussed.
Muhammad Yusuf Onimisi,
Natural Pigments as Sensitizers for Dye Sensitized Solar Cells, Advances in Materials.
Vol. 5, No. 5,
2016, pp. 31-34.
Karl Martin Karlsson, 2011: “Design, Synthesis and Properties of Organic Sensitizers for Dye Sensitized Solar Cells”, KTH Chemical Science and Engineering, Royal Institute of Technology, SE-100 44 Stockholm, Sweden.
Lewis, N. S., Nocera, D. G., Proc. Natl. Acad. Sci. 2006, 103 (43), 15729-15735.
Hagfeldt, A., Boschloo, G., Sun, L. C., Kloo, L., Pettersson, H., Chem. Rev. 2010, 110 (11), 6595-6663.
Danladi Eli, M. Y. Onimisi, S. G. Abdu, P. M. Gyuk and Ezeoke Jonathan. Enhanced Performance of a Dye Sensitized Solar Cell Using Silver Nanoparticles Modified Photoanode. Journal of Scientific Research & Reports. 2016; 10 (4): 1-8.
Danladi Eli, Muhammad Sani Ahmad, Ayiya Bitrus Bikimi and O. A. Babatunde. Plasmonic Dye Sensitized Solar Cells Incorporated with TiO2-Ag Nanostructures. International Research Journal of Pure & Applied Chemistry. 2016; 11 (3): 1-7.
M. Y. Onimisi, Danladi Eli, S. G. Abdu, H. O. Aboh and Ezeoke Jonathan. Size Effects of Silver Nanoparticles on the Photovoltaic Performance of Dye Sensitized Solar Cells. American Chemical Science Journal. 2016; 13 (3): 1-8.
Danladi Eli, Ezeoke Jonathan, M. S. Ahmad, Danladi Ezra, S. H. Sarki, Ishaya Iliyasu, and P. M. Gyuk. Photoelectrochemical Performance of Dye-Sensitized Organic Photovoltaic Cells Based on Natural Pigments and Wide-Bandgap Nanostructured Semiconductor. Physical Science International Journal. 2016; 10 (2): 1-7.
Danladi Eli, M. Y. Onimisi, S. G. Abdu, Ezeoke Jonathan and S. O. Yakubu. Photoelectric Characterization of a Dye-sensitized Solar Cell Based on Natural Pigment Extracted from Roselle (Hibiscus sabdariffa) Flower and TiO2 Nanoparticles. British Journal of Applied Science & Technology. 2016; 15 (2): 1-6.
Haruna Isah, Danladi Eli, Gyuk PM. Development of organic dye sensitized solar cell incorporated with TiO2 nanostructures with low conversion efficiency for exploring solar energy concepts. International Journal of Optoelectronic Engineering. 2015; 5 (1): 16-19. DOI: 10.5923/j.ijoe.20150501.03.
Danladi Eli, Muhammad Ahmad, Idodo Maxwell, Danladi Ezra, Aungwa Francis, Sunday Sarki. Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers. Journal of Energy and Natural Resources. 2016; 5 (1): 11-15, doi: 10.11648/j.jenr.20160501.12.
Danladi Eli, Joshua Adeyemi Owolabi, Gabriel Olawale Olowomofe, Ezeoke Jonathan. Plasmon-Enhanced Efficiency in Dye Sensitized Solar Cells Decorated with Size-Controlled Silver Nanoparticles Based on Anthocyanins as Light Harvesting Pigment. Submitted for publication in Journal of Photonic Materials and Technology.
Danladi Eli, JA Owolabi, GO Olowomofe, MY Onimisi and Aungwa Francis. Enhancement in Photovoltaic Parameters of a Dye Sensitized Solar Cell by Surface Plasmon Resonance of Metallic Silver Nanoparticles. American Chemical Science Journal. 2016; 14 (3): 1-8.
Adenike Boyo, Okafor Paul, Ibrahim Abdulsalami, Oluwole Surukite, Dr H. O. Boyo, Henry Boyo. Application of Hibiscus Sabdariffa and leaves of Azardirachta Indica calyxes as sensitizers in Dye sensitized solar cells. International Journal of Engineering Research and Development. Volume 8, Issue 12 (October 2013), PP. 38-42.
Khwanchit Wongcharee, Vissanu Meeyoo, Sumaeth Chavadej. Dye sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Front matter Elsevier B. V. 2007.
Barness Chirazo Mphande, Alexander Pogrebnoi. Outdoor photoelectrochemical characterization of dyes from Acalypha wilkesiana ‘Haleakala’ and Hibiscus sabdariffa as dye solar cells sensitizers. British Journal of Applied Science & Technology. 2015; 7 (2): 195-204.
Zhou H, Wu L, Gao Y, Ma T. Dye-sensitized solar cells using 20 natural dyes as sensitizers. J. Photobio. A Chemistry 291, 2011. pp 188-194.
Ezeoke Jonathan, M. Y. Onimisi, Danladi Eli, S. G. Abdu and M. S. Abdulsalam. Photovoltaic Perfomance of Dye Sensitized Solar Cells Using Natural Dyes Extracted from Bougainvillea Flower and Mango Leaves. Journal of Scientific Research & Reports. 2016; 10 (6): 1-5.
Getachew Yirga, Sisay Tadesse, Teketel Yohannes. Photoelectrochmeical cell based on natural pigments and ZnO nanoparticles. Journal of Energy and Natural Resources. 2016; 5 (1): 1-10. DOI: 10.11648/j.jenr.20160501.11.
Mohammed Isah Kimpa, Musa Momoh, Kasim Uthman Isah, Hassan Nawawi Yahya, Muhammed Muhammed Ndamitso. Photoelectric Characterization of Dye Sensitized Solar Cells Using Natural Dye from Pawpaw Leaf and Flame Tree Flower as Sensitizers. Materials Sciences and Applications, 2012, 3, 281-286.