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The Antioxidant Properties of Oxygen

Received: 11 March 2013    Accepted:     Published: 02 April 2013
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Abstract

New reaction scheme is suggested for the initiated nonbranched-chain addition of free radicals to the multiple bond of the molecular oxygen. The scheme includes the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in this scheme involves a few of free radicals, one of which (tetraoxyl) is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the proposed scheme rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. The kinetic description with use the obtained rate equations is applied to the γ-induced nonbranched-chain processes of the free-radical oxidation of liquid o-xylene at 373 K and hydrogen dissolved in water containing different amounts of oxygen at 296 K. In these processes the oxygen with the increase of its concentration begins to act as an oxidation autoingibitor (or an antioxidant), and the rate of peroxide formation as a function of the dissolved oxygen concentration has a maximum. The energetics of the key radical-molecule reactions is considered.

DOI 10.11648/j.ajpc.20130202.12
Published in American Journal of Physical Chemistry (Volume 2, Issue 2, April 2013)
Page(s) 33-43
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Competition, Low-Reactive Radical, Autoinhibitor, Thermochemical Data, Energy, Hydrogen

References
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  • Department of Chemistry, Lomonosov Moscow State University, Vorob’evy Gory, Moscow 119991, Russia

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    Michael M. Silaev. (2013). The Antioxidant Properties of Oxygen. American Journal of Physical Chemistry, 2(2), 33-43. https://doi.org/10.11648/j.ajpc.20130202.12

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  • @article{10.11648/j.ajpc.20130202.12,
      author = {Michael M. Silaev},
      title = {The Antioxidant Properties of Oxygen},
      journal = {American Journal of Physical Chemistry},
      volume = {2},
      number = {2},
      pages = {33-43},
      doi = {10.11648/j.ajpc.20130202.12},
      url = {https://doi.org/10.11648/j.ajpc.20130202.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajpc.20130202.12},
      abstract = {New reaction scheme is suggested for the initiated nonbranched-chain addition of free radicals to the multiple bond of the molecular oxygen. The scheme includes the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in this scheme involves a few of free radicals, one of which (tetraoxyl) is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the proposed scheme rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. The kinetic description with use the obtained rate equations is applied to the γ-induced nonbranched-chain processes of the free-radical oxidation of liquid o-xylene at 373 K and hydrogen dissolved in water containing different amounts of oxygen at 296 K. In these processes the oxygen with the increase of its concentration begins to act as an oxidation autoingibitor (or an antioxidant), and the rate of peroxide formation as a function of the dissolved oxygen concentration has a maximum. The energetics of the key radical-molecule reactions is considered.},
     year = {2013}
    }
    

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  • TY  - JOUR
    T1  - The Antioxidant Properties of Oxygen
    AU  - Michael M. Silaev
    Y1  - 2013/04/02
    PY  - 2013
    N1  - https://doi.org/10.11648/j.ajpc.20130202.12
    DO  - 10.11648/j.ajpc.20130202.12
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
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    EP  - 43
    PB  - Science Publishing Group
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    UR  - https://doi.org/10.11648/j.ajpc.20130202.12
    AB  - New reaction scheme is suggested for the initiated nonbranched-chain addition of free radicals to the multiple bond of the molecular oxygen. The scheme includes the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in this scheme involves a few of free radicals, one of which (tetraoxyl) is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the proposed scheme rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. The kinetic description with use the obtained rate equations is applied to the γ-induced nonbranched-chain processes of the free-radical oxidation of liquid o-xylene at 373 K and hydrogen dissolved in water containing different amounts of oxygen at 296 K. In these processes the oxygen with the increase of its concentration begins to act as an oxidation autoingibitor (or an antioxidant), and the rate of peroxide formation as a function of the dissolved oxygen concentration has a maximum. The energetics of the key radical-molecule reactions is considered.
    VL  - 2
    IS  - 2
    ER  - 

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