Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2

N. S. Orang; R. Abdollahi

doi:doi:10.11648/j.ajpc.20140303.11

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Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2

N. S. Orang, R. Abdollahi

Published in American Journal of Physical Chemistry (Volume 3, Issue 3)

Received: 1 March 2014 Accepted: 12 April 2014 Published: 30 June 2014

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Abstract

The degradation of poly (vinyl pyrrolidone) (PVP) by means of ultrasound irradiation and its combination with homogeneous photocatalysis (photo-Fenton) was investigated. Emphasis was given on the effect of additive on degradation rate constants. 24 kHz of ultrasound irradiation was provided by a sonicator, while an ultraviolet source of 16 W was used for UV irradiation. To increase the efficiency of degradation process, degradation system was combined with Fe (III) (2.510-4mol/L) and H2O2 (0.020 - 0.118 mol/L) in the presence of UV irradiation and the rate of degradation process change from 4.07x10-5 to 8.24x10-5 mol15 l-1.5 min-1. Photo-Fenton process led to complete PVP degradation in 150 min with the rate increasing with increasing catalyst loading. Sonophotocatalysis in the presence of Fe (III)/H2O2 was always faster than the respective individual processes. A negative order for the dependence of the reaction rate on total molar concentration of PVP solution within the degradation process was suggested. Results of this study indicate that the presence of catalyst in the reaction medium can be utilized to reduce molecular weight of PVP while maintaining the power of irradiated ultrasound.

Published in	American Journal of Physical Chemistry (Volume 3, Issue 3)
DOI	10.11648/j.ajpc.20140303.11
Page(s)	26-32
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Poly (Vinyl Pyrrolidone), Sono-Fenton, Sonophoto-Fenton, Fe (III)/H2O2, Viscosity

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APA Style

N. S. Orang, R. Abdollahi. (2014). Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. American Journal of Physical Chemistry, 3(3), 26-32. https://doi.org/10.11648/j.ajpc.20140303.11

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ACS Style

N. S. Orang; R. Abdollahi. Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. Am. J. Phys. Chem. 2014, 3(3), 26-32. doi: 10.11648/j.ajpc.20140303.11

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AMA Style

N. S. Orang, R. Abdollahi. Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. Am J Phys Chem. 2014;3(3):26-32. doi: 10.11648/j.ajpc.20140303.11

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@article{10.11648/j.ajpc.20140303.11,
  author = {N. S. Orang and R. Abdollahi},
  title = {Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {3},
  pages = {26-32},
  doi = {10.11648/j.ajpc.20140303.11},
  url = {https://doi.org/10.11648/j.ajpc.20140303.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140303.11},
  abstract = {The degradation of poly (vinyl pyrrolidone) (PVP) by means of ultrasound irradiation and its combination with homogeneous photocatalysis (photo-Fenton) was investigated. Emphasis was given on the effect of additive on degradation rate constants. 24 kHz of ultrasound irradiation was provided by a sonicator, while an ultraviolet source of 16 W was used for UV irradiation. To increase the efficiency of degradation process, degradation system was combined with Fe (III) (2.510-4mol/L) and H2O2 (0.020 - 0.118 mol/L) in the presence of UV irradiation and the rate of degradation process change from 4.07x10-5 to 8.24x10-5 mol15 l-1.5 min-1. Photo-Fenton process led to complete PVP degradation in 150 min with the rate increasing with increasing catalyst loading. Sonophotocatalysis in the presence of Fe (III)/H2O2 was always faster than the respective individual processes. A negative order for the dependence of the reaction rate on total molar concentration of PVP solution within the degradation process was suggested. Results of this study indicate that the presence of catalyst in the reaction medium can be utilized to reduce molecular weight of PVP while maintaining the power of irradiated ultrasound.},
 year = {2014}
}

