The kinetics of oxidation of cadaverine (CAD) by permanganate ion in acidic, neutral and alkaline media has been investigated spectrophtometrically at constant ionic strengths and temperature. The reactions in different media exhibited a first order kinetics in [MnO4-] and less than unit order dependences with respect to [CAD]. The oxidation of cadaverine showed less than unit order dependences with respect to [H+] and [OH-] in acidic and alkaline media, respectively. Variation of ionic strengths in both acidic and alkaline media had no significant effect on the oxidation rates. The proposed oxidations mechanisms in all media involve formation of 1:1 intermediate complexes between the kinetically active species of both cadaverine and permanganate ion. The final oxidation products of cadaverine were identified as 5-aminopentanal and ammonia. The appropriate rate laws in all media were deduced. The reaction constants involved in the different steps of the mechanisms were evaluated.
| DOI | 10.11648/j.ajpc.20160506.12 |
| Published in | American Journal of Physical Chemistry (Volume 5, Issue 6, December 2016) |
| Page(s) | 108-117 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2024. Published by Science Publishing Group |
Cadaverine, Permanganate, Oxidation, Kinetics, Mechanism
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APA Style
Ahmed Fawzy, Ishaq A. Zaafarany, Metwally Abdallah, Rabab S. Jassas, Rami J. Obaid. (2016). Kinetics and Mechanisms of Permanganate Oxidations of Cadaverine in Different Media. American Journal of Physical Chemistry, 5(6), 108-117. https://doi.org/10.11648/j.ajpc.20160506.12
ACS Style
Ahmed Fawzy; Ishaq A. Zaafarany; Metwally Abdallah; Rabab S. Jassas; Rami J. Obaid. Kinetics and Mechanisms of Permanganate Oxidations of Cadaverine in Different Media. Am. J. Phys. Chem. 2016, 5(6), 108-117. doi: 10.11648/j.ajpc.20160506.12
AMA Style
Ahmed Fawzy, Ishaq A. Zaafarany, Metwally Abdallah, Rabab S. Jassas, Rami J. Obaid. Kinetics and Mechanisms of Permanganate Oxidations of Cadaverine in Different Media. Am J Phys Chem. 2016;5(6):108-117. doi: 10.11648/j.ajpc.20160506.12
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Download@article{10.11648/j.ajpc.20160506.12,
author = {Ahmed Fawzy and Ishaq A. Zaafarany and Metwally Abdallah and Rabab S. Jassas and Rami J. Obaid},
title = {Kinetics and Mechanisms of Permanganate Oxidations of Cadaverine in Different Media},
journal = {American Journal of Physical Chemistry},
volume = {5},
number = {6},
pages = {108-117},
doi = {10.11648/j.ajpc.20160506.12},
url = {https://doi.org/10.11648/j.ajpc.20160506.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20160506.12},
abstract = {The kinetics of oxidation of cadaverine (CAD) by permanganate ion in acidic, neutral and alkaline media has been investigated spectrophtometrically at constant ionic strengths and temperature. The reactions in different media exhibited a first order kinetics in [MnO4-] and less than unit order dependences with respect to [CAD]. The oxidation of cadaverine showed less than unit order dependences with respect to [H+] and [OH-] in acidic and alkaline media, respectively. Variation of ionic strengths in both acidic and alkaline media had no significant effect on the oxidation rates. The proposed oxidations mechanisms in all media involve formation of 1:1 intermediate complexes between the kinetically active species of both cadaverine and permanganate ion. The final oxidation products of cadaverine were identified as 5-aminopentanal and ammonia. The appropriate rate laws in all media were deduced. The reaction constants involved in the different steps of the mechanisms were evaluated.},
year = {2016}
}
TY - JOUR T1 - Kinetics and Mechanisms of Permanganate Oxidations of Cadaverine in Different Media AU - Ahmed Fawzy AU - Ishaq A. Zaafarany AU - Metwally Abdallah AU - Rabab S. Jassas AU - Rami J. Obaid Y1 - 2016/12/23 PY - 2016 N1 - https://doi.org/10.11648/j.ajpc.20160506.12 DO - 10.11648/j.ajpc.20160506.12 T2 - American Journal of Physical Chemistry JF - American Journal of Physical Chemistry JO - American Journal of Physical Chemistry SP - 108 EP - 117 PB - Science Publishing Group SN - 2327-2449 UR - https://doi.org/10.11648/j.ajpc.20160506.12 AB - The kinetics of oxidation of cadaverine (CAD) by permanganate ion in acidic, neutral and alkaline media has been investigated spectrophtometrically at constant ionic strengths and temperature. The reactions in different media exhibited a first order kinetics in [MnO4-] and less than unit order dependences with respect to [CAD]. The oxidation of cadaverine showed less than unit order dependences with respect to [H+] and [OH-] in acidic and alkaline media, respectively. Variation of ionic strengths in both acidic and alkaline media had no significant effect on the oxidation rates. The proposed oxidations mechanisms in all media involve formation of 1:1 intermediate complexes between the kinetically active species of both cadaverine and permanganate ion. The final oxidation products of cadaverine were identified as 5-aminopentanal and ammonia. The appropriate rate laws in all media were deduced. The reaction constants involved in the different steps of the mechanisms were evaluated. VL - 5 IS - 6 ER -
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