Science Journal of Chemistry

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Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds

Received: 13 June 2018    Accepted: 27 June 2018    Published: 23 July 2018
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Abstract

A Schiff base (SB) derived from p-hydroxy benzaldehyde and 4-aminobenzoic acid. The transition metal complexes of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) were prepared separately with the Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data show the formation of 1:2 [M1:2L] and 1:3 [M2:3L] complexes of the formula of M2+L2 and M3+L3, respectively where M2+ =Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and M3+= Cr (III) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are nonelectrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complex compounds. The free Schiff base and its complexes have been tested for their antimicrobial activities against several human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that the complex compounds exhibit moderate to strong antimicrobial activity compared with kanamycin and ampicillin.

DOI 10.11648/j.sjc.20180602.11
Published in Science Journal of Chemistry (Volume 6, Issue 2, April 2018)
Page(s) 17-23
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Schiff Base, Metal Complex, Spectral Studies, Antimicrobial Activity

References
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Author Information
  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Textile Engineering, Khwaja Yunus Ali University, Sirajganj, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Rangpur, Bangladesh

  • Department of Chemistry, Mawlana Bhashani Science and Technology University, Santosh, Tangail, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

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  • APA Style

    Md. Motahar Hossain, Md. Abul Bashar, Md. Nuruzzaman Khan, Pijush Kanti Roy, Md. Siddik Ali, et al. (2018). Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds. Science Journal of Chemistry, 6(2), 17-23. https://doi.org/10.11648/j.sjc.20180602.11

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    ACS Style

    Md. Motahar Hossain; Md. Abul Bashar; Md. Nuruzzaman Khan; Pijush Kanti Roy; Md. Siddik Ali, et al. Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds. Sci. J. Chem. 2018, 6(2), 17-23. doi: 10.11648/j.sjc.20180602.11

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    AMA Style

    Md. Motahar Hossain, Md. Abul Bashar, Md. Nuruzzaman Khan, Pijush Kanti Roy, Md. Siddik Ali, et al. Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds. Sci J Chem. 2018;6(2):17-23. doi: 10.11648/j.sjc.20180602.11

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  • @article{10.11648/j.sjc.20180602.11,
      author = {Md. Motahar Hossain and Md. Abul Bashar and Md. Nuruzzaman Khan and Pijush Kanti Roy and Md. Siddik Ali and Md. Akhter Farooque},
      title = {Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds},
      journal = {Science Journal of Chemistry},
      volume = {6},
      number = {2},
      pages = {17-23},
      doi = {10.11648/j.sjc.20180602.11},
      url = {https://doi.org/10.11648/j.sjc.20180602.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.sjc.20180602.11},
      abstract = {A Schiff base (SB) derived from p-hydroxy benzaldehyde and 4-aminobenzoic acid. The transition metal complexes of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) were prepared separately with the Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data show the formation of 1:2 [M1:2L] and 1:3 [M2:3L] complexes of the formula of M2+L2 and M3+L3, respectively where M2+ =Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and M3+= Cr (III) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are nonelectrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complex compounds. The free Schiff base and its complexes have been tested for their antimicrobial activities against several human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that the complex compounds exhibit moderate to strong antimicrobial activity compared with kanamycin and ampicillin.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Preparation, Physical Characterization and Antibacterial Activity of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) Schiff Base Complex Compounds
    AU  - Md. Motahar Hossain
    AU  - Md. Abul Bashar
    AU  - Md. Nuruzzaman Khan
    AU  - Pijush Kanti Roy
    AU  - Md. Siddik Ali
    AU  - Md. Akhter Farooque
    Y1  - 2018/07/23
    PY  - 2018
    N1  - https://doi.org/10.11648/j.sjc.20180602.11
    DO  - 10.11648/j.sjc.20180602.11
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 17
    EP  - 23
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20180602.11
    AB  - A Schiff base (SB) derived from p-hydroxy benzaldehyde and 4-aminobenzoic acid. The transition metal complexes of Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and Cr (III) were prepared separately with the Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data show the formation of 1:2 [M1:2L] and 1:3 [M2:3L] complexes of the formula of M2+L2 and M3+L3, respectively where M2+ =Ni (II), Cu (II), Co (II), Cd (II), Zn (II) and M3+= Cr (III) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are nonelectrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complex compounds. The free Schiff base and its complexes have been tested for their antimicrobial activities against several human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that the complex compounds exhibit moderate to strong antimicrobial activity compared with kanamycin and ampicillin.
    VL  - 6
    IS  - 2
    ER  - 

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