Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace

doi:doi:10.11648/j.ajpc.20180702.11

| Peer-Reviewed

Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace

Published in American Journal of Physical Chemistry (Volume 7, Issue 2)

Received: 11 February 2018 Accepted: 14 March 2018 Published: 1 June 2018

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g^-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r²). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, q_m, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g^-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.

Published in	American Journal of Physical Chemistry (Volume 7, Issue 2)
DOI	10.11648/j.ajpc.20180702.11
Page(s)	12-18
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Biosorption, Kinetics, Modified Moringaoleifera Leaves, Pseudo First Order, Pseudo Second Order

References

[1]	S. Naser., A. Reza, & K. Bakhtiar, Removal of Copper ions from aqueous solutions Usingpolymer derivations of poly (styrene-altmaleic anhydride). Egyptian Journal of Petroleum. 2017, 26, 375–389.
[2]	M. Bilal, J. A. Shah, T. Ashfaq, S. M. H. Gardazi, A. A. Tahir, A. Pervez, H. Haroon & Q. Mahmood, (2013) “Waste biomass adsorbents for copper removal from industrialwastewater—A review,” Journal of Hazardous Materials, 2013, vol. 263, pp. 322-333.
[3]	O. Demirbaş, A. Karadağ, M. Alkan.& M. Doğan, M. (2008) “Removal of copper ionsfrom aqueous solutions by hazelnut shell,” Journal of Hazardous Material S, 2008, vol. 153, pp. 677-684,
[4]	M. Dinesh & P. S. Kunwar (2002):Single- and multi-component adsorption of cadmiumand zinc usingactivated carbon derived from bagasse - an agricultural waste $ Water Research, 2002, 36, 2304–2318.
[5]	L. I. Xiaomin, T. Yanru, C. Xiuju, L. Dandan, L. Fang &S. Wenjing S. Colloids and Surfaces, 2008, 317, 512-521.
[6]	Y. W. Fa, H. Wang & J. Wei Ma, Adsorption of cadmium (II) ions from aqueoussolutionby a new low-cost adsorbent—Bamboo charcoal, Journal of Hazardous Materials, 2010, 177, 300–306.
[7]	F. Anwar, S. Latif., M. Ashraf & A. H. Gilani, “Moringaoleifera: a food plant with multiplemedicinal uses,” Phytotherapy Research, 2007, vol. 21, pp. 17-25,
[8]	V. Jahn, H. A. Musnad & H. Burgstaller, “Tree that purifies water: Cultivating multipurposeMoringaceae in the Sudan,” Unasylva. 1986.
[9]	V. Nand, M. Maata, K. Koshy & S. Sotheeswaran, “Water Purification using MoringaoleiferaandOtherLocallyAvailable Seeds in Fiji for Heavy Metal Removal,” InternationalJournal of Applied Science andTechnology, 2012, vol. 2, pp. 125-129.
[10]	M. Suarez, J. J. Entenza, J. J. Doerries, J. Meyer, L. Bourquin, J. Sutherland, L. Marison, P. Moreillon& N. Mermod“Expression of a plant-derived peptide harboringwater-cleaning and antimicrobial activities,”Biotechnology and Bioengineering, 2003, vol. 81, pp. 13-20. http://dx.doi.org/10.1002/bit.10550
