The interaction of two anionic polyelectrolytes, namely, sodium alginate (NaAlg) & sodium heparin ate (NaHep) with a cationic dye Toluidine Blue (TB) has been investigated by spectrophotometric method. The polymers induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between TB and sodiumalginate was found to be lesser than that formed between TB and sodiumheparinate. This fact was further confirmed by reversal studies using alcohols, urea and electrolytes. The interaction parameters revealed that binding between TB and anionic polyelectrolytes was mainly due to electrostatic interaction andhydrophobicforces. The effect of the temperature on to metachromasy has beendiscussed.
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Science Journal of Chemistry (Volume 5, Issue 4-1)
This article belongs to the Special Issue Polyelectrolyte-Dye Interaction |
| DOI | 10.11648/j.sjc.s.2017050401.11 |
| Page(s) | 1-7 |
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Cationic Dye, Metachromasy, Polyelectrolyte’s, Aggregation, Temperature
| [1] | A Mitra, R. K Nath, SBiswas., A. K., Chakraborty, A. K., Panda Mitra A., J. Photochrem. Photobiol, A: Chem, vol. 111, 1997, pp 157. |
| [2] | A. Mitra, A. K. Chakraborty, J. Photochem. Photobiol. A: Chem., vol. 178, 2006, pp198. |
| [3] | R. W Horbin., Biochemie. Biochem., vol.77, 2002, pp 3. |
| [4] | Bergeron J. A., M. J Singer, Biophys. Biochem. Cytol. vol. 4, 1958, pp. 433. |
| [5] | M. K. Pal, B. K. Ghosh, Makromol. Chem. vol. 181, 1980, pp1459. |
| [6] | Norden B., Kubista M., in: B. Samori, E. W. Thulstrup (Eds.), Polarized Spectroscopy of ordered systems, vol. 242, Kulwer Academic Publisher, Dordrecht, Holland, 1988. |
| [7] | Sabate R., Esterlich J. J. Phys. Chem B, vol. 107, 2003, pp. 4137. |
| [8] | Meszaos R., Varga, I., Gilanyi T., J. Phys. Chem. B vol.117, 2005, pp.13538. |
| [9] | Monteux C., Williams C. E., Meunier J., Anthony O., Bergeron V., Langmuir Vol. 20, 2004, pp. 57. |
| [10] | Honda C., Kamizono H.,. Matsumoto K., Endo K., J. Colloid Interface Sci vol. 278. 2004, pp. 310. |
| [11] | Moulik S. P., Gupta S,. Das A. R., Makromol. Chem, vol. 181, 1980, pp. 1459. |
| [12] | Lee J., Moroi Y, J. Colloid Interface Sci. 2 vol. 273, 2004, pp. 645. |
| [13] | Mesa C. L., J. Colloid Interface Sci. vol. 286, 2005, pp. 148. |
| [14] | Konradi R., Ruhe J., Macromolecules vol. 38, 2005, pp. 6140. |
| [15] | Villeti M., Borsali A., Crespo R., Soldi V., Fukada K., Macromol. Chem. Phys. vol. 205, 2004, pp. 907. |
| [16] | Fundin J, Hansson P., Brown W., Lidegran I., Macromolecules vol.30, 1997, pp. 1118. |
| [17] | Ohkuma S., Furuhata T, M. J. A. Proc. Japan Acad., vol 46, (1974), 857. |
| [18] | Stone A. L., Bradely D. F., Biochim. Biophys. Acta; vol. 148, (1967), 172. |
| [19] | Ohkuma S., Fukawa K., Furihata T., Proc. Japan Acad; vol. 46, (1970), 713. |
| [20] | Dorfman A., Am. Acad. Pediat Proc; vol. 22, (1958), 573. |
| [21] | Ohkuma S., Furuhata T., Proc. Japan. Acad. vol. 46, (1970), 884. |
| [22] | Kelley J. W., Chang L., Rothstein F., The journal of Histochemistry and Cytochemistry, vol. 17, (1969), 651. |
| [23] | Ushio H., Uchimura H., Sano T., Yasunaga T., Polymer Journal, vol. 10, (1978), 153. |
| [24] | Gupta A. K., and Rohatgi-Mukherjee K. K, J. Indian Chem. Soc.1 vol. 59, 982, pp.578. |
| [25] | Pal M. K., Schubert M. J. Histochem Cytoche., vol. 9, 1961, pp. 673. |
| [26] | Pal M. K, and Ghosh B. K., Macromol. Chem, vol. 181, 1980, pp. 1459. |
| [27] | Pal M. K and Ghosh B. K., Macromol. Chem. vol. 180, 1979, pp. 959. |
| [28] | Pal M. K and Schubert M., J. Phys. Chem., vol. 17, 1963, pp. 182. |
| [29] | Frank. H. S., and. Evans M. W., J. Chem. Phys. vol. 17, 1945, pp. 507. |
