American Journal of Physical Chemistry

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Three Separate Regions in the Prepared Aniline-Palladium Mixture

Received: 15 December 2013    Accepted:     Published: 30 December 2013
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Abstract

Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.

DOI 10.11648/j.ajpc.20140301.11
Published in American Journal of Physical Chemistry (Volume 3, Issue 1, February 2014)
Page(s) 1-4
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Aniline, Palladium, Chemical Synthesis, SEM, PXD, FTIR

References
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Author Information
  • Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine

  • Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine

  • Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine

  • Department of Physical and Colloid Chemistry, Ivan Franko National University of L’viv, 6 Kyryla and Mefodiya Str., UA-79005, L’viv, Ukraine; Physics Department, Institute for Energy Technology, Kjeller, Norway

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    Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. (2013). Three Separate Regions in the Prepared Aniline-Palladium Mixture. American Journal of Physical Chemistry, 3(1), 1-4. https://doi.org/10.11648/j.ajpc.20140301.11

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    ACS Style

    Yuriy Semenyuk; Orest Pereviznyk; Oleksandr Reshetnyak; Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am. J. Phys. Chem. 2013, 3(1), 1-4. doi: 10.11648/j.ajpc.20140301.11

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    AMA Style

    Yuriy Semenyuk, Orest Pereviznyk, Oleksandr Reshetnyak, Ivan Saldan. Three Separate Regions in the Prepared Aniline-Palladium Mixture. Am J Phys Chem. 2013;3(1):1-4. doi: 10.11648/j.ajpc.20140301.11

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  • @article{10.11648/j.ajpc.20140301.11,
      author = {Yuriy Semenyuk and Orest Pereviznyk and Oleksandr Reshetnyak and Ivan Saldan},
      title = {Three Separate Regions in the Prepared Aniline-Palladium Mixture},
      journal = {American Journal of Physical Chemistry},
      volume = {3},
      number = {1},
      pages = {1-4},
      doi = {10.11648/j.ajpc.20140301.11},
      url = {https://doi.org/10.11648/j.ajpc.20140301.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajpc.20140301.11},
      abstract = {Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.},
     year = {2013}
    }
    

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    T1  - Three Separate Regions in the Prepared Aniline-Palladium Mixture
    AU  - Yuriy Semenyuk
    AU  - Orest Pereviznyk
    AU  - Oleksandr Reshetnyak
    AU  - Ivan Saldan
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    DO  - 10.11648/j.ajpc.20140301.11
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
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    EP  - 4
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20140301.11
    AB  - Polyaniline-palladium composite might be proposed for the electrode material in the oxidation of aliphatic alcohols (methanol, ethanol, ethylene glycol). Prepared mixture of aniline-palladium in sulfuric acid medium (0<рН<1) is investigated by SEM, PXD and FTIR. Obtained results confirm existence of three separate regions: polydisperse palladium powder with agglomerations size of ~0.5 micron in width and ~3-7 microns in length; single palladium particles (~0.5×0.2 micron) coated mainly by polyaniline form – emeraldine; aniline balls (diameter of ~2-5 microns) with ~0.2 atomic percent of Pd in their bulk and converted at the surface to emeraldine base and emeraldine salt.
    VL  - 3
    IS  - 1
    ER  - 

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