[11]	V. N. Alves & N. M. M. Coelho “Selective extraction and preconcentration of chromiumusingMoringaoleiferahusks as biosorbent and flame atomic absorption spectrometr,” Microchemical Journal, 2013, vol. 109, pp. 16-22.
[12]	F. N. Obuseng, & H. M. Kwaambwa., “A study of the removal of heavy metals fromaqueous solutions by Moringaoleiferaseeds and amine-based ligand 1, 4-bis [N, N-bis(2-picoyl)amino]butane,” Analytica ChimicaActa, 2012, vol. 730, pp. 87-92.
[13]	R. A. Ongulu, J. L. Kituyi & Z. M. Getenga, Biosorption of Pb2+ and Cr2+ Using MoringaOleiferaand their Adsorption Isotherms Science Journal of Analytical Chemistry, 2015, 3(6): 100-108.
[14]	G. Sears, Determination of specific surface area of colloidal silica by titration with sodium hydroxide. Analytical Chemistry, 1956, 28, 1981−1983.
[15]	L. S. Balistrieri, & J. W. Murray, The surface chemistry of goethite (α-FeOOH) in major ionseawater. Am. J. Sci., 1981, 281 (6), 788− 806.
[16]	H. R. Pouretedal & M. Kazemi, sodium silicate precursor and its application as adsorbentof Cu2+, Cd2+, and Pb2+ ions. International Journal of Industrial Chemistry, 2012, 3: 20-28.
[17]	J. Wang, S. Zheng, Y. Shao, J. Liu & Z. Xu, core- shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. Journal of Colloid Interface Science, 2010, 349: 293-299.
[18]	A. H. Chen, S. C. Liu, & C. Y. Chen, Comparative adsorption of Cu(II), Zn(II), and Pb(II) ions in aqueous solution on the cross linked chitosan with epichlorohydrin. Journal Hazard Mater, 2008, 154: 184-191.
[19]	M. Iqbal&R. G. J. Edyvean, Biosorption of lead, copper and zinc in a loofa sponge immobilised biomass of Phanerochaetechrysosporium. Min EngInt, 2004, 17: 217-223.
[20]	N. A. Oladoja, C. O. Aboluwoye, I. A. Ololade, O. L. Adebayo, S. E. Olaseni, &AdelagunR. O. A.: Intercalation of gastropod shell derived calcium oxide in clay andapplication in phosphate abstraction from aqua medium. Industrial and Engineering Chemistry research, 2012, 51 (45), 14637–14645.
[21]	K. V. Kumar, V. Ramamurthi,&S. Sivanesan, “Modeling the Mechanism InvolvedDuringthe Sorption of Methylene Blue onto Fly Ash”. Journal of Colloid Interface Science., 2006, 1; 284, 14-21.
[22]	R. P Han., Y. F. Wang, P. Han, J. Shi, J. Yang, Y. S. Lu., JournalHazard. Mater., 2006, 133(1–3), 262–268.
[23]	A. Shukla, Y. H. Zheng, P. Dubey, J. L. Margrare., S. S. Shukla, J. of Hazard Mater. 2002 95(1-2), 137.
[24]	L. J. Yu, S. S. Shukla, K. L. Doris, A. Shukla, J. L. Masgrave, J. of Hazard. Mater, 2003, 100(1-3), 53.
[25]	G. M. Pereira, M. A. Z. Arruda. Trends in preconcentration procedures for metaldetermination using atomic spectrometry techniques. MicrochimicaActa, 2003; 141, 115-31.
[26]	I. D. Mall, V. C. Srivastava, N. K. Agarwal, Removal of orange G and Methyl violet dyes byadsorption onto bagasse fly ash-Kinetic study and equilibrium Is other manalyses. Of Dyes Pigments, 2006, 69, 210–223.
[27]	S. Senthilkumaar, S. Bharathi, D. Nithyanandhi, V. Subburam, Biosorption of toxic heavymetals from aqueous solutions. Bioresource Technology 2000; 75 163-5.

