Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions

Ahmed Diab; Salah Abd El Wanees

doi:doi:10.11648/j.ajpc.20140303.12

| Peer-Reviewed

Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions

Ahmed Diab, Salah Abd El Wanees

Published in American Journal of Physical Chemistry (Volume 3, Issue 3)

Received: 8 July 2014 Accepted: 18 July 2014 Published: 20 August 2014

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The oxide film formation and growth on indium electrode in Na2B4O7 solutions have been studied using polarization technique. The effects of concentration of Na2B4O7, pH and temperature of electrolyte solution are investigated based on the formation of oxide film. It was found that lowering the concentrations of Na2B4O7 solutions, pH or decreasing of temperature of the solution assist the formation of a passive oxide film on indium electrode. The corrosion current density, icorr, increased with increasing the concentrations of Na2B4O7 solutions, pH and the rising of solution temperature. The free activation energy of oxide film growth process is determined to be 15.7kJ/mole. The above studies indicate that the oxide film growth process is diffusion-controlled. The effect of addition of NaCl, NaBr, and NaI with different amounts was also investigated. Higher concentrations of these salts lead to the dissolution of the passive oxide film due to the increasing of corrosion current density, icorr, and the shift of corrosion potential, Ecorr, to more active potentials.

Published in	American Journal of Physical Chemistry (Volume 3, Issue 3)
DOI	10.11648/j.ajpc.20140303.12
Page(s)	33-40
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Indium, Na2B4O7, Oxide film, Anodic, Cathodic, Polarization, Tafel Slopes

References

[1]	J. R. Mils, R. C. Bell and R. A. King, Rare Metals Handbook . 2nd Edn. Edited by C. A. Hampel. Chapman and Hall Ltd. London (1961) .p. 220.
[2]	J.R. Mills, R.A. King, C.E.T. White, “Indium”, C.A. Hampel (ed) Rare metals handbook, Chapman and Hall Ltd, London, 220-238 (1961).
[3]	W. Koster and B. Thoma, Z. Metallkd., 46, 291 (1955).
[4]	D.G. Avery, D.W. Goodwin, W.D. Lawson and T.S. Moss, Proc. Phys. Soc. B, 67, 761 (1954).
[5]	S. Ozer and C. Besikci J. Phys D: Appl. Phys., 36, 559 (2003).
[6]	C.S. Johnson, J.T. Vaughey, M.M. Thackeray, T. Sarakonsri, S.A. Hackney, L. Fransson, K. Edström and J.O. Thomas, Electrochem. Commun., 2, 595 (2000).
[7]	M.I. Khan, X. Wang, K.N. Bozhilov and C.S. Ozkan, J. Nanomater., 2008, 698759 (2008).
[8]	S.Y. Wang, S.H. Lin and Y.M. Houng, Appl. Phys. Lett., 51, 83 (1987); S. Wang, Fundamentals of semiconductor theory and device physics, Prentice-Hall, Englewood Cliffs, New Jersey, 523 (1989).
[9]	T.S. Chao, C.L. Lee and T.F. Lei, J. Mater. Sci. Lett., 12, 721 (1993).
[10]	T. Inushima, V.V. Mamutin, V.A. Vekshin, S.V. Ivanov, T. Sakon, M. Motokawa, S. Ohoya, J. Cryst. Growth, 227-228, 481 (2001).
[11]	A.G. Bhuiyan, A. Hashimoto and A. Yamamoto, J. Appl. Phys., 94, 2779 (2003).
