Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K
American Journal of Physical Chemistry
Volume 6, Issue 2, April 2017, Pages: 6-19
Received: Feb. 7, 2017; Accepted: Mar. 1, 2017; Published: Mar. 21, 2017
Views 2226      Downloads 115
Authors
Belcher Fulele, Department of Chemistry, Faculty of Science, University of Botswana, Gaborone, Botswana
Wilfred A. A. Ddamba, Department of Chemistry, Faculty of Science, University of Botswana, Gaborone, Botswana
Article Tools
Follow on us
Abstract
Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation. values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.
Keywords
Difurylmethane, an Amide, Excess Molar Volume, Excess Partial Molar Volume, Binary Mixtures, Dipole-Dipole Interactions, Hydrogen Bond
To cite this article
Belcher Fulele, Wilfred A. A. Ddamba, Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K, American Journal of Physical Chemistry. Vol. 6, No. 2, 2017, pp. 6-19. doi: 10.11648/j.ajpc.20170602.11
Copyright
Copyright © 2017 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
References
[1]
Mokate, O., Ddamba, W. A. A., Volumetric properties of difurylmethane in methanol from 288.15 to 308.15K. Journal of Solution Chemistry, 34 (2005) 1327-1339.
[2]
Mokate, O., Ddamba, W. A. A., Volumetric properties of (Difurylmethane + Alkan-1-ol) binary mixtures at 298.15K. Journal of Solution Chemistry, 35 (2006) 1493-1503.
[3]
Mokate, O., Ddamba, W. A. A., Effect of temperature on volumetric properties of [Difurylmethane + (C2-C6) Alkan-1-ol] binary systems: Analyses of new literature density data in the temperature range 288.15-308.15K. Journal of Solution Chemistry, 37 (2008) 331-350.
[4]
Mmereki, B. T., Oathotse, I., Ddamba, W. A. A., Ultrasonic speeds and isentropic compressibilities of {Difurylmethane + (C1-C6) Alkan-1-ol} binary mixtures at T = 298.15K. Journal of Chemical Thermodynamics, 42 (2010) 1346-1351.
[5]
Zarei, H., Golroudbari, A. S., Behroozi, M, Experimental studies on volumetric and viscometric properties of binary and ternary mixtures of N,N-dimethylacetamide, N-methylformamide, and propane-1,2-diol at different temperatures. Journal of Molecular Liquids, 187 (2013) 260-265.
[6]
Nain, K. A., Densities and volumetric properties of (acetonitrile + an amide) binary mixtures at temperatures between 293.15K and 318.15K. Journal of Chemical Thermodynamics, 38 (2006) 1362-1370.
[7]
Garcia, B., Alcalde, R., Leal, M. J., Solute-Solvent interactions in amide-water mixed solvents. Journal of Physical Chemistry, 101 (1997) 7991-7997.
[8]
Gadzuric, S., Nikolic, A., Vranes, M., Jovic, B., Damjanovic, M., Dozic, S., Volumetric properties of binary mixtures of N-ethylformamide with tetrahydrofuran, 2-butanone, and ethylacetate from T = (293.15 to 313.15) K. Journal of Chemical Thermodynamics, 51 (2012) 37-44.
[9]
Jovic, B., Nikolic, A., Kordic, B., Densitometric and spectroscopic investigation of interactions of selected N-substituted amides and acetonitrile. Journal of Molecular Liquids, 191 (2014) 10-15.
[10]
Sengwa, R. J., Sankhla, S., Khatri, V., Choudhary, S., Static permittivity and molecular interactions in binary mixtures of ethanolamine with alcohols and amides. Fluid Phase Equilibria, 293 (2010) 137-140.
[11]
Nain, A. K., Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N, N-dimethylformamide and N, N-dimethylacetamide at different temperatures. Journal of Chemical Thermodynamics, 60 (2013) 105-116.
[12]
Nikolic, A., Jovic, B., Krstic, V., Trickovic, J, Excess molar volumes of N-methylformamide + tetrahydropyran, + 2-pentanone + n-propylacetate at the temperatures between 298.15K and 313.15K. Journal of Molecular Liquids, 133 (2007) 39-42.
[13]
Scharlin, P., Steinby, K., Domanska, U., Volumetric properties of binary mixtures of N,N-dimethylformamide with water or water-d2 at temperatures from 277.13K to 318.15K. Journal of Chemical Thermodynamics, 34 (2002) 927-957.
[14]
Weissberger, A., Organic Solvents: Physical Properties and Methods of Purification, New York, USA: John Wiley & Sons (1986) 55-57.
[15]
Pandey, K., Awasthi, A., Awasthi, A, Acoustic, volumetric and spectroscopic investigations in binary mixtures of formamide/N-methylformamide + 2-chloroethanol at various temperatures. Journal of Molecular Liquids, 189 (2013) 343-349.
[16]
Sharma, V. K., Dua, R., Sharma, D, Excess molar volumes and excess isentropic compressibilities of binary and ternary mixtures of o-chlorotoluene with cyclic ether and amides or cyclohexane at different temperatures. Journal of Chemical Thermodynamics, 78 (2014) 241-253.
[17]
Almasi, M., Thermodynamic properties of binary mixtures containing N,N-dimethylformamide + 2-alkanol. Cubic and statistical associating fluid theory-based equation of state analysis. Taiwan Institute of Chemical Engineers, 45 (2014) 365-371.
[18]
Pal, A., Sharma, S., Kumar, H, Volumetric properties of binary mixtures of 2-alkoxyethanols with N, N-dimethylformamide and N, N-dimethylacetamide at 298.15K. Journal of Molecular Liquids, 108 (2003) 231-255.
[19]
Peshwe, A., Arbad, B., Pachaling, S, Volumetric and viscometric studies on N,N-dimethylacetamide and methanol binary mixtures at different temperatures. Journal of Chemical Science, 7 (2009) 1505-1517.
[20]
Buchwalter. S. L. Polymer Chemistry. Journal of Polymer Science: Polymer Chemistry Edition, 23 (1985) 2879-3098.
[21]
Redlich, O. and Kister, T. A., Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345-348 (1948).
[22]
Ivanov, E., Abrosimov, V. K., Lebedeva, E. Y., Apparent molar volume and expansivities of H2O and D2O in N,N-dimethylformamide and N,N-dimethyacetamide in the range of T = (278.15 to 318.15)K at p=0.1MPa: A comparative analysis Journal of Chemical Thermodynamics, 53 (2012) 131-139.
[23]
Douhẻret, G., Davis, M. I., Measurement, analysis, and utility of excess molar -(∂V/∂p). Chemical Society Reviews, 22 (1993) 43-50.
[24]
Acree Jr, W. E., Thermodynamic properties of nonelectrolytes, Orlando, Florida, USA: Academic Press (1984) 15-19.
[25]
Reading, J. F., Watson, I. D., Hedwig, G. R., Thermodynamic properties of peptide solutions 5. Partial molar volumes of glycylglycine, glycyl-DL-leucine, and glycyl-DL-serine at 308.15 and 318.15K. Journal of Chemical Thermodynamics, 22 (1990) 159-165.
ADDRESS
Science Publishing Group
1 Rockefeller Plaza,
10th and 11th Floors,
New York, NY 10020
U.S.A.
Tel: (001)347-983-5186