Cite This Article

Plain Text BibTeX RIS

APA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. (2018). Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). American Journal of Physical Chemistry, 7(2), 12-18. https://doi.org/10.11648/j.ajpc.20180702.11

Copy | Download

ACS Style

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am. J. Phys. Chem. 2018, 7(2), 12-18. doi: 10.11648/j.ajpc.20180702.11

Copy | Download

AMA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am J Phys Chem. 2018;7(2):12-18. doi: 10.11648/j.ajpc.20180702.11

Copy | Download

@article{10.11648/j.ajpc.20180702.11,
  author = {Adebayo Oluwafemi Lawrence and Kenni Amoke Monisola and Oyetunde Julius Gbenga and Jegede Rufus Oluwafemi and Ajayi Margret Grace},
  title = {Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {2},
  pages = {12-18},
  doi = {10.11648/j.ajpc.20180702.11},
  url = {https://doi.org/10.11648/j.ajpc.20180702.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180702.11},
  abstract = {The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)
AU  - Adebayo Oluwafemi Lawrence
AU  - Kenni Amoke Monisola
AU  - Oyetunde Julius Gbenga
AU  - Jegede Rufus Oluwafemi
AU  - Ajayi Margret Grace
Y1  - 2018/06/01
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpc.20180702.11
DO  - 10.11648/j.ajpc.20180702.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180702.11
AB  - The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.
VL  - 7
IS  - 2
ER  -

Copy | Download

Author Information

Adebayo Oluwafemi Lawrence

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Kenni Amoke Monisola

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Oyetunde Julius Gbenga

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Jegede Rufus Oluwafemi

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria
Ajayi Margret Grace

Department of Chemistry, College of Education, Ikere, Ekiti State, Nigeria

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. (2018). Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). American Journal of Physical Chemistry, 7(2), 12-18. https://doi.org/10.11648/j.ajpc.20180702.11

Copy | Download

ACS Style

Adebayo Oluwafemi Lawrence; Kenni Amoke Monisola; Oyetunde Julius Gbenga; Jegede Rufus Oluwafemi; Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am. J. Phys. Chem. 2018, 7(2), 12-18. doi: 10.11648/j.ajpc.20180702.11

Copy | Download

AMA Style

Adebayo Oluwafemi Lawrence, Kenni Amoke Monisola, Oyetunde Julius Gbenga, Jegede Rufus Oluwafemi, Ajayi Margret Grace. Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL). Am J Phys Chem. 2018;7(2):12-18. doi: 10.11648/j.ajpc.20180702.11

Copy | Download

@article{10.11648/j.ajpc.20180702.11,
  author = {Adebayo Oluwafemi Lawrence and Kenni Amoke Monisola and Oyetunde Julius Gbenga and Jegede Rufus Oluwafemi and Ajayi Margret Grace},
  title = {Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)},
  journal = {American Journal of Physical Chemistry},
  volume = {7},
  number = {2},
  pages = {12-18},
  doi = {10.11648/j.ajpc.20180702.11},
  url = {https://doi.org/10.11648/j.ajpc.20180702.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20180702.11},
  abstract = {The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Copper (11) Ions Biosorption from Aqueous Solution Using Modified Moringa Oleiferal Leaves (MMOL)
AU  - Adebayo Oluwafemi Lawrence
AU  - Kenni Amoke Monisola
AU  - Oyetunde Julius Gbenga
AU  - Jegede Rufus Oluwafemi
AU  - Ajayi Margret Grace
Y1  - 2018/06/01
PY  - 2018
N1  - https://doi.org/10.11648/j.ajpc.20180702.11
DO  - 10.11648/j.ajpc.20180702.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20180702.11
AB  - The present research work demonstrated the ability of MMOL in removing Copper (II) ions from an aqueous solution. The modified (MMOL) and unmodified moringaoleifera (UMOL) was characterized based on PZC and surface area. Isotherm experiments were conducted and the data obtained were fitted to Langmuir and Freundlich isotherm equations. The Freundlich equation gave the best description of the sorption process and the maximum saturated monolayer sorption capacity of the MMOL for CU (II) ions was 78.45 mg g-1. The kinetics of the sorption process was studied by varying the initial CU (II) ions concentrations and the result obtained was analyzed by using pseudo-first-order and pseudo-second-order kinetic models. The pseudo second-order kinetic model was found to fit the experimental data for the entire sorption period with high coefficient of determination (r2). The effects of MMOL dose were studied using batch sorption system. The linear form of the Langmuir equation was used to analyze the data obtained when the sorbent dosage was optimized by method of continuous variation. The results obtained showed that the equilibrium monolayer sorption capacity, qm, of the MMOL for CU (II) ions decreased (78.45 - 38.66 mg g-1) with an increase in sorbent dosage. The result obtained from pH optimization showed that CU(II) ions removal increases with increase in CU(II) ions solution pH.
VL  - 7
IS  - 2
ER  -

Copy | Download