[12]	T.P. Pearsall and M. Papuchon, Appl. Phys. Lett., 33, 640 (1978).
[13]	W.J. Li, Y.N. Zhou and Z.W. Fu, Appl. Surf. Sci., 257, 2881 (2011).
[14]	V.A. Williams, J. Electrochem. Soc., 113, 234 (1966).
[15]	J.L. Vossen and E.S. Poliniak, Thin Solid Films, 13, 281 (1972).
[16]	A. Yamamoto, M. Tsujino, M. Ohkubo and A. Hashimoto, Sol. Energ. Mat. Sol. C., 35, 53 (1994).
[17]	H.P.T. Nguyen, Y.L. Chang, I. Shih and Z. Mi, IEEE J. Sel. Top. Quant., 17, 1062 (2011).
[18]	H. Neff, O.K. Semchinova, A. M.N. Lima, A. Filimonov and G. Holzhueter, Sol. Energy Materials & Solar Cells, 90, 982 (2006).
[19]	S.W. Zeng, X.M. Cai and B.P. Zhang, IEEE J. Quantum Elect., 46, 783 (2010).
[20]	S. Wagner and P.M. Bridenbaugh, J. Cryst. Growth, 39, 151 (1977).
[21]	A.N. Tiwari, D.K. Pandya and K.L. Chopra, Sol. Energ. Mater., 15, 121 (1987).
[22]	M. Kemell, M. Ritala and M. Leskelä, Crit. Rev. Solid State Mater. Sci., 30, 1 (2005).
[23]	V. S. Saji, S. M. Lee and C. W. Lee, J. Kor. Electrochem. Soc., 14, 61 (2011).
[24]	S.J. Duncan, G.T. Burstein, J. Appl. Electrochem. 17 (1987) 196.
[25]	S. Omanovi´c, M. Metikoš-Hukovi´c, Solid State Ionics 78 (1995) 69.
[26]	M. Metikoš-Hukovi´c, S. Omanovi´c, J. Electroanal. Chem. 455 (1998) 181.
[27]	K. Wade, A.J. Banister, in: J.C. Bailar, H.J. Emeléus, Sir Ronald Nyholm, A.F. Trotman-Dickenson (Eds.), Comprehensive Inorganic Chemistry, vol. 1, Pergamon Press, Oxford, 1973.
[28]	S.Omanovic and M. Metikos-Hukovic, Solid State Ionics 78 (1995) 69.
[29]	M .Metikos-Hukovic and S. Omanovic, J. Electroanal. Chem. 455 (1998) 181-189.
[30]	S.B. Saidman, E.C. Bellocq, J.B. Bessone, Electrochim. Acta 35 (1990) 329-338.
[31]	S.Omanovic and M. Metikos-Hukovic, J. Appl. Electrochem., 27( 1997) 35-41.
[32]	S.B. Saidman, J.B. Bessone, Electrochim. Acta, 36(1991) 2063-2067.
[33]	A.G. Munoz, J.B. Bessone, Electrochim. Acta, 43 (1998) 2033-2040.
[34]	S. Omanovic and M. Metikos-Hokovic, Thin Solid Films, 458, 52 (2004).
[35]	M. Stern and A.L. Geary, J., Electrochem. Soc., 104(1957) 56.
[36]	S.B. Saidman, E.C. Bellocq, J.B. Bessone, Electrochim. Acta 35 (1990) 329.
[37]	S. Omaovic and M. Metikos-Hukovic., Solid State Ionics 78 (1995) 69-78.
[38]	T. Popova, N.A. Simonova, Izv. Akad. Nauk. SSSR. Ser. Khim. 7 (1963) 1086.
[39]	R. Piercy, N.A. Hampson, J. Electroanal. Chem. 53 (1974) 271.
[40]	R.D. Armstrong, A.B. Suttie, H.R. Thirsk, Electrochim. Acta 13 (1968) 1.
[41]	F. Faizullin, N.A. Amirkhanova, Elektrokhimiya 2 (1966) 80.
[42]	A. G. Munoz and J. B. Bessone, J. Electrochimica Acta, 43, 14-15(1998) 2033-2040.
[43]	J.M. Abd El Kader and A.M. Shams El Din, British Corrosion Journal 4(1979) 40–45.
[44]	Yonghwa Chung and Chi-Woo Lee, Journal of Electrochemical Science and Technology, 3, No. 1, (2012) 1-13
[45]	A.M. Bond, J. Electrochem. Soc., 119, 1503 (1972).
[46]	P. Kondziela and J. Biernat, J. Electroanal. Chem., 61, 281 (1975).
[47]	C. Nanjundiah and R. Narayan, Electrochim. Acta, 26, 203 (1981).

Cite This Article

Plain Text BibTeX RIS

APA Style

Ahmed Diab, Salah Abd El Wanees. (2014). Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. American Journal of Physical Chemistry, 3(3), 33-40. https://doi.org/10.11648/j.ajpc.20140303.12

Copy | Download

ACS Style

Ahmed Diab; Salah Abd El Wanees. Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. Am. J. Phys. Chem. 2014, 3(3), 33-40. doi: 10.11648/j.ajpc.20140303.12

Copy | Download

AMA Style

Ahmed Diab, Salah Abd El Wanees. Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. Am J Phys Chem. 2014;3(3):33-40. doi: 10.11648/j.ajpc.20140303.12

Copy | Download

@article{10.11648/j.ajpc.20140303.12,
  author = {Ahmed Diab and Salah Abd El Wanees},
  title = {Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {3},
  pages = {33-40},
  doi = {10.11648/j.ajpc.20140303.12},
  url = {https://doi.org/10.11648/j.ajpc.20140303.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140303.12},
  abstract = {The oxide film formation and growth on indium electrode in Na2B4O7 solutions have been studied using polarization technique. The effects of concentration of Na2B4O7, pH and temperature of electrolyte solution are investigated based on the formation of oxide film. It was found that lowering the concentrations of Na2B4O7 solutions, pH or decreasing of temperature of the solution assist the formation of a passive oxide film on indium electrode. The corrosion current density, icorr, increased with increasing the concentrations of Na2B4O7 solutions, pH and the rising of solution temperature. The free activation energy of oxide film growth process is determined to be 15.7kJ/mole. The above studies indicate that the oxide film growth process is diffusion-controlled. The effect of addition of NaCl, NaBr, and NaI with different amounts was also investigated. Higher concentrations of these salts lead to the dissolution of the passive oxide film due to the increasing of corrosion current density, icorr, and the shift of corrosion potential, Ecorr, to more active potentials.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions
AU  - Ahmed Diab
AU  - Salah Abd El Wanees
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajpc.20140303.12
DO  - 10.11648/j.ajpc.20140303.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 33
EP  - 40
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140303.12
AB  - The oxide film formation and growth on indium electrode in Na2B4O7 solutions have been studied using polarization technique. The effects of concentration of Na2B4O7, pH and temperature of electrolyte solution are investigated based on the formation of oxide film. It was found that lowering the concentrations of Na2B4O7 solutions, pH or decreasing of temperature of the solution assist the formation of a passive oxide film on indium electrode. The corrosion current density, icorr, increased with increasing the concentrations of Na2B4O7 solutions, pH and the rising of solution temperature. The free activation energy of oxide film growth process is determined to be 15.7kJ/mole. The above studies indicate that the oxide film growth process is diffusion-controlled. The effect of addition of NaCl, NaBr, and NaI with different amounts was also investigated. Higher concentrations of these salts lead to the dissolution of the passive oxide film due to the increasing of corrosion current density, icorr, and the shift of corrosion potential, Ecorr, to more active potentials.
VL  - 3
IS  - 3
ER  -

Copy | Download

Author Information

Ahmed Diab

Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt; Chemistry Department, Faculty of Preparatory Year, Jazan University, Jazan, KSA
Salah Abd El Wanees

Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt; Chemistry Department, Faculty of Science, Tabouk University, Tabouk, KSA

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Ahmed Diab, Salah Abd El Wanees. (2014). Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. American Journal of Physical Chemistry, 3(3), 33-40. https://doi.org/10.11648/j.ajpc.20140303.12

Copy | Download

ACS Style

Ahmed Diab; Salah Abd El Wanees. Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. Am. J. Phys. Chem. 2014, 3(3), 33-40. doi: 10.11648/j.ajpc.20140303.12

Copy | Download

AMA Style

Ahmed Diab, Salah Abd El Wanees. Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions. Am J Phys Chem. 2014;3(3):33-40. doi: 10.11648/j.ajpc.20140303.12

Copy | Download

@article{10.11648/j.ajpc.20140303.12,
  author = {Ahmed Diab and Salah Abd El Wanees},
  title = {Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {3},
  pages = {33-40},
  doi = {10.11648/j.ajpc.20140303.12},
  url = {https://doi.org/10.11648/j.ajpc.20140303.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140303.12},
  abstract = {The oxide film formation and growth on indium electrode in Na2B4O7 solutions have been studied using polarization technique. The effects of concentration of Na2B4O7, pH and temperature of electrolyte solution are investigated based on the formation of oxide film. It was found that lowering the concentrations of Na2B4O7 solutions, pH or decreasing of temperature of the solution assist the formation of a passive oxide film on indium electrode. The corrosion current density, icorr, increased with increasing the concentrations of Na2B4O7 solutions, pH and the rising of solution temperature. The free activation energy of oxide film growth process is determined to be 15.7kJ/mole. The above studies indicate that the oxide film growth process is diffusion-controlled. The effect of addition of NaCl, NaBr, and NaI with different amounts was also investigated. Higher concentrations of these salts lead to the dissolution of the passive oxide film due to the increasing of corrosion current density, icorr, and the shift of corrosion potential, Ecorr, to more active potentials.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Controlling the Passive Oxide Film Formation on Indium Electrode in Na2B4O7 Solutions
AU  - Ahmed Diab
AU  - Salah Abd El Wanees
Y1  - 2014/08/20
PY  - 2014
N1  - https://doi.org/10.11648/j.ajpc.20140303.12
DO  - 10.11648/j.ajpc.20140303.12
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 33
EP  - 40
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20140303.12
AB  - The oxide film formation and growth on indium electrode in Na2B4O7 solutions have been studied using polarization technique. The effects of concentration of Na2B4O7, pH and temperature of electrolyte solution are investigated based on the formation of oxide film. It was found that lowering the concentrations of Na2B4O7 solutions, pH or decreasing of temperature of the solution assist the formation of a passive oxide film on indium electrode. The corrosion current density, icorr, increased with increasing the concentrations of Na2B4O7 solutions, pH and the rising of solution temperature. The free activation energy of oxide film growth process is determined to be 15.7kJ/mole. The above studies indicate that the oxide film growth process is diffusion-controlled. The effect of addition of NaCl, NaBr, and NaI with different amounts was also investigated. Higher concentrations of these salts lead to the dissolution of the passive oxide film due to the increasing of corrosion current density, icorr, and the shift of corrosion potential, Ecorr, to more active potentials.
VL  - 3
IS  - 3
ER  -

Copy | Download