Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Wen Yao; Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Emtenan Suliman Hassan; Ali Mahmoud Alamin

doi:doi:10.11648/j.sjc.20160405.12

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Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Emtenan Suliman Hassan, Ali Mahmoud Alamin

Received: 27 August 2016 Accepted: 21 September 2016 Published: 11 October 2016

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Abstract

A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.

DOI	10.11648/j.sjc.20160405.12
Published in	Science Journal of Chemistry (Volume 4, Issue 5, October 2016)
Page(s)	61-68
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Ionic Liquids Monomer, Suspension Polymerization, High Oil-Absorption Resins, Oil Absorbency

References

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APA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, et al. (2016). Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Science Journal of Chemistry, 4(5), 61-68. https://doi.org/10.11648/j.sjc.20160405.12

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ACS Style

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Wen Yao; Mahgoub Ibrahim Shinger, et al. Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Sci. J. Chem. 2016, 4(5), 61-68. doi: 10.11648/j.sjc.20160405.12

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AMA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, et al. Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Sci J Chem. 2016;4(5):61-68. doi: 10.11648/j.sjc.20160405.12

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@article{10.11648/j.sjc.20160405.12,
  author = {Fathelrahman Mohammed Soliman and Wu Yang and Hao Guo and Wen Yao and Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Emtenan Suliman Hassan and Ali Mahmoud Alamin},
  title = {Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance},
  journal = {Science Journal of Chemistry},
  volume = {4},
  number = {5},
  pages = {61-68},
  doi = {10.11648/j.sjc.20160405.12},
  url = {https://doi.org/10.11648/j.sjc.20160405.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20160405.12},
  abstract = {A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.},
 year = {2016}
}

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TY  - JOUR
T1  - Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance
AU  - Fathelrahman Mohammed Soliman
AU  - Wu Yang
AU  - Hao Guo
AU  - Wen Yao
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Emtenan Suliman Hassan
AU  - Ali Mahmoud Alamin
Y1  - 2016/10/11
PY  - 2016
N1  - https://doi.org/10.11648/j.sjc.20160405.12
DO  - 10.11648/j.sjc.20160405.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 61
EP  - 68
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20160405.12
AB  - A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.
VL  - 4
IS  - 5
ER  -

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Author Information

Fathelrahman Mohammed Soliman

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wu Yang

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Hao Guo

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wen Yao

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Mahgoub Ibrahim Shinger

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Ahmed Mahmoud Idris

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Emtenan Suliman Hassan

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Ali Mahmoud Alamin

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

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APA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, et al. (2016). Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Science Journal of Chemistry, 4(5), 61-68. https://doi.org/10.11648/j.sjc.20160405.12

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ACS Style

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Wen Yao; Mahgoub Ibrahim Shinger, et al. Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Sci. J. Chem. 2016, 4(5), 61-68. doi: 10.11648/j.sjc.20160405.12

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AMA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, et al. Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance. Sci J Chem. 2016;4(5):61-68. doi: 10.11648/j.sjc.20160405.12

Copy | Download

@article{10.11648/j.sjc.20160405.12,
  author = {Fathelrahman Mohammed Soliman and Wu Yang and Hao Guo and Wen Yao and Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Emtenan Suliman Hassan and Ali Mahmoud Alamin},
  title = {Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance},
  journal = {Science Journal of Chemistry},
  volume = {4},
  number = {5},
  pages = {61-68},
  doi = {10.11648/j.sjc.20160405.12},
  url = {https://doi.org/10.11648/j.sjc.20160405.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20160405.12},
  abstract = {A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance
AU  - Fathelrahman Mohammed Soliman
AU  - Wu Yang
AU  - Hao Guo
AU  - Wen Yao
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Emtenan Suliman Hassan
AU  - Ali Mahmoud Alamin
Y1  - 2016/10/11
PY  - 2016
N1  - https://doi.org/10.11648/j.sjc.20160405.12
DO  - 10.11648/j.sjc.20160405.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 61
EP  - 68
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20160405.12
AB  - A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.
VL  - 4
IS  - 5
ER  -

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