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TY - JOUR
T1 - Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2
AU - N. S. Orang
AU - R. Abdollahi
Y1 - 2014/06/30
PY - 2014
N1 - https://doi.org/10.11648/j.ajpc.20140303.11
DO - 10.11648/j.ajpc.20140303.11
T2 - American Journal of Physical Chemistry
JF - American Journal of Physical Chemistry
JO - American Journal of Physical Chemistry
SP - 26
EP - 32
PB - Science Publishing Group
SN - 2327-2449
UR - https://doi.org/10.11648/j.ajpc.20140303.11
AB - The degradation of poly (vinyl pyrrolidone) (PVP) by means of ultrasound irradiation and its combination with homogeneous photocatalysis (photo-Fenton) was investigated. Emphasis was given on the effect of additive on degradation rate constants. 24 kHz of ultrasound irradiation was provided by a sonicator, while an ultraviolet source of 16 W was used for UV irradiation. To increase the efficiency of degradation process, degradation system was combined with Fe (III) (2.510-4mol/L) and H2O2 (0.020 - 0.118 mol/L) in the presence of UV irradiation and the rate of degradation process change from 4.07x10-5 to 8.24x10-5 mol15 l-1.5 min-1. Photo-Fenton process led to complete PVP degradation in 150 min with the rate increasing with increasing catalyst loading. Sonophotocatalysis in the presence of Fe (III)/H2O2 was always faster than the respective individual processes. A negative order for the dependence of the reaction rate on total molar concentration of PVP solution within the degradation process was suggested. Results of this study indicate that the presence of catalyst in the reaction medium can be utilized to reduce molecular weight of PVP while maintaining the power of irradiated ultrasound.
VL - 3
IS - 3
ER -

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Author Information

N. S. Orang

Department of Chemical Engineering, Islamic Azad University-Ahar Branch, Ahar, Iran
R. Abdollahi

Department of Chemical Engineering, Islamic Azad University-Ahar Branch, Ahar, Iran

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APA Style

N. S. Orang, R. Abdollahi. (2014). Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. American Journal of Physical Chemistry, 3(3), 26-32. https://doi.org/10.11648/j.ajpc.20140303.11

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ACS Style

N. S. Orang; R. Abdollahi. Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. Am. J. Phys. Chem. 2014, 3(3), 26-32. doi: 10.11648/j.ajpc.20140303.11

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AMA Style

N. S. Orang, R. Abdollahi. Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2. Am J Phys Chem. 2014;3(3):26-32. doi: 10.11648/j.ajpc.20140303.11

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@article{10.11648/j.ajpc.20140303.11,
  author = {N. S. Orang and R. Abdollahi},
  title = {Sonophotocatalytic Degradation of Poly (Vinyl Pyrrolidone) in the Presence of Fe (III)/H2O2},
  journal = {American Journal of Physical Chemistry},
  volume = {3},
  number = {3},
  pages = {26-32},
  doi = {10.11648/j.ajpc.20140303.11},
  url = {https://doi.org/10.11648/j.ajpc.20140303.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140303.11},
  abstract = {The degradation of poly (vinyl pyrrolidone) (PVP) by means of ultrasound irradiation and its combination with homogeneous photocatalysis (photo-Fenton) was investigated. Emphasis was given on the effect of additive on degradation rate constants. 24 kHz of ultrasound irradiation was provided by a sonicator, while an ultraviolet source of 16 W was used for UV irradiation. To increase the efficiency of degradation process, degradation system was combined with Fe (III) (2.510-4mol/L) and H2O2 (0.020 - 0.118 mol/L) in the presence of UV irradiation and the rate of degradation process change from 4.07x10-5 to 8.24x10-5 mol15 l-1.5 min-1. Photo-Fenton process led to complete PVP degradation in 150 min with the rate increasing with increasing catalyst loading. Sonophotocatalysis in the presence of Fe (III)/H2O2 was always faster than the respective individual processes. A negative order for the dependence of the reaction rate on total molar concentration of PVP solution within the degradation process was suggested. Results of this study indicate that the presence of catalyst in the reaction medium can be utilized to reduce molecular weight of PVP while maintaining the power of irradiated ultrasound.},
 year = {2014}
}

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