| [30] | Kauzmann W., Advan. Protein. Chem. vol. 14, 1959, pp1. |
| [31] | Bruning and Holtzer A., J. Am. Chem Soc., vol. 83, 1961, pp. 4865. |
| [32] | Whitney P. L., and Tanford C., J. Biol. Chem vol. 237, 1962, pp. 1735. |
| [33] | Mukerjee P., and Ray A., J. Phys. Chem. vol. 67, 1963, pp. 190. |
| [34] | Tan J. S, Schneider R. L, J. Phys. Chem. vol. 79, 1975, pp.1380. |
| [35] | RoseNJ; DragoRS; Journal of American Chemical Society, 1 vol. 81, 959, pp. 6138. |
| [36] | Nandini R, Vishalakshi B, J. Polym Eng, vol 31., 2011, pp. 191. |
| [37] | Nandini R, Vishalakshi B, spectrochimica acta Part A, vol 75., 2010 pp. 14. |
| [38] | Rose N. J., and Drago R. S., J. Am. Chem. Soc., 81, 1959, 6138. |
| [39] | Gummow B. D., and Roberts G. A. F., Makromol. Chem., 187, 1985, 995. |
APA Style
Nandini R., Vishalakshi B. (2017). A Comparative Study of Metachromasy Induced by Anionic Polelectroytes in Toluidine Blue. Science Journal of Chemistry, 5(4-1), 1-7. https://doi.org/10.11648/j.sjc.s.2017050401.11
ACS Style
Nandini R.; Vishalakshi B. A Comparative Study of Metachromasy Induced by Anionic Polelectroytes in Toluidine Blue. Sci. J. Chem. 2017, 5(4-1), 1-7. doi: 10.11648/j.sjc.s.2017050401.11
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Download@article{10.11648/j.sjc.s.2017050401.11,
author = {Nandini R. and Vishalakshi B.},
title = {A Comparative Study of Metachromasy Induced by Anionic Polelectroytes in Toluidine Blue},
journal = {Science Journal of Chemistry},
volume = {5},
number = {4-1},
pages = {1-7},
doi = {10.11648/j.sjc.s.2017050401.11},
url = {https://doi.org/10.11648/j.sjc.s.2017050401.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.s.2017050401.11},
abstract = {The interaction of two anionic polyelectrolytes, namely, sodium alginate (NaAlg) & sodium heparin ate (NaHep) with a cationic dye Toluidine Blue (TB) has been investigated by spectrophotometric method. The polymers induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between TB and sodiumalginate was found to be lesser than that formed between TB and sodiumheparinate. This fact was further confirmed by reversal studies using alcohols, urea and electrolytes. The interaction parameters revealed that binding between TB and anionic polyelectrolytes was mainly due to electrostatic interaction andhydrophobicforces. The effect of the temperature on to metachromasy has beendiscussed.},
year = {2017}
}
TY - JOUR T1 - A Comparative Study of Metachromasy Induced by Anionic Polelectroytes in Toluidine Blue AU - Nandini R. AU - Vishalakshi B. Y1 - 2017/03/06 PY - 2017 N1 - https://doi.org/10.11648/j.sjc.s.2017050401.11 DO - 10.11648/j.sjc.s.2017050401.11 T2 - Science Journal of Chemistry JF - Science Journal of Chemistry JO - Science Journal of Chemistry SP - 1 EP - 7 PB - Science Publishing Group SN - 2330-099X UR - https://doi.org/10.11648/j.sjc.s.2017050401.11 AB - The interaction of two anionic polyelectrolytes, namely, sodium alginate (NaAlg) & sodium heparin ate (NaHep) with a cationic dye Toluidine Blue (TB) has been investigated by spectrophotometric method. The polymers induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between TB and sodiumalginate was found to be lesser than that formed between TB and sodiumheparinate. This fact was further confirmed by reversal studies using alcohols, urea and electrolytes. The interaction parameters revealed that binding between TB and anionic polyelectrolytes was mainly due to electrostatic interaction andhydrophobicforces. The effect of the temperature on to metachromasy has beendiscussed. VL - 5 IS - 4-1 